CH3I+

• Formula: CH₃I⁺
• Molecular weight: 141.9384
• CAS Registry Number: 12538-72-6
• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C

State:   B

State:   A

State:   X

Additional references: Jacox, 1994, page 239; Jacox, 2003, page 260; Bae and Kim, 2008, 2; Grutter, Michaud, et al., 2011

Notes

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Potts, Lempka, et al., 1970
Potts, A.W.; Lempka, H.J.; Streets, D.G.; Price, W.C., Photoelectron spectra of the halides of elements in groups III, IV, V and VI, Phil. Trans. Roy. Soc. (London), 1970, A268, 59. [all data]

Ragle, Stenhouse, et al., 1970
Ragle, J.L.; Stenhouse, I.A.; Frost, D.C.; McDowell, C.A., Valence-shell ionization potentials of halomethanes by photoelectron spectroscopy. I. CH₃Cl, CH₃Br, CH₃I. Vibrational frequencies and vibronic interaction in CH₃Br⁺ and CH₃Cl⁺, J. Chem. Phys., 1970, 53, 178. [all data]

Karlsson, Jadrny, et al., 1977
Karlsson, L.; Jadrny, R.; Mattsson, L.; Chau, F.T.; Siegbahn, K., Vibrational and Vibronic Structure in the Valence Electron Spectra of CH, Phys. Scripta, 1977, 16, 5-6, 224, https://doi.org/10.1088/0031-8949/16/5-6/010 . [all data]

Goss, Morrison, et al., 1981
Goss, S.P.; Morrison, J.D.; Smith, D.L., A laser-induced photodissociation study of CH3I+ and CD3I+ at high resolution, J. Chem. Phys., 1981, 75, 2, 757, https://doi.org/10.1063/1.442117 . [all data]

Goss, McGilvery, et al., 1981
Goss, S.P.; McGilvery, D.C.; Morrison, J.D.; Smith, D.L., The photodissociation of some alkyl iodide cations, J. Chem. Phys., 1981, 75, 4, 1820, https://doi.org/10.1063/1.442261 . [all data]

McLoughlin, Morrison, et al., 1985
McLoughlin, R.G.; Morrison, J.D.; Smith, D.L.; Wahrhaftig, A.L., Rotational analysis of the A 2E1/2(0,1,7)←X 2E1/2 (0,0,0) transition in CH3I+, J. Chem. Phys., 1985, 82, 3, 1237, https://doi.org/10.1063/1.448443 . [all data]

Woodward, Colson, et al., 1986
Woodward, A.M.; Colson, S.D.; Chupka, W.A.; White, M.G., Vibrational analysis of the ~A-~X photodissociation spectrum of methyl iodide, J. Phys. Chem., 1986, 90, 2, 173, https://doi.org/10.1021/j100274a014 . [all data]

Weinkauf, Walter, et al., 1987
Weinkauf, R.; Walter, K.; Boesl, U.; Schlag, E.W., Mass-selected molecular ion spectra: (1+1)-Photodissociation spectroscopy of CH3I+ and CD3I+, Chem. Phys. Lett., 1987, 141, 4, 267, https://doi.org/10.1016/0009-2614(87)85022-4 . [all data]

Walter, Weinkauf, et al., 1988
Walter, K.; Weinkauf, R.; Boesl, U.; Schlag, E.W., Molecular ion spectroscopy: Mass selected, resonant two-photon dissociation spectra of CH3I+ and CD3I+, J. Chem. Phys., 1988, 89, 4, 1914, https://doi.org/10.1063/1.455088 . [all data]

Lee and Kim, 2007
Lee, M.; Kim, M.S., High resolution spectroscopy for the A [sup 2]A[sub 1] state of CH[sub 3]I[sup +] by mass-analyzed threshold ionization/photodissociation, J. Chem. Phys., 2007, 127, 12, 124313, https://doi.org/10.1063/1.2778679 . [all data]

Bae and Kim, 2008
Bae, Y.J.; Kim, M.S., Rotational state selection of a CH[sub 3]I[sup +] ion beam using vacuum ultraviolet--mass-analyzed threshold ionization spectroscopy: Characterization using photodissociation spectroscopy, J. Chem. Phys., 2008, 128, 12, 124324, https://doi.org/10.1063/1.2884340 . [all data]

Andrews, Miller, et al., 1979
Andrews, L.; Miller, J.H.; Prochaska, E.S., Matrix photoionization of methyl halides. Ultraviolet spectra of the parent cations and infrared evidence for intramolecular hydrogen-bonded parent anions in solid argon, J. Am. Chem. Soc., 1979, 101, 24, 7158, https://doi.org/10.1021/ja00518a005 . [all data]

Strobel, Fischer, et al., 1994
Strobel, A.; Fischer, I.; Lochschmidt, A.; Muller-Dethlefs, K.; Bondybey, V.E., Photodissociation Dynamics of CH3I and CD3I Probed by Zero Kinetic Energy Photoelectron Spectroscopy, J. Phys. Chem., 1994, 98, 8, 3035, https://doi.org/10.1021/j100059a008 . [all data]

Urban and Bondybey, 2002
Urban, B.; Bondybey, V.E., One-color multiphoton threshold photoelectron spectra of methyl bromide, and their comparison with methyl iodide, J. Chem. Phys., 2002, 116, 12, 4938, https://doi.org/10.1063/1.1447219 . [all data]

Wang, Xing, et al., 2004
Wang, P.; Xing, X.; Lau, K.-C.; Woo, H.K.; Ng, C.Y., Rovibrational-state-selected pulsed field ionization-photoelectron study of methyl iodide using two-color infrared-vacuum ultraviolet lasers, J. Chem. Phys., 2004, 121, 15, 7049, https://doi.org/10.1063/1.1807818 . [all data]

Lee, Bae, et al., 2008
Lee, M.; Bae, Y.J.; Kim, M.S., K selection in one-photon mass-analyzed threshold ionization of CH[sub 3]I and CD[sub 3]I to the X [sup 2]E[sub 3«8725»2] state cations, J. Chem. Phys., 2008, 128, 4, 044310, https://doi.org/10.1063/1.2823032 . [all data]

Xing, Reed, et al., 2008
Xing, X.; Reed, B.; Bahng, M.-K.; Baek, S.-J.; Wang, P.; Ng, C.Y., Infrared--vacuum ultraviolet--pulsed field ionization--photoelectron study of CH[sub 3]I[sup +] using a high-resolution infrared laser, J. Chem. Phys., 2008, 128, 10, 104306, https://doi.org/10.1063/1.2888557 . [all data]

Chau and Karlsson, 1977
Chau, F.T.; Karlsson, L., Vibronic Interaction in Molecules and Ions. II., Phys. Scripta, 1977, 16, 5-6, 258, https://doi.org/10.1088/0031-8949/16/5-6/014 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Bae and Kim, 2008, 2
Bae, Y.J.; Kim, M.S., Photodissociation Spectroscopy of CD, ChemPhysChem, 2008, 9, 12, 1709, https://doi.org/10.1002/cphc.200800207 . [all data]

Grutter, Michaud, et al., 2011
Grutter, M.; Michaud, J.M.; Merkt, F., Photoelectron spectroscopic study of the E«8855»e Jahn--Teller effect in the presence of a tunable spin--orbit interaction. I. Photoionization dynamics of methyl iodide and rotational fine structure of CH3I+ and CD3I+, J. Chem. Phys., 2011, 134, 5, 054308, https://doi.org/10.1063/1.3547548 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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