Dibromoborane

• Formula: BBr₂H
• Molecular weight: 171.627
• IUPAC Standard InChI: InChI=1S/BBr2H/c2-1-3/h1H Copy

  
• IUPAC Standard InChIKey: WVJGKRMLCSNRKG-UHFFFAOYSA-N Copy
• CAS Registry Number: 13709-65-4
• Chemical structure:
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• Information on this page:
  • Gas phase thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
• Data at other public NIST sites:
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1998, page 238

References

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Lynds and Bass, 1964
Lynds, L.; Bass, C.D., Infrared Spectrum of ν2 of Dibromoborane and Dibromoborane-d, J. Chem. Phys., 1964, 41, 10, 3165, https://doi.org/10.1063/1.1725691 . [all data]

Lynds, Wolfram, et al., 1965
Lynds, L.; Wolfram, T.; Bass, C.D., Infrared Spectrum and Vibrational Analysis of Dibromoborane and Dibromoborane-d, J. Chem. Phys., 1965, 43, 11, 3775, https://doi.org/10.1063/1.1696562 . [all data]

Wason and Porter, 1965
Wason, S.K.; Porter, R.F., None, J. Phys. Chem., 1965, 69, 7, 2461, https://doi.org/10.1021/j100891a502 . [all data]

Miller and Andrews, 1980
Miller, J.H.; Andrews, L., Matrix photoionization and radiolysis of boron trihalides. Infrared and ultraviolet spectra of boron trichloride(1+) and boron tribromide(1+) and infrared spectra of boron dichloride and boron dibromide, J. Am. Chem. Soc., 1980, 102, 15, 4900, https://doi.org/10.1021/ja00535a011 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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