lead sulphide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas31.501kcal/molReviewChase, 1998Data last reviewed in June, 1973
Quantity Value Units Method Reference Comment
gas,1 bar60.088cal/mol*KReviewChase, 1998Data last reviewed in June, 1973

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 2000. to 6000.
A 18.61410
B -7.115720
C 1.803761
D -0.121947
E -5.991109
F 16.39430
G 74.22801
H 31.50000
ReferenceChase, 1998
Comment Data last reviewed in June, 1973

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-20.09kcal/molReviewChase, 1998Data last reviewed in June, 1973
Quantity Value Units Method Reference Comment
liquid,1 bar24.089cal/mol*KReviewChase, 1998Data last reviewed in June, 1973
Quantity Value Units Method Reference Comment
Δfsolid-23.50kcal/molReviewChase, 1998Data last reviewed in June, 1973
Quantity Value Units Method Reference Comment
solid21.83cal/mol*KReviewChase, 1998Data last reviewed in June, 1973

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1386.5 to 2000.
A 16.00000
B -1.783951×10-8
C 9.057790×10-9
D -1.593441×10-9
E -2.397481×10-9
F -26.95779
G 39.46730
H -20.09180
ReferenceChase, 1998
Comment Data last reviewed in June, 1973

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1386.5
A 11.32430
B 1.804620
C 0.479946
D -0.167414
E -0.007609
F -26.98650
G 34.93320
H -23.50000
ReferenceChase, 1998
Comment Data last reviewed in June, 1973

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)8.5 ± 0.5eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
8.4 ± 0.5EIUy and Drowart, 1969RDSH
8.6 ± 0.5EIColin and Drowart, 1962RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Pb+11.6 ± 0.5SEIColin and Drowart, 1962RDSH
S+16.0 ± 2.0PbEIColin and Drowart, 1962RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Uy and Drowart, 1969
Uy, O.M.; Drowart, J., Mass spectrometric determination of the dissociation energies of the molecules BiO, BiS, BiSe and BiTe, J. Chem. Soc. Faraday Trans., 1969, 65, 3221. [all data]

Colin and Drowart, 1962
Colin, R.; Drowart, J., Thermodynamic study of tin sulfide and lead sulfide using a mass spectrometer, J. Chem. Phys., 1962, 37, 1120. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References