magnesium hydroxide
- Formula: H2MgO2
- Molecular weight: 58.3197
- CAS Registry Number: 1309-42-8
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Gas phase thermochemistry data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -136.80 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1975 |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 63.877 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1975 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 1800. | 1800. to 6000. |
---|---|---|
A | 19.23200 | 23.26770 |
B | 3.111932 | 1.135970 |
C | -0.139038 | -0.191042 |
D | -0.100458 | 0.011410 |
E | -0.316364 | -3.486062 |
F | -143.7330 | -149.7490 |
G | 84.44909 | 85.01190 |
H | -136.8000 | -136.8000 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in December, 1975 | Data last reviewed in December, 1975 |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
OH stretch | 3829.8 | Ar | IR | Andrews and Wang, 2005 Wang and Andrews, 2005 | |||
OH stretch | 3815.4 | H2 | IR | Wang and Andrews, 2005 | |||
MgO a-stretch | 867.2 | Ar | IR | Tague and Andrews, 1994 Andrews and Wang, 2005 Wang and Andrews, 2005 | |||
MgO a-stretch | 846.5 | H2 | IR | Wang and Andrews, 2005 | |||
Additional references: Jacox, 1998, page 282
References
Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Andrews and Wang, 2005
Andrews, L.; Wang, X.,
Infrared Spectra of the Group 2 Metal Dihydroxide Molecules,
Inorg. Chem., 2005, 44, 1, 11, https://doi.org/10.1021/ic0483794
. [all data]
Wang and Andrews, 2005
Wang, X.; Andrews, L.,
Infrared Spectra and Electronic Structure Calculations for the Group 2 Metal M(OH),
J. Phys. Chem. A, 2005, 109, 12, 2782, https://doi.org/10.1021/jp044660s
. [all data]
Tague and Andrews, 1994
Tague, T.J., Jr.; Andrews, L.,
Pulsed Laser Evaporated Magnesium Atom Reactions with Hydrogen: Infrared Spectra of Five Magnesium Hydride Molecules,
J. Phys. Chem., 1994, 98, 35, 8611, https://doi.org/10.1021/j100086a004
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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