Manganese, pentacarbonylmethyl-
- Formula: C6H3MnO5
- Molecular weight: 210.0231
- IUPAC Standard InChIKey: KJJLHDHVFFAISC-UHFFFAOYSA-N
- CAS Registry Number: 13601-24-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Manganese, pentacarbonylmethyl-, (OC-6-21)-; Methyl pentacarbonylmanganese; Methylmanganese pentacarbonyl; Pentacarbonylmethylmanganese; CH3(CO)5Mn
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 764.4 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 735.4 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.4 | PE | Lichtenberger and Fenski, 1974 | LLK |
8.65 | PE | Lichtenberger and Fenski, 1974 | Vertical value; LLK |
8.46 | PE | Evans, Green, et al., 1969 | Vertical value; RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Lichtenberger and Fenski, 1974
Lichtenberger, D.I.; Fenski, R.F.,
Assignment of the photoelectron spectra of Mn(CO)5CH3 and Mn(CO)5CF3,
Inorg. Chem., 1974, 13, 486. [all data]
Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W.,
Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy,
Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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