rhenium trioxide
- Formula: O3Re
- Molecular weight: 234.205
- CAS Registry Number: 1314-28-9
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(O4Re- • 4294967295O3Re) + O3Re = O4Re-
By formula: (O4Re- • 4294967295O3Re) + O3Re = O4Re-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 799. ± 30. | kJ/mol | N/A | Chen, Zhai, et al., 2011 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
View reactions leading to O3Re+ (ion structure unspecified)
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
3.530 ± 0.050 | LPES | Chen, Zhai, et al., 2011 | B |
3.60 ± 0.10 | LPES | Pramann and Rademann, 2001 | Vertical Detachment Energy: 3.7±0.1 eV; B |
3.01 ± 0.47 | R-A | Gould and Miller, 1975 | B |
>2.50211 | IMRB | Center, 1972 | B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
12.1 ± 0.3 | EI | Maleev, Semenov, et al., 1974 | LLK |
12.5 ± 0.4 | EI | Skinner and Searcy, 1973 | LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
ORe+ | ~18. | ? | EI | Skinner and Searcy, 1973 | LLK |
O2Re+ | 14.4 ± 1.0 | ? | EI | Skinner and Searcy, 1973 | LLK |
Ion clustering data
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
(O4Re- • 4294967295O3Re) + O3Re = O4Re-
By formula: (O4Re- • 4294967295O3Re) + O3Re = O4Re-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 799. ± 30. | kJ/mol | N/A | Chen, Zhai, et al., 2011 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chen, Zhai, et al., 2011
Chen, W.J.; Zhai, H.J.; Huang, X.; Wang, L.S.,
On the electronic structure of mono-rhenium oxide clusters: ReOn- and ReOn (n=3, 4),
Chem. Phys. Lett., 2011, 512, 1-3, 49-53, https://doi.org/10.1016/j.cplett.2011.07.018
. [all data]
Pramann and Rademann, 2001
Pramann, A.; Rademann, K.,
Photoelectron spectroscopy of ReO2- and ReO3-,
Chem. Phys., 2001, 343, 99-104. [all data]
Gould and Miller, 1975
Gould, B.K.; Miller, W.J.,
Electron attachment and compound formation in flames. VI. Negative ion and compound formation in flames containing rhenium and potassium,
J. Chem. Phys., 1975, 62, 644. [all data]
Center, 1972
Center, R.E.,
Ion-molecule experiments involving negative ions of tungsten and rhenium oxides,
J. Chem. Phys., 1972, 56, 371. [all data]
Maleev, Semenov, et al., 1974
Maleev, A.N.; Semenov, G.A.; Kholodov, A.I.,
Evaporator with gas flooding for high-temperature thermodynamic investigations on a mass spectrometer,
Ind. Lab., 1974, 40, 1179, In original 987. [all data]
Skinner and Searcy, 1973
Skinner, H.B.; Searcy, A.W.,
Mass spectrometric studies of gaseous oxides of rhenium,
J. Phys. Chem., 1973, 77, 1573. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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