Xenon hexafluoride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
≥11.96PEBrundle, Jones, et al., 1971LLK
12.19 ± 0.02PIBerkowitz, Chupka, et al., 1971LLK
12.35SNielsen and Schwarz, 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
XeF3+15.93FPIBerkowitz, Chupka, et al., 1971LLK
XeF4+15.67 ± 0.052FPIBerkowitz, Chupka, et al., 1971LLK
XeF5+12.56FPIBerkowitz, Chupka, et al., 1971LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brundle, Jones, et al., 1971
Brundle, C.R.; Jones, G.R.; Basch, H., He I and He II photoelectron spectra and the electronic structures of XeF2, XeF4, and XeF6, J. Chem. Phys., 1971, 55, 1098. [all data]

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Guyon, P.M.; Holloway, J.H.; Spohr, R., Photoionization mass spectrometric study of XeF2, XeF4, and XeF6, J. Phys. Chem., 1971, 75, 1461. [all data]

Nielsen and Schwarz, 1976
Nielsen, U.; Schwarz, W.H.E., VUV spectra of the xenon fluorides, Chem. Phys., 1976, 13, 195. [all data]


Notes

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