osmium hexafluoride
- Formula: F6Os
- Molecular weight: 304.22
- CAS Registry Number: 13768-38-2
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
5.93 ± 0.28 | TDEq | Korobov, Kuznetsov, et al., 1989 | PtF4- + OsF6 <=> OsF6- + PtF4, ΔH = -10.0±1.3 kcal/mol.; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
12.2 | PE | Vovna, Dudin, et al., 1980 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Korobov, Kuznetsov, et al., 1989
Korobov, M.V.; Kuznetsov, S.V.; Sidorov, L.N.; Shipachev, V.A.; Mit'kin, V.N.,
Gas Phase Negative Ions of Platinum Metal Fluorides. II. Electron Affinity of Platinum Metal Hexafluorides,
Int. J. Mass Spectrom. Ion Proc., 1989, 87, 1, 13, https://doi.org/10.1016/0168-1176(89)80002-3
. [all data]
Vovna, Dudin, et al., 1980
Vovna, V.I.; Dudin, A.S.; Lopatin, S.N.; Rakov, E.G.,
Photoelectronic spectra of hexafluorides of transition metals with open shells (ReF6 and OsF6),
Koord. Khim., 1980, 6, 1580. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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