1,4-Bis(trimethylsilyl)benzene

• Formula: C₁₂H₂₂Si₂
• Molecular weight: 222.4741
• IUPAC Standard InChI: InChI=1S/C12H22Si2/c1-13(2,3)11-7-9-12(10-8-11)14(4,5)6/h7-10H,1-6H3 Copy

  
• IUPAC Standard InChIKey: NVRBTKMAZQNKPX-UHFFFAOYSA-N Copy
• CAS Registry Number: 13183-70-5
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Silane, 1,4-phenylenebis[trimethyl-; Silane, p-phenylenebis[trimethyl-; p-Bis(trimethylsilyl)benzene; Benzene, p-bis(trimethylsilyl)-; p-Phenylenebis(trimethylsilane); Trimethyl[4-(trimethylsilyl)phenyl]silane
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase ion energetics data
  • IR Spectrum
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
  • UV/Visible spectrum
• Options:
  • Switch to SI units

Gas phase ion energetics data

Go To: Top, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IR Spectrum

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

For Zoom

1.) Enter the desired X axis range (e.g., 100, 200)

2.) Check here for automatic Y scaling

3.) Press here to zoom

Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

References

Go To: Top, Gas phase ion energetics data, IR Spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Traven', Redchenko, et al., 1982
Traven', V.F.; Redchenko, V.V.; Stepanov, B.I., Parameterization of quantum-chemical calculations of organic compounds of silicon by means of photoelectron spectroscopy and the electronic spectroscopy of ctc, J. Gen. Chem. USSR, 1982, 52, 2015, In original 2262. [all data]

Bock and Alt, 1970
Bock, H.; Alt, H., d-Orbital effects in silicon substituted π-electron systems. XXIV. Charge-transfer studies of silyl- and alkylbenzenes, J. Am. Chem. Soc., 1970, 92, 1569. [all data]

Kaim, Tesmann, et al., 1980
Kaim, W.; Tesmann, H.; Bock, H., Me₃C-, Me₃Si-, Me₃Ge-, Me₃Sn- und Me₃Pb-substituierte benzol- und naphthalin-derivate und ihre radikalanionen, Chem. Ber., 1980, 113, 3221. [all data]

Limouzin and Maire, 1976
Limouzin, Y.; Maire, J.C., Spectres photo-electroniques des composes organometalliques, J. Organomet. Chem., 1976, 105, 179. [all data]

Notes

Go To: Top, Gas phase ion energetics data, IR Spectrum, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.