Aluminum monofluoride


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-63.499kcal/molReviewChase, 1998Data last reviewed in September, 1979
Quantity Value Units Method Reference Comment
gas,1 bar51.401cal/mol*KReviewChase, 1998Data last reviewed in September, 1979

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 6000.
A 8.487410
B 0.548945
C -0.161092
D 0.019665
E -0.092069
F -66.36860
G 60.99661
H -63.50010
ReferenceChase, 1998
Comment Data last reviewed in September, 1979

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.73 ± 0.01PEDyke, Kirby, et al., 1984LBLHLM
9.8EVALHuber and Herzberg, 1979LLK
9.86 ± 0.05SBarrow, Kopp, et al., 1974LLK
9.EIUy, Srivastava, et al., 1972LLK
9.2EIHildenbrand and Murad, 1966RDSH
8.9 ± 0.6EIHildenbrand and Theard, 1965RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Al+9.2 ± 0.3F-?EIEhlert and Margrave, 1964RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Dyke, Kirby, et al., 1984
Dyke, J.M.; Kirby, C.; Morris, A.; Gravenor, B.W.J.; Klein, R.; Rosmus, P., A study of aluminium monofluoride and aluminium trifluoride by high-temperature photoelectron spectroscopy, Chem. Phys., 1984, 88, 289. [all data]

Huber and Herzberg, 1979
Huber, K.P.; Herzberg, G., Molecular Spectra and Molecular Structure. IV. Constants of Diatomic Molecules,, Van Nostrand Reinhold Co., 1979, ,1. [all data]

Barrow, Kopp, et al., 1974
Barrow, R.F.; Kopp, I.; Malmberg, C., The electronic spectrum of gaseous AlF, Phys. Scr., 1974, 10, 86. [all data]

Uy, Srivastava, et al., 1972
Uy, O.M.; Srivastava, R.D.; Farber, M., Mass spectrometric determination of the heats of formation of the gaseous molecules AlOF2 and AlF2, High Temp. Sci., 1972, 4, 227. [all data]

Hildenbrand and Murad, 1966
Hildenbrand, D.L.; Murad, E., Mass-spectrometric determination of the dissociation energy of beryllium monofluoride, J. Chem. Phys., 1966, 44, 1524. [all data]

Hildenbrand and Theard, 1965
Hildenbrand, D.L.; Theard, L.P., Effusion studies, mass spectra, and thermodynamics of beryllium fluoride vapor, J. Chem. Phys., 1965, 42, 3230. [all data]

Ehlert and Margrave, 1964
Ehlert, T.C.; Margrave, J.L., The heat of atomization of aluminum difluoride, J. Am. Chem. Soc., 1964, 86, 3901. [all data]


Notes

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