Plutonium hexafluoride
- Formula: F6Pu
- Molecular weight: 358
- CAS Registry Number: 13693-06-6
- Information on this page:
- Options:
Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| FPu+ | 33.9 ± 0.5 | 5F | EI | Kleinschmidt, 1988 | LL |
| FPu+ | 32.8 | ? | EI | Kleinschmidt and Ward, 1986 | LBLHLM |
| F2Pu+ | 27.2 ± 0.5 | 4F | EI | Kleinschmidt, 1988 | LL |
| F2Pu+ | 27.7 | ? | EI | Kleinschmidt and Ward, 1986 | LBLHLM |
| F3Pu+ | 22.7 ± 0.5 | 3F | EI | Kleinschmidt, 1988 | LL |
| F3Pu+ | 22.7 | ? | EI | Kleinschmidt and Ward, 1986 | LBLHLM |
| F3Pu+ | 24.1 | ? | EI | Kleinschmidt and Ward, 1986 | LBLHLM |
| F4Pu+ | 19.6 ± 0.1 | 2F | EI | Kleinschmidt, 1988 | LL |
| F4Pu+ | 18.5 | ? | EI | Kleinschmidt and Ward, 1986 | LBLHLM |
| F4Pu+ | 20.5 | ? | EI | Kleinschmidt and Ward, 1986 | LBLHLM |
| F5Pu+ | 16.8 ± 0.2 | F | EI | Kleinschmidt, 1988 | LL |
| F5Pu+ | 17.4 | F | EI | Kleinschmidt and Ward, 1986 | LBLHLM |
| Pu+ | 40.8 ± 1.0 | 6F | EI | Kleinschmidt, 1988 | LL |
| Pu+ | 39.2 | ? | EI | Kleinschmidt and Ward, 1986 | LBLHLM |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kleinschmidt, 1988
Kleinschmidt, P.D.,
Thermochemistry of the plutonium fluorides from electron impact studies,
J. Chem. Phys., 1988, 89, 6897. [all data]
Kleinschmidt and Ward, 1986
Kleinschmidt, P.D.; Ward, J.W.,
Thermochemical studies on the plutonium fluorides and protactinium oxides,
J. Less-Common Met., 1986, 121, 61. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.