Bicyclo[2.2.1]heptan-2-one, 3,3-dimethyl-

• Formula: C₉H₁₄O
• Molecular weight: 138.2069
• IUPAC Standard InChI: InChI=1S/C9H14O/c1-9(2)7-4-3-6(5-7)8(9)10/h6-7H,3-5H2,1-2H3 Copy

  
• IUPAC Standard InChIKey: ZYPYEBYNXWUCEA-UHFFFAOYSA-N Copy
• CAS Registry Number: 13211-15-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: 2-Norbornanone, 3,3-dimethyl-; Camphenilone; 3,3-Dimethylnorcamphor; 3,3-Dimethylbicyclo[2.2.1]heptan-2-one
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• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

 +  =  + 2

By formula: C₁₁H₂₀O₂ + H₂O = C₉H₁₄O + 2CH₄O

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C₉H₁₄O⁺ (ion structure unspecified)

Ionization energy determinations

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg and Cunningham, 1990
Wiberg, K.B.; Cunningham, W.C., Jr., Thermochemical studies of carbonyl reactions. 4. Enthalpies of hydrolysis of norbornyl ketals, J. Org. Chem., 1990, 55, 679-684. [all data]

Frost, Westwood, et al., 1980
Frost, D.C.; Westwood, N.P.C.; Werstiuk, N.H., Ultraviolet photoelectron spectra of 2-norbornanone, 2,5-norbornanedione. Their akyl derivatives and thio-analogues. An investigation of transannular interactions by photoelectron spectroscopy, Can. J. Chem., 1980, 58, 1659. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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