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thiophenoxide anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

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Clustering reactions

thiophenoxide anion + Methyl Alcohol = (thiophenoxide anion bullet Methyl Alcohol)

By formula: C6H5S- + CH4O = (C6H5S- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar56.1kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

thiophenoxide anion + Methyl Alcohol = C7H9OS-

By formula: C6H5S- + CH4O = C7H9OS-

Quantity Value Units Method Reference Comment
Deltar56.07 ± 0.42kJ/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar27.2 ± 1.3kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

thiophenoxide anion + Ethanol, 2,2,2-trifluoro- = (thiophenoxide anion bullet Ethanol, 2,2,2-trifluoro-)

By formula: C6H5S- + C2H3F3O = (C6H5S- bullet C2H3F3O)

Quantity Value Units Method Reference Comment
Deltar87.9kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

thiophenoxide anion + Ethanol, 2,2,2-trifluoro- = C8H8F3OS-

By formula: C6H5S- + C2H3F3O = C8H8F3OS-

Quantity Value Units Method Reference Comment
Deltar87.86 ± 0.84kJ/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar56.5 ± 2.5kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

thiophenoxide anion + Acetic acid = (thiophenoxide anion bullet Acetic acid)

By formula: C6H5S- + C2H4O2 = (C6H5S- bullet C2H4O2)

Quantity Value Units Method Reference Comment
Deltar84.9kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

thiophenoxide anion + Acetic acid = C8H9O2S-

By formula: C6H5S- + C2H4O2 = C8H9O2S-

Quantity Value Units Method Reference Comment
Deltar84.94 ± 0.42kJ/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar52.3 ± 1.7kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

thiophenoxide anion + Propanoic acid = C9H11O2S-

By formula: C6H5S- + C3H6O2 = C9H11O2S-

Quantity Value Units Method Reference Comment
Deltar83.7 ± 1.7kJ/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar51.9 ± 5.4kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

thiophenoxide anion + Ethyl formate = (thiophenoxide anion bullet Ethyl formate)

By formula: C6H5S- + C3H6O2 = (C6H5S- bullet C3H6O2)

Quantity Value Units Method Reference Comment
Deltar83.7kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

thiophenoxide anion + Isopropyl Alcohol = C9H13OS-

By formula: C6H5S- + C3H8O = C9H13OS-

Quantity Value Units Method Reference Comment
Deltar62.76 ± 0.42kJ/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar30.5 ± 1.7kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

thiophenoxide anion + 1-Propanol = (thiophenoxide anion bullet 1-Propanol)

By formula: C6H5S- + C3H8O = (C6H5S- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar62.8kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

thiophenoxide anion + 1-Butanol = (thiophenoxide anion bullet 1-Butanol)

By formula: C6H5S- + C4H10O = (C6H5S- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar61.1kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

thiophenoxide anion + 2-Propanol, 2-methyl- = C10H15OS-

By formula: C6H5S- + C4H10O = C10H15OS-

Quantity Value Units Method Reference Comment
Deltar61.09 ± 0.42kJ/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar30.1 ± 2.1kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

thiophenoxide anion + Water = (thiophenoxide anion bullet Water)

By formula: C6H5S- + H2O = (C6H5S- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar47.7kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

thiophenoxide anion + Water = C6H7OS-

By formula: C6H5S- + H2O = C6H7OS-

Quantity Value Units Method Reference Comment
Deltar47.70 ± 0.84kJ/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar23.4 ± 2.9kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sieck and Meot-ner, 1989
Sieck, L.W.; Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 8. RS-..HOR Bond Strengths. Correlation with Acidities., J. Phys. Chem., 1989, 93, 4, 1586, https://doi.org/10.1021/j100341a079 . [all data]


Notes

Go To: Top, Ion clustering data, References