Copper monofluoride
- Formula: CuF
- Molecular weight: 82.544
- IUPAC Standard InChI: InChI=1S/Cu.FH/h;1H/q+1;/p-1
- IUPAC Standard InChIKey: BMRUOURRLCCWHB-UHFFFAOYSA-M
- CAS Registry Number: 13478-41-6
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to CuF+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.8 | EI | Hildenbrand and Lau, 1991 | LL |
| 10.15 ± 0.02 | PE | Dyke, Fayad, et al., 1980 | LLK |
| 10.5 ± 0.3 | EI | Hastie and Margrave, 1968 | Unpublished result of D.L.Hildenbrand; RDSH |
| 8.6 ± 0.3 | EI | Kent, McDonald, et al., 1966 | RDSH |
| 10.90 ± 0.01 | PE | Dyke, Fayad, et al., 1980 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hildenbrand and Lau, 1991
Hildenbrand, D.L.; Lau, K.H.,
Redetermination of the thermochemistry of gaseous UF5, UF2, and UF,
J. Chem. Phys., 1991, 94, 1420. [all data]
Dyke, Fayad, et al., 1980
Dyke, J.M.; Fayad, N.K.; Josland, G.D.; Morris, A.,
Study by high-temperature photoelectron spectroscopy of the electronic structure of the transition metal difluorides, CuF2 and ZnF2,
J. Chem. Soc. Faraday Trans. 2, 1980, 76, 1672. [all data]
Hastie and Margrave, 1968
Hastie, J.W.; Margrave, J.L.,
Ionization potentials and molecule-ion dissociation energies for diatomic metal halides,
Fluorine Chem. Rev., 1968, 2, 77. [all data]
Kent, McDonald, et al., 1966
Kent, R.A.; McDonald, J.D.; Margrave, J.L.,
Mass spectrometric studies at high temperatures. IX. The sublimation pressure of copper(II) fluoride,
J. Phys. Chem., 1966, 70, 874. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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