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Chloryl fluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
>2.29999EIAEAlekseev, Fedorova, et al., 1983From ClO3F; G3MP2B3 calculations indicate an EA of ca. 1.1 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
12.41 ± 0.10EIBaluev, Nikitina, et al., 1980LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ClO+13.41 ± 0.08?EIBaluev, Nikitina, et al., 1980LLK
ClO2+13.15 ± 0.08FEIBaluev, Nikitina, et al., 1980LLK
O2+12.16 ± 0.05?EIBaluev, Nikitina, et al., 1980LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Alekseev, Fedorova, et al., 1983
Alekseev, V.I.; Fedorova, L.I.; Baluev, A.V., Mass Spectrometric Study of Thermochemical Characteristics of Perchloryl Fluoride and its Decomposition Product Chlorosyl Fluoride, Izv. Akad. Nauk SSR Ser. Khim. 1084, 1983. [all data]

Baluev, Nikitina, et al., 1980
Baluev, A.V.; Nikitina, Z.K.; Fedorova, L.I.; Rosolovskii, V.Ya., Mass spectrometric investigation of electron-impact induced ionization of chlorine dioxide and chloryl fluoride molecules, Izv. Akad. Nauk SSSR, Ser. Khim., 1980, 1963. [all data]


Notes

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