Aluminum difluoride
- Formula: AlF2
- Molecular weight: 64.9783450
- CAS Registry Number: 13569-23-8
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
View reactions leading to AlF2+ (ion structure unspecified)
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
2.25 ± 0.13 | TDEq | Srivastava, Uy, et al., 1974 | EA: 26.5 kcal < EA(F), new EA(F) data used; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10. | EI | Uy, Srivastava, et al., 1972 | LLK |
9. ± 1. | EI | Ehlert and Margrave, 1964 | RDSH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Srivastava, Uy, et al., 1974
Srivastava, R.D.; Uy, O.M.; Farber, M.,
Experimental determination of heats of formation of negative ions and electron affinities of several boron and aluminum fluorides,
J. Chem. Soc. Faraday Trans. 1, 1974, 70, 1033. [all data]
Uy, Srivastava, et al., 1972
Uy, O.M.; Srivastava, R.D.; Farber, M.,
Mass spectrometric determination of the heats of formation of the gaseous molecules AlOF2 and AlF2,
High Temp. Sci., 1972, 4, 227. [all data]
Ehlert and Margrave, 1964
Ehlert, T.C.; Margrave, J.L.,
The heat of atomization of aluminum difluoride,
J. Am. Chem. Soc., 1964, 86, 3901. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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