Molybdenum,bis(η-2,4-cyclopentadien-1-yl)dihydro-
- Formula: C10H12Mo
- Molecular weight: 228.16
- CAS Registry Number: 1291-40-3
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C10H12Mo (cr) + 2 (cr) = C10H10I2Mo (cr) + 2 (g)
By formula: C10H12Mo (cr) + 2I2 (cr) = C10H10I2Mo (cr) + 2HI (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -87.8 ± 5.1 | kJ/mol | RSC | Calado, Dias, et al., 1979 |
C10H12Mo (cr) + 2 (cr) = C10H10Br2Mo (cr) + 2 (l)
By formula: C10H12Mo (cr) + 2CBr4 (cr) = C10H10Br2Mo (cr) + 2CHBr3 (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -296.5 ± 4.5 | kJ/mol | RSC | Calado, Dias, et al., 1980 |
C10H12Mo (cr) + 2 (l) = C10H10Cl2Mo (cr) + 2 (l)
By formula: C10H12Mo (cr) + 2CCl4 (l) = C10H10Cl2Mo (cr) + 2CHCl3 (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -321.3 ± 4.4 | kJ/mol | RSC | Calado, Dias, et al., 1979, 2 |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
6.4 ± 0.1 | PE | Green, Jackson, et al., 1975 | Vertical value; LLK |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V.,
Rev. Port. Quím., 1979, 21, 129. [all data]
Calado, Dias, et al., 1980
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.,
J. Organometal. Chem., 1980, 195, 203. [all data]
Calado, Dias, et al., 1979, 2
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V.,
J. Organometal. Chem., 1979, 174, 77. [all data]
Green, Jackson, et al., 1975
Green, J.C.; Jackson, S.E.; Higginson, B.,
Photoelectron studies of some bent bis(n-cyclopentadienyl)metal complexes. Part I. Some eighteen-electron systems with hydride, alkyl, olefin, allyl, carbonyl ligands,
J. Chem. Soc. Dalton Trans., 1975, 403. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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