Fluorogermane
- Formula: FGeH3
- Molecular weight: 94.66
- IUPAC Standard InChI: InChI=1S/FGeH3/c1-2/h2H3
- IUPAC Standard InChIKey: BCQKCDCVNZQJKN-UHFFFAOYSA-N
- CAS Registry Number: 13537-30-9
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 12.3 ± 0.1 | PE | Cradock and Whiteford, 1971 | Vertical value |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Takehiko Shimanouchi
Symmetry: C3ν Symmetry Number σ = 3
| Sym. | No | Approximate | Selected Freq. | Infrared | Raman | Comments | ||||
|---|---|---|---|---|---|---|---|---|---|---|
| Species | type of mode | Value | Rating | Value | Phase | Value | Phase | |||
| a1 | 1 | GeH3 s-str | 2121 | C | 2120.6 S | gas | ||||
| a1 | 2 | GeH3 s-deform | 859 | C | 859.0 VS | gas | ||||
| a1 | 3 | GeF str | 689 | B | 689.1 S | gas | ||||
| e | 4 | GeH3 d-str | 2132 | B | 2131.7 S | gas | ||||
| e | 5 | GeH3 d-deform | 874 | B | 874.0 S | gas | ||||
| e | 6 | GeH3 rock | 643 | B | 642.6 M | gas | ||||
Source: Shimanouchi, 1972
Notes
| VS | Very strong |
| S | Strong |
| M | Medium |
| B | 1~3 cm-1 uncertainty |
| C | 3~6 cm-1 uncertainty |
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cradock and Whiteford, 1971
Cradock, S.; Whiteford, R.A.,
Photo-electron spectra of the mono and dihalo silanes and germanes,
J. Chem. Soc. Faraday Trans., 1971, 67, 3425. [all data]
Shimanouchi, 1972
Shimanouchi, T.,
Tables of Molecular Vibrational Frequencies Consolidated Volume II,
J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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