Osmocene

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas87.07kcal/molReviewMartinho SimõesThe enthalpy of formation relies on the assumption that OsO4(cr, yellow) is the only oxide formed but it is likely that the combustion products include a mixture of oxides.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid67.83kcal/molReviewMartinho SimõesThe enthalpy of formation relies on the assumption that OsO4(cr, yellow) is the only oxide formed but it is likely that the combustion products include a mixture of oxides.
Quantity Value Units Method Reference Comment
Δcsolid-1444.0kcal/molCC-SBBrendel and Grubert, 1959No experimental details are reported.

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Tboil571.KN/ABaev, Barkatin, et al., 1979Uncertainty assigned by TRC = 0.00001 K; TRC
Quantity Value Units Method Reference Comment
Tfus506.8KN/ABaev, Barkatin, et al., 1979Crystal phase 1 phase; Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Δsub19.2 ± 0.41kcal/molN/ABaev and Barkatin, 1984AC
Δsub19.2 ± 0.41kcal/molCC-SBBaev and Barkatin, 1984Another value for the enthalpy of vaporization has been reported: 18.0 kcal/mol Fischer and Grubert, 1959; MS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
13.5 ± 0.31535.Baev and Barkatin, 1984Based on data from 506. to 563. K.; AC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Reference Comment
17.4 ± 0.33393. to 506.Baev and Barkatin, 1984AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
~7.0EQRyan, Eyler, et al., 1992LL
7.6 ± 0.1EIMuller and D'Or, 1967RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Brendel and Grubert, 1959
Brendel, G.; Grubert, H., Chem. Ber., 1959, 92, 2302. [all data]

Baev, Barkatin, et al., 1979
Baev, A.K.; Barkatin, A.A.; Gubin, S.P.; Dyagileva, S.P., Thermodynamics of phase transitions and vapor state of some compounds of elements with incomplete d-shells in Vses. Konf. po Kalorimetrii i Khim. Termodinamike, 8th, Ivanovo, p 386-389, 1979. [all data]

Baev and Barkatin, 1984
Baev, A.K.; Barkatin, A.A., Russ. J. Phys. Chem., 1984, 58, 195. [all data]

Fischer and Grubert, 1959
Fischer, E.O.; Grubert, H., Chem. Ber., 1959, 92, 2302. [all data]

Ryan, Eyler, et al., 1992
Ryan, M.F.; Eyler, J.R.; Richardson, D.E., Adiabatic ionization energies, bond disruption enthalpies, and solvation free energies for gas-phase metallocenes and metallocenium ions, J. Am. Chem. Soc., 1992, 114, 8611. [all data]

Muller and D'Or, 1967
Muller, J.; D'Or, L., Massenspektrometrische Untersuchungen an Dicyclopentadienylkomplexen von Ubergangsmetallen, J.Organometal. Chem., 1967, 10, 313. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References