C3-
- Formula: C3-
- Molecular weight: 36.0326
- CAS Registry Number: 12595-80-1
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Reaction thermochemistry data
Go To: Top, Ion clustering data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: (C3- • 4294967295C) + C = C3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.9 ± 2.0 | kcal/mol | N/A | Arnold, Bradforth, et al., 1991 | gas phase; Linear structure for both neutral and anion |
Ion clustering data
Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: (C3- • 4294967295C) + C = C3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.9 ± 2.0 | kcal/mol | N/A | Arnold, Bradforth, et al., 1991 | gas phase; Linear structure for both neutral and anion |
Vibrational and/or electronic energy levels
Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: E
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 32003 ± 3 | gas | E-X | 308 | 313 | Lakin, Guthe, et al., 2000 | ||
State: D
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 29885 ± 3 | gas | D-X | 327 | 335 | Lakin, Guthe, et al., 2000 | ||
To = 29833 ± 20 | Ne | D-X | 329 | 336 | Lakin, Guthe, et al., 2000 | ||
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 28507 ± 3 | gas | C-X | 335 | 351 | Tulej, Fulara, et al., 2000 | ||
Lakin, Guthe, et al., 2000 | |||||||
To = 28660 ± 7 | Ne | C-X | 335 | 349 | Tulej, Fulara, et al., 2000 | ||
Lakin, Guthe, et al., 2000 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 1140 ± 6 | gas | PD | Lakin, Guthe, et al., 2000 | |
1 | Sym. stretch | 1180 ± 14 | Ne | AB | Tulej, Fulara, et al., 2000 | ||
Πu | 2 | Bend | 445 | H | gas | PD | Lakin, Guthe, et al., 2000 |
State: B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 25948 ± 3 | gas | B-X | 355 | 386 | Tulej, Fulara, et al., 2000 | ||
To = 25968 ± 7 | Ne | B-X | 370 | 385 | Tulej, Fulara, et al., 2000 | ||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 1072 ± 6 | gas | PD | Tulej, Fulara, et al., 2000 | |
1 | Sym. stretch | 1062 ± 14 | Ne | AB | Tulej, Fulara, et al., 2000 | ||
Πu | 2 | Bend (w) | 407 | gas | PD | Tulej, Fulara, et al., 2000 | |
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 24743 ± 3 | gas | A-X | 386 | 405 | Tulej, Fulara, et al., 2000 | ||
To = 24810 ± 7 | Ne | A-X | 385 | 403 | Tulej, Fulara, et al., 2000 | ||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 1140 ± 6 | gas | PD | Tulej, Fulara, et al., 2000 | |
1 | Sym. stretch | 1110 ± 14 | Ne | AB | Tulej, Fulara, et al., 2000 | ||
Πu | 2 | Bend (w) | 410 | gas | PD | Tulej, Fulara, et al., 2000 | |
State: b
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 22342 ± 3 | gas | b-X | 429 | 448 | Tulej, Fulara, et al., 2000 | ||
To = 22306 ± 7 | Ne | b-X | 412 | 448 | Tulej, Fulara, et al., 2000 | ||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 959 ± 4 | gas | PD | Tulej, Fulara, et al., 2000 | |
1 | Sym. stretch | 953 ± 10 | Ne | AB | Tulej, Fulara, et al., 2000 | ||
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td = 15980 ± 160 | gas | Oakes and Ellison, 1986 | |||||
Yang, Taylor, et al., 1988 | |||||||
Arnold, Bradforth, et al., 1991 | |||||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 1075 ± 100 | gas | PE | Arnold, Bradforth, et al., 1991 | |
Σu- | 3 | Asym. stretch | 1721.8 | Ar | IR | Szczepanski, Ekern, et al., 1997 Szczepanski, Wehlburg, et al., 1997 | |
Additional references: Jacox, 1994, page 68; Jacox, 1998, page 173; Jacox, 2003, page 99
Notes
H | (1/2)(2ν) |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
d | Photodissociation threshold |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Arnold, Bradforth, et al., 1991
Arnold, D.W.; Bradforth, S.E.; Kitsopoulos, T.N.; Neumark, D.M.,
Vibrationally Resolved Spectra of C2-C11 by Anion Photoelectron Spectroscopy,
J. Chem. Phys., 1991, 95, 12, 8753, https://doi.org/10.1063/1.461211
. [all data]
Lakin, Guthe, et al., 2000
Lakin, N.M.; Guthe, F.; Tulej, M.; Pachkov, M.; Maier, J.P.,
Spectroscopy of excited states of carbon anions above the photodetachment threshold,
Faraday Discuss., 2000, 115, 383, https://doi.org/10.1039/a909545d
. [all data]
Tulej, Fulara, et al., 2000
Tulej, M.; Fulara, J.; Sobolewski, A.; Jungen, M.; Maier, J.P.,
Electronic transitions of C[sub 3][sup -] above the photodetachment threshold,
J. Chem. Phys., 2000, 112, 8, 3747, https://doi.org/10.1063/1.480992
. [all data]
Oakes and Ellison, 1986
Oakes, J.M.; Ellison, G.B.,
Photoelectron spectroscopy of radical anions,
Tetrahedron, 1986, 42, 6263. [all data]
Yang, Taylor, et al., 1988
Yang, S.; Taylor, K.J.; Craycraft, M.J.; Conceicao, J.; Pettiette, C.L.; Cheshnovsky, O.; Smalley, R.E.,
UPS of 2--30-atom carbon clusters: Chains and rings,
Chem. Phys. Lett., 1988, 144, 5-6, 431, https://doi.org/10.1016/0009-2614(88)87291-9
. [all data]
Szczepanski, Ekern, et al., 1997
Szczepanski, J.; Ekern, S.; Vala, M.,
Vibrational Spectroscopy of Small Matrix-Isolated Linear Carbon Cluster Anions,
J. Phys. Chem. A, 1997, 101, 10, 1841, https://doi.org/10.1021/jp963200z
. [all data]
Szczepanski, Wehlburg, et al., 1997
Szczepanski, J.; Wehlburg, C.; Vala, M.,
C,
J. Phys. Chem. A, 1997, 101, 38, 7039, https://doi.org/10.1021/jp971410l
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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