rhenium trioxide


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

(O4Re- • 4294967295O3Re) + O3Re = O4Re-

By formula: (O4Re- • 4294967295O3Re) + O3Re = O4Re-

Quantity Value Units Method Reference Comment
Δr799. ± 30.kJ/molN/AChen, Zhai, et al., 2011gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to O3Re+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
3.530 ± 0.050LPESChen, Zhai, et al., 2011B
3.60 ± 0.10LPESPramann and Rademann, 2001Vertical Detachment Energy: 3.7±0.1 eV; B
3.01 ± 0.47R-AGould and Miller, 1975B
>2.50211IMRBCenter, 1972B

Ionization energy determinations

IE (eV) Method Reference Comment
12.1 ± 0.3EIMaleev, Semenov, et al., 1974LLK
12.5 ± 0.4EISkinner and Searcy, 1973LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ORe+~18.?EISkinner and Searcy, 1973LLK
O2Re+14.4 ± 1.0?EISkinner and Searcy, 1973LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chen, Zhai, et al., 2011
Chen, W.J.; Zhai, H.J.; Huang, X.; Wang, L.S., On the electronic structure of mono-rhenium oxide clusters: ReOn- and ReOn (n=3, 4), Chem. Phys. Lett., 2011, 512, 1-3, 49-53, https://doi.org/10.1016/j.cplett.2011.07.018 . [all data]

Pramann and Rademann, 2001
Pramann, A.; Rademann, K., Photoelectron spectroscopy of ReO2- and ReO3-, Chem. Phys., 2001, 343, 99-104. [all data]

Gould and Miller, 1975
Gould, B.K.; Miller, W.J., Electron attachment and compound formation in flames. VI. Negative ion and compound formation in flames containing rhenium and potassium, J. Chem. Phys., 1975, 62, 644. [all data]

Center, 1972
Center, R.E., Ion-molecule experiments involving negative ions of tungsten and rhenium oxides, J. Chem. Phys., 1972, 56, 371. [all data]

Maleev, Semenov, et al., 1974
Maleev, A.N.; Semenov, G.A.; Kholodov, A.I., Evaporator with gas flooding for high-temperature thermodynamic investigations on a mass spectrometer, Ind. Lab., 1974, 40, 1179, In original 987. [all data]

Skinner and Searcy, 1973
Skinner, H.B.; Searcy, A.W., Mass spectrometric studies of gaseous oxides of rhenium, J. Phys. Chem., 1973, 77, 1573. [all data]


Notes

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