xenon tetrafluoride

• Formula: F₄Xe
• Molecular weight: 207.287
• CAS Registry Number: 13709-61-0
• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to F₄Xe⁺ (ion structure unspecified)

Ionization energy determinations

Appearance energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ogrin, Zemva, et al., 1972
Ogrin, T.; Zemva, B.; Bohinc, M.; slivnik, J., Critical constants and liquid densities of xenon difluoride and xenon tetrafluoride, J. Chem. Eng. Data, 1972, 17, 418-9. [all data]

House, 1983
House, J.E., Cohesion energies and solubility parameters for xenon difluoride and xenon tetrafluoride, Journal of Fluorine Chemistry, 1983, 22, 3, 299-303, https://doi.org/10.1016/S0022-1139(00)84959-3 . [all data]

Brundle, Jones, et al., 1971
Brundle, C.R.; Jones, G.R.; Basch, H., He I and He II photoelectron spectra and the electronic structures of XeF₂, XeF₄, and XeF₆, J. Chem. Phys., 1971, 55, 1098. [all data]

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Guyon, P.M.; Holloway, J.H.; Spohr, R., Photoionization mass spectrometric study of XeF₂, XeF₄, and XeF₆, J. Phys. Chem., 1971, 75, 1461. [all data]

Svec and Flesch, 1963
Svec, H.J.; Flesch, G.D., Thermochemical properties of xenon difluoride and xenon tetrafluoride from massspectra, Science, 1963, 142, 954. [all data]

Nielsen and Schwarz, 1976
Nielsen, U.; Schwarz, W.H.E., VUV spectra of the xenon fluorides, Chem. Phys., 1976, 13, 195. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  IE (evaluated)	Recommended ionization energy
  Pc	Critical pressure
  Tc	Critical temperature
  Ttriple	Triple point temperature
  ΔvapH	Enthalpy of vaporization
  ρc	Critical density

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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