3-Hexene, (E)-
- Formula: C6H12
- Molecular weight: 84.1595
- IUPAC Standard InChIKey: ZQDPJFUHLCOCRG-AATRIKPKSA-N
- CAS Registry Number: 13269-52-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: (E)-3-Hexene; trans-3-Hexene; (E)-3-C6H12; trans-hex-3-ene
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Donald R. Burgess, Jr.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -49.3 ± 1.0 | kJ/mol | Chyd | Rogers, Crooks, et al., 1987 | Value computed using ΔfHliquid° from Rogers, Crooks, et al., 1987 and ΔvapH° value of 31.5 kJ/mol from Steele and Chirico, 1993. |
ΔfH°gas | -49.3 ± 1.1 | kJ/mol | Chyd | Rogers and Crooks, 1983 | Value computed using ΔfHliquid° from Rogers and Crooks, 1983 and ΔvapH° value of 31.5 kJ/mol from Steele and Chirico, 1993. |
ΔfH°gas | -51.5 | kJ/mol | N/A | Wiberg and Wasserman, 1981 | Value computed using ΔfHliquid° value of -82.13±0.84 kj/mol from Wiberg and Wasserman, 1981 and ΔvapH° value of 30.7 kj/mol from alkenes correlation. |
ΔfH°gas | -50.6 ± 0.8 | kJ/mol | Eqk | Wiberg and Wasserman, 1981 | Value computed using ΔfHliquid° from Wiberg and Wasserman, 1981 and ΔvapH° value of 31.5 kJ/mol from Steele and Chirico, 1993. |
ΔfH°gas | -57.4 ± 1.8 | kJ/mol | Chyd | Rogers, Papadimetriou, et al., 1975 | Value computed using ΔfHliquid° from Rogers, Papadimetriou, et al., 1975 and ΔvapH° value of 31.5 kJ/mol from Steele and Chirico, 1993. |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -80.8 ± 1.0 | kJ/mol | Chyd | Rogers, Crooks, et al., 1987 | DRB |
ΔfH°liquid | -80.8 ± 1.1 | kJ/mol | Chyd | Rogers and Crooks, 1983 | DRB |
ΔfH°liquid | -82.13 ± 0.84 | kJ/mol | Eqk | Wiberg and Wasserman, 1981 | ALS |
ΔfH°liquid | -88.9 ± 1.8 | kJ/mol | Chyd | Rogers, Papadimetriou, et al., 1975 | DRB |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 340.2 ± 0.7 | K | AVG | N/A | Average of 13 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 159.6 ± 0.7 | K | AVG | N/A | Average of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 31.6 | kJ/mol | N/A | Reid, 1972 | AC |
ΔvapH° | 31.5 | kJ/mol | V | Camin and Rossini, 1956 | ALS |
ΔvapH° | 31.5 | kJ/mol | N/A | Pennington, Scott, et al., 1956 | Based on data from 291. to 341. K.; AC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
32.3 | 293. | A | Stephenson and Malanowski, 1987 | Based on data from 278. to 341. K.; AC |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: C6H12 + H2 = C6H14
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -117.9 ± 0.73 | kJ/mol | Chyd | Rogers, Crooks, et al., 1987 | liquid phase |
ΔrH° | -117.9 ± 0.82 | kJ/mol | Chyd | Rogers and Crooks, 1983 | liquid phase; solvent: Hexane |
ΔrH° | -109.8 ± 1.7 | kJ/mol | Chyd | Rogers, Papadimetriou, et al., 1975 | liquid phase; solvent: Hexane |
By formula: C6H12 = C6H12
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -9.77 ± 0.15 | kJ/mol | Eqk | Wiberg and Wasserman, 1981 | liquid phase; Trifluoroacetolysis |
ΔrH° | -13.7 ± 0.96 | kJ/mol | Ciso | Bartolo and Rossini, 1960 | liquid phase; Calculated from ΔHc |
By formula: C6H12 + C2HF3O2 = C8H13F3O2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -40.90 ± 0.13 | kJ/mol | Eqk | Wiberg and Wasserman, 1981 | liquid phase; Trifluoroacetolysis |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to C6H12+ (ion structure unspecified)
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.83 ± 0.02 | PE | Ashmore and Burgess, 1978 | LLK |
8.97 | EI | Lossing and Traeger, 1975 | LLK |
8.965 ± 0.005 | PE | Masclet, Grosjean, et al., 1973 | LLK |
8.95 ± 0.01 | PI | Demeo and El-Sayed, 1970 | RDSH |
9.14 ± 0.01 | PE | Krause, Taylor, et al., 1978 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C5H9+ | 8.97 | CH3 | EI | Lossing and Traeger, 1975, 2 | LLK |
C5H9+ | ≤10.39 | CH3 | EI | Lossing and Traeger, 1975 | LLK |
Gas Chromatography
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | Methyl Silicone | 30. | 603.2 | Soják, Addová, et al., 2002 | He; Column length: 150. m; Column diameter: 0.250 mm |
Capillary | Squalane | 30. | 592.1 | Soják, Addová, et al., 2002 | He; Column length: 93. m; Column diameter: 0.250 mm |
Capillary | Squalane | 100. | 591. | Heinzen, Soares, et al., 1999 | |
Capillary | OV-101 | 40. | 601. | Laub and Purnell, 1988 | |
Capillary | OV-101 | 60. | 601. | Laub and Purnell, 1988 | |
Capillary | OV-101 | 80. | 600. | Laub and Purnell, 1988 | |
Capillary | OV-101 | 50. | 602.8 | Boneva and Dimov, 1986 | 100. m/0.27 mm/0.9 μm, N2 |
Capillary | OV-101 | 70. | 602.4 | Boneva and Dimov, 1986 | 100. m/0.27 mm/0.9 μm, N2 |
Capillary | Squalane | 50. | 592.5 | Boneva and Dimov, 1986 | N2; Column length: 100. m; Column diameter: 0.25 mm |
Capillary | Squalane | 70. | 591.9 | Boneva and Dimov, 1986 | N2; Column length: 100. m; Column diameter: 0.25 mm |
Capillary | DB-1 | 40. | 602. | Lubeck and Sutton, 1984 | 60. m/0.264 mm/0.25 μm, H2 |
Capillary | HP-PONA | 40. | 602. | Lubeck and Sutton, 1984 | 50. m/0.21 mm/0.5 μm, H2 |
Capillary | OV-101 | 30. | 602. | Chien, Furio, et al., 1983 | |
Capillary | OV-101 | 40. | 601. | Chien, Furio, et al., 1983 | |
Capillary | OV-101 | 50. | 601. | Chien, Furio, et al., 1983 | |
Capillary | OV-101 | 60. | 601. | Chien, Furio, et al., 1983 | |
Capillary | OV-101 | 70. | 600. | Chien, Furio, et al., 1983 | |
Capillary | OV-101 | 80. | 600. | Chien, Furio, et al., 1983 | |
Capillary | OV-3 | 30. | 606.9 | Chien, Furio, et al., 1983, 2 | |
Capillary | OV-3 | 40. | 606.6 | Chien, Furio, et al., 1983, 2 | |
Capillary | OV-3 | 50. | 606.3 | Chien, Furio, et al., 1983, 2 | |
Capillary | OV-3 | 60. | 605.9 | Chien, Furio, et al., 1983, 2 | |
Capillary | OV-3 | 70. | 605.5 | Chien, Furio, et al., 1983, 2 | |
Capillary | OV-3 | 80. | 605.2 | Chien, Furio, et al., 1983, 2 | |
Capillary | OV-1 | 30. | 602.3 | Chien, Kopecni, et al., 1981 | H2 |
Capillary | OV-1 | 40. | 602.3 | Chien, Kopecni, et al., 1981 | H2 |
Capillary | OV-1 | 50. | 602.2 | Chien, Kopecni, et al., 1981 | H2 |
Capillary | OV-1 | 60. | 602.2 | Chien, Kopecni, et al., 1981 | H2 |
Capillary | OV-1 | 70. | 602.3 | Chien, Kopecni, et al., 1981 | H2 |
Capillary | OV-1 | 80. | 602.2 | Chien, Kopecni, et al., 1981 | H2 |
Capillary | SE-30 | 30. | 604. | Chien, Kopecni, et al., 1981 | H2 |
Capillary | SE-30 | 40. | 603.2 | Chien, Kopecni, et al., 1981 | H2 |
Capillary | SE-30 | 50. | 602. | Chien, Kopecni, et al., 1981 | H2 |
Capillary | SE-30 | 60. | 601. | Chien, Kopecni, et al., 1981 | H2 |
Capillary | SE-30 | 70. | 599.7 | Chien, Kopecni, et al., 1981 | H2 |
Capillary | SE-30 | 80. | 598.6 | Chien, Kopecni, et al., 1981 | H2 |
Capillary | Squalane | 50. | 592.1 | Bajus, Veselý, et al., 1979 | Column length: 100. m; Column diameter: 0.25 mm |
Capillary | Squalane | 70. | 591.7 | Bajus, Veselý, et al., 1979 | Column length: 100. m; Column diameter: 0.25 mm |
Capillary | Squalane | 50. | 592.4 | Bajus, Veselý, et al., 1979, 2 | Column length: 100. m; Column diameter: 0.25 mm |
Capillary | Squalane | 70. | 591.8 | Bajus, Veselý, et al., 1979, 2 | Column length: 100. m; Column diameter: 0.25 mm |
Packed | Squalane | 80. | 592. | Chrétien and Dubois, 1977 | |
Capillary | Squalane | 50. | 592. | Chretien and Dubois, 1976 | |
Capillary | Squalane | 100. | 592.2 | Lulova, Leont'eva, et al., 1976 | He; Column length: 120. m; Column diameter: 0.25 mm |
Capillary | Squalane | 50. | 592. | Rijks and Cramers, 1974 | N2; Column length: 100. m; Column diameter: 0.25 mm |
Capillary | Squalane | 70. | 592. | Rijks and Cramers, 1974 | N2; Column length: 100. m; Column diameter: 0.25 mm |
Capillary | Squalane | 27. | 592.27 | Schomburg and Dielmann, 1973 | Column length: 100. m; Column diameter: 0.25 mm |
Capillary | Squalane | 100. | 591. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Squalane | 115. | 591. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Squalane | 86. | 591. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Apiezon L | 100. | 595.8 | Eisen, Orav, et al., 1972 | Column length: 45. m; Column diameter: 0.25 mm |
Capillary | Squalane | 50. | 592.7 | Eisen, Orav, et al., 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | Squalane | 60. | 593. | Orav and Eisen, 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | Squalane | 115. | 590.6 | Soják and Bucinská, 1970 | N2; Column length: 200. m; Column diameter: 0.2 mm |
Capillary | Squalane | 86. | 591.4 | Soják and Bucinská, 1970 | N2; Column length: 200. m; Column diameter: 0.2 mm |
Capillary | Squalane | 40. | 595. | Matukuma, 1969 | N2; Column length: 91.4 m; Column diameter: 0.25 mm |
Packed | Squalane | 27. | 594. | Hively and Hinton, 1968 | He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm |
Packed | Squalane | 49. | 593. | Hively and Hinton, 1968 | He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm |
Packed | Squalane | 67. | 593. | Hively and Hinton, 1968 | He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm |
Packed | Squalane | 86. | 592. | Hively and Hinton, 1968 | He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm |
Capillary | Squalane | 70. | 593. | Schomburg, 1967 | Ar; Column length: 100. m |
Packed | SE-30 | 70. | 602. | Widmer, 1967 | Diatoport S; Column length: 7.9 m |
Packed | Squalane | 26. | 595. | Zulaïca and Guiochon, 1966 | Column length: 10. m |
Kovats' RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Petrocol DH-100 | 603. | Haagen-Smit Laboratory, 1997 | He; Column length: 100. m; Column diameter: 0.2 mm; Program: 5C(10min) => 5C/min => 50C(48min) => 1.5C/min => 195C(91min) |
Capillary | DB-1 | 604. | Hoekman, 1993 | 60. m/0.32 mm/1.0 μm, He; Program: -40 C for 12 min; -40 - 125 C at 3 deg.min; 125-185 C at 6 deg/min; 185 - 220 C at 20 deg/min; hold 220 C for 2 min |
Kovats' RI, polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | PEG 4000 | 50. | 656. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 60. | 656. | Rang, Orav, et al., 1988 | |
Capillary | Polyethylene Glycol 4000 | 50. | 656.4 | Eisen, Orav, et al., 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | Polyethylene Glycol 4000 | 60. | 655.6 | Eisen, Orav, et al., 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | PEG 4000 | 60. | 655.6 | Orav and Eisen, 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | PEG 4000 | 50. | 656.4 | Orav and Eisen, 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Packed | Carbowax 20M | 130. | 643. | Widmer, 1967 | Diatoport P; Column length: 7.9 m |
Packed | Carbowax 20M | 70. | 633. | Widmer, 1967 | Diatoport P; Column length: 7.9 m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Methyl Silicone | 603.2 | Soják, Addová, et al., 2002 | He, 1. K/min; Column length: 150. m; Column diameter: 0.250 mm; Tstart: 30. C; Tend: 200. C |
Capillary | Ultra-1 | 604. | Olson, Sinkevitch, et al., 1992 | 4. K/min; Tstart: -40. C; Tend: 230. C |
Capillary | Petrocol DH | 601.03 | White, Douglas, et al., 1992 | 100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C |
Capillary | Petrocol DH | 601.42 | White, Douglas, et al., 1992 | 100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C |
Capillary | Petrocol DH | 601. | White, Hackett, et al., 1992 | 100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C |
Van Den Dool and Kratz RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-Wax | 640. | Chung, Eiserich, et al., 1994 | He, 60. C @ 4. min, 3. K/min, 220. C @ 30. min; Column length: 60. m; Column diameter: 0.25 mm |
Normal alkane RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | Squalane | 40. | 592.2 | Sojak, Addova, et al., 2000 | He; Column length: 93. m; Column diameter: 0.25 mm |
Capillary | OV-101 | 40. | 592. | Li and Deng, 1998 | N2; Column length: 51. m; Column diameter: 0.25 mm |
Capillary | Methyl Silicone | 40. | 596. | Meng and Liu, 1991 | 115. m/0.20 mm/0.30 μm |
Capillary | Methyl Silicone | 50. | 592. | N/A | N2; Column length: 74.6 m; Column diameter: 0.28 mm |
Capillary | Squalane | 70. | 593. | Schomburg, 1966 |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Polydimethyl siloxane: CP-Sil 5 CB | 603. | Bramston-Cook, 2013 | 60. m/0.25 mm/1.0 μm, Helium, 45. C @ 1.45 min, 3.6 K/min, 210. C @ 2.72 min |
Capillary | Petrocol DH | 601. | Supelco, 2012 | 100. m/0.25 mm/0.50 μm, Helium, 20. C @ 15. min, 15. K/min, 220. C @ 30. min |
Capillary | PONA | 602. | Zhang, Ding, et al., 2009 | 50. m/0.20 mm/0.50 μm, Nitrogen, 35. C @ 15. min, 2. K/min, 200. C @ 10. min |
Capillary | SE-54 | 602. | Guan, Li, et al., 1995 | 60. C @ 2. min, 4. K/min; Column length: 50. m; Column diameter: 0.32 mm; Tend: 200. C |
Capillary | DB-1 | 602. | Ramnas, Ostermark, et al., 1994 | 50. m/0.32 mm/1.0 μm, He, 2. K/min; Tstart: -20. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Polydimethyl siloxane | 591. | Junkes, Castanho, et al., 2003 | Program: not specified |
Capillary | PONA | 603. | Perkin Elmer Instruments, 2002 | Column length: 100. m; Phase thickness: 0.50 μm; Program: not specified |
Capillary | Methyl Silicone | 603. | Zenkevich and Marinichev, 2001 | Program: not specified |
Capillary | Methyl Silicone | 603. | Spieksma, 1999 | Program: not specified |
Capillary | SE-54 | 604. | Zhu and He, 1999 | Program: not specified |
Capillary | SE-54 | 604. | Zhu and He, 1999 | Program: not specified |
Capillary | Methyl Silicone | 597. | Meng and Liu, 1991 | 115. m/0.20 mm/0.30 μm; Program: not specified |
Packed | SE-30 | 600. | Robinson and Odell, 1971 | N2, Chromosorb W; Column length: 6.1 m; Program: 50C910min) => 20C/min => 90(6min) => 10C/min => 150C(hold) |
Packed | Squalane | 593. | Robinson and Odell, 1971 | N2, Embacel; Column length: 3.0 m; Program: 25C(5min) => 2C/min => 35 => 4C/min => 95C(hold) |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rogers, Crooks, et al., 1987
Rogers, D.W.; Crooks, E.; Dejroongruang, K.,
Enthalpies of hydrogenation of the hexenes,
J. Chem. Thermodyn., 1987, 19, 1209-1215. [all data]
Steele and Chirico, 1993
Steele, W.V.; Chirico, R.D.,
Thermodynamic properties of alkenes (mono-olefins larger than C4),
J. Phys. Chem. Ref. Data, 1993, 22, 377-430. [all data]
Rogers and Crooks, 1983
Rogers, D.W.; Crooks, E.L.,
Enthalpies of hydrogenation of the isomers of n-hexene,
J. Chem. Thermodyn., 1983, 15, 1087-1092. [all data]
Wiberg and Wasserman, 1981
Wiberg, K.B.; Wasserman, D.J.,
Enthalpies of hydration of alkenes. 1. The n-hexenes,
J. Am. Chem. Soc., 1981, 103, 6563-6566. [all data]
Rogers, Papadimetriou, et al., 1975
Rogers, D.W.; Papadimetriou, P.M.; Siddiqui, N.A.,
An improved hydrogen microcalorimeter for use with large molecules,
Mikrochim. Acta, 1975, 2, 389-400. [all data]
Reid, 1972
Reid, Robert C.,
Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00,
AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637
. [all data]
Camin and Rossini, 1956
Camin, D.L.; Rossini, F.D.,
Physical properties of the 17 isomeric hexenes of the API research series,
J. Phys. Chem., 1956, 60, 1446. [all data]
Pennington, Scott, et al., 1956
Pennington, R.E.; Scott, D.W.; Finke, H.L.; McCullough, J.P.; Messerly, J.F.; Hossenlopp, I.A.; Waddington, G.,
The chemical thermodynamic properties and rotational tautomerism of 1-propanethiol,
J. Am. Chem. Soc., 1956, 78, 3266-3272. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Bartolo and Rossini, 1960
Bartolo, H.F.; Rossini, F.D.,
Heats of isomerization of the seventeen isomeric hexenes,
J. Phys. Chem., 1960, 64, 1685-1689. [all data]
Ashmore and Burgess, 1978
Ashmore, F.S.; Burgess, A.R.,
Photoelectron spectra of the unbranched C5-C7 alkenes, aldehydes and ketones,
J. Chem. Soc. Faraday Trans. 2, 1978, 74, 734. [all data]
Lossing and Traeger, 1975
Lossing, F.P.; Traeger, J.C.,
Stabilization in cyclopentadienyl, cyclopentenyl, and cyclopentyl cations,
J. Am. Chem. Soc., 1975, 97, 1579. [all data]
Masclet, Grosjean, et al., 1973
Masclet, P.; Grosjean, D.; Mouvier, G.,
Alkene ionization potentials. Part I. Quantitative determination of alkyl group structural effects,
J. Electron Spectrosc. Relat. Phenom., 1973, 2, 225. [all data]
Demeo and El-Sayed, 1970
Demeo, D.A.; El-Sayed, M.A.,
Ionization potential and structure of olefins,
J. Chem. Phys., 1970, 52, 2622. [all data]
Krause, Taylor, et al., 1978
Krause, D.A.; Taylor, J.W.; Fenske, R.F.,
An analysis of the effects of alkyl substituents on the ionization potentials of n-alkenes,
J. Am. Chem. Soc., 1978, 100, 718. [all data]
Lossing and Traeger, 1975, 2
Lossing, F.P.; Traeger, J.C.,
Free radicals by mass spectrometry XLVI. Heats of formation of C5H7 and C5H9 radicals and cations.,
J. Am. Chem. Soc., 1975, 19, 9. [all data]
Soják, Addová, et al., 2002
Soják, L.; Addová, G.; Kubinec, R.; Kraus, A.; Hu, G.,
Gas chromatographic-mass spectrometric characterization of all acyclic C5-C7 alkenes from fluid catalytic cracked gasoline using polydimethylsiloxane and squalane stationary phases,
J. Chromatogr. A, 2002, 947, 1, 103-117, https://doi.org/10.1016/S0021-9673(01)01564-3
. [all data]
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Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Gas Chromatography, References
- Symbols used in this document:
AE Appearance energy Tboil Boiling point Tfus Fusion (melting) point ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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