Hexachlorodisilane
- Formula: Cl6Si2
- Molecular weight: 268.889
- IUPAC Standard InChIKey: LXEXBJXDGVGRAR-UHFFFAOYSA-N
- CAS Registry Number: 13465-77-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Si2Cl6; Disilane, hexachloro-
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.0 ± 0.3 | EI | Ihle, Wu, et al., 1978 | LLK |
10.4 | PE | Potzinger, Ritter, et al., 1975 | LLK |
10.91 | PE | Khvostenko, Zykov, et al., 1981 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
Cl3Si+ | 11.4 ± 0.1 | SiCl3 | EI | Potzinger, Ritter, et al., 1975 | LLK |
SiCl3+ | 11.6 ± 0.1 | SiCl3 | EI | Steele and Stone, 1962 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ihle, Wu, et al., 1978
Ihle, H.R.; Wu, C.H.; Miletic, M.; Zmbov, K.F.,
Mass spectrometric studies of gas species in the systems Si-Cl and Si-Li,
Adv. Mass Spectrom., 1978, 7, 670. [all data]
Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J.,
Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen,
Z. Naturforsch. A:, 1975, 30, 347. [all data]
Khvostenko, Zykov, et al., 1981
Khvostenko, V.I.; Zykov, B.G.; Yuriev, V.P.; Mironov, V.F.; Kovel'zon, G.I.; Panasenko, A.A.; Sheludyakov, V.D.; Gailyunas, I.A.,
Study of d(π)-p(π) interaction in vinyl- and alkylsilicon-containing compounds by photoelectron spectroscopy,
J. Organomet. Chem., 1981, 218, 155. [all data]
Steele and Stone, 1962
Steele, W.C.; Stone, F.G.A.,
Silicon-silicon bond dissociation energies in disilane and hexachlorodisilane,
J. Am. Chem. Soc., 1962, 84, 3599. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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