Manganese, pentacarbonyl(trifluoromethyl)-
- Formula: C6F3MnO5
- Molecular weight: 263.9945
- CAS Registry Number: 13601-14-4
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -330.8 ± 5.2 | kcal/mol | Review | Martinho Simões | |
| ΔfH°gas | -330.5 ± 1.1 | kcal/mol | Review | Martinho Simões | Selected data |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -349.4 ± 5.2 | kcal/mol | Review | Martinho Simões | |
| ΔfH°solid | -349.1 ± 1.1 | kcal/mol | Review | Martinho Simões | Selected data |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.8 | PE | Lichtenberger and Fenski, 1974 | LLK |
| 9.17 | PE | Lichtenberger and Fenski, 1974 | Vertical value; LLK |
| 9.20 | PE | Evans, Green, et al., 1969 | Vertical value; RDSH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Lichtenberger and Fenski, 1974
Lichtenberger, D.I.; Fenski, R.F.,
Assignment of the photoelectron spectra of Mn(CO)5CH3 and Mn(CO)5CF3,
Inorg. Chem., 1974, 13, 486. [all data]
Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W.,
Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy,
Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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