trifluorooxovanadium
- Formula: F3OV
- Molecular weight: 123.9361
- CAS Registry Number: 13709-31-4
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 3.10 ± 0.40 | IMRB | Flesch and Svec, 1975 | EA: > VOF2-, < F-; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 13.88 ± 0.05 | EI | Flesch and Svec, 1975 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| OFV+ | 19.92 ± 0.06 | 2F | EI | Flesch and Svec, 1975 | LLK |
| FV+ | 25.75 ± 0.26 | 2F+O | EI | Flesch and Svec, 1975 | LLK |
| OF2V+ | 15.31 ± 0.06 | F | EI | Flesch and Svec, 1975 | LLK |
| F2V+ | 20.83 ± 0.19 | F+O | EI | Flesch and Svec, 1975 | LLK |
| F3V+ | 16.76 ± 0.05 | O | EI | Flesch and Svec, 1975 | LLK |
| OV+ | 24.41 ± 0.10 | 3F | EI | Flesch and Svec, 1975 | LLK |
| V+ | 31.26 ± 0.19 | 3F+O | EI | Flesch and Svec, 1975 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Flesch and Svec, 1975
Flesch, G.D.; Svec, H.J.,
Thermochemistry of vanadium oxytrichloride and vanadium oxytrifluoride by mass spectrometry,
Inorg. Chem., 1975, 14, 1817. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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