Dimethylamine

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas-4.7 ± 0.5kcal/molEqkIssoire and Long, 1960Heat of formation derived by Cox and Pilcher, 1970; ALS
Δfgas-5.69kcal/molN/ALemoult, 1907Value computed using ΔfHliquid° value of -49.8 kj/mol from Lemoult, 1907 and ΔvapH° value of 26.0 kj/mol from Issoire and Long, 1960.; DRB

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-10.7 ± 0.5kcal/molEqkIssoire and Long, 1960Heat of formation derived by Cox and Pilcher, 1970; ALS
Δfliquid-11.9kcal/molCcbLemoult, 1907ALS
Quantity Value Units Method Reference Comment
Δcliquid-428.2kcal/molCcbMuller, 1910At 288 K; ALS
Δcliquid-418.2kcal/molCcbLemoult, 1907ALS
Quantity Value Units Method Reference Comment
liquid41.551cal/mol*KN/AAston, Eidinoff, et al., 1939Saturated liquid at boiling point.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
32.689280.44Aston, Eidinoff, et al., 1939T = 14 to 280 K. Value for saturated liquid.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil281. ± 1.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus180.15KN/ARoberts, Emeleus, et al., 1939Uncertainty assigned by TRC = 0.4 K; not clear whether this was measured or not; TRC
Tfus178.9KN/ASimon and Huter, 1935Uncertainty assigned by TRC = 0.5 K; TRC
Tfus180.15KN/ASimon and Huter, 1935, 2Uncertainty assigned by TRC = 1.5 K; TRC
Tfus180.25KN/AWiberg and Sutterlin, 1935Uncertainty assigned by TRC = 1. K; TRC
Tfus177.15KN/ATimmermans and Mattaar, 1921Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Ttriple180.97KN/AAston, Eidinoff, et al., 1939, 2Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc437.22KN/AKay and Young, 1974Uncertainty assigned by TRC = 0.15 K; TRC
Tc437.7KN/ABerthoud, 1917Uncertainty assigned by TRC = 0.3 K; TRC
Tc437.75KN/ABerthoud, 1917Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Pc52.70atmN/AKay and Young, 1974Uncertainty assigned by TRC = 0.03 atm; TRC
Pc52.3500atmN/ABerthoud, 1917Uncertainty assigned by TRC = 0.2999 atm; TRC
Pc52.4300atmN/ABerthoud, 1917Uncertainty assigned by TRC = 0.4000 atm; TRC
Quantity Value Units Method Reference Comment
Δvap6.080kcal/molN/AMajer and Svoboda, 1985 
Δvap6.07 ± 0.01kcal/molVIssoire and Long, 1960Heat of formation derived by Cox and Pilcher, 1970; ALS
Δvap6.21kcal/molN/AIssoire and Long, 1960DRB
Δvap6.33 ± 0.03kcal/molVAston, Eidinoff, et al., 1939, 3ALS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
6.3301280.03N/AAston, Eidinoff, et al., 1939P = 101.325 kPa; DH
6.31280.N/AMajer and Svoboda, 1985 
6.45292.AStephenson and Malanowski, 1987Based on data from 277. to 360. K.; AC
5.69373.AStephenson and Malanowski, 1987Based on data from 358. to 438. K.; AC
6.79264.AStephenson and Malanowski, 1987Based on data from 202. to 279. K. See also Aston, Eidinoff, et al., 1939 and Boublik, Fried, et al., 1984.; AC

Entropy of vaporization

ΔvapS (cal/mol*K) Temperature (K) Reference Comment
22.61280.03Aston, Eidinoff, et al., 1939P; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
201.38 to 280.014.28800995.445-47.869Aston, Eidinoff, et al., 1939Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
1.420180.97Aston, Eidinoff, et al., 1939DH
1.42181.Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
7.847180.97Aston, Eidinoff, et al., 1939DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H9Sn+ + Dimethylamine = (C3H9Sn+ • Dimethylamine)

By formula: C3H9Sn+ + C2H7N = (C3H9Sn+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr44.2kcal/molPHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
Δr44.1kcal/molPHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr30.3cal/mol*KN/AStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
Δr31.8cal/mol*KN/AStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
28.3525.PHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
27.4525.PHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M

Lithium ion (1+) + Dimethylamine = (Lithium ion (1+) • Dimethylamine)

By formula: Li+ + C2H7N = (Li+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr42.2kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Δr27.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Δr34.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

C2H6N- + Hydrogen cation = Dimethylamine

By formula: C2H6N- + H+ = C2H7N

Quantity Value Units Method Reference Comment
Δr395.1 ± 2.0kcal/molD-EARadisic, Xu, et al., 2002gas phase; BDE supported by 72GOL/SOL, over McMillen and Golden, 1982; B
Δr396.44 ± 0.89kcal/molG+TSMacKay, Hemsworth, et al., 1976gas phase; B
Quantity Value Units Method Reference Comment
Δr387.9 ± 2.1kcal/molH-TSRadisic, Xu, et al., 2002gas phase; BDE supported by 72GOL/SOL, over McMillen and Golden, 1982; B
Δr389.20 ± 0.60kcal/molIMREMacKay, Hemsworth, et al., 1976gas phase; B

C3H9Si+ + Dimethylamine = (C3H9Si+ • Dimethylamine)

By formula: C3H9Si+ + C2H7N = (C3H9Si+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr60.0kcal/molPHPMSLi and Stone, 1990gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)C6H5COOC2H5; Wojtyniak and Stone, 1986; M
Quantity Value Units Method Reference Comment
Δr42.7cal/mol*KPHPMSLi and Stone, 1990gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)C6H5COOC2H5; Wojtyniak and Stone, 1986; M

C2H8N+ + Dimethylamine = (C2H8N+ • Dimethylamine)

By formula: C2H8N+ + C2H7N = (C2H8N+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr24.1kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Δr20.8kcal/molPHPMSYamdagni and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr28.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Δr25.7cal/mol*KPHPMSYamdagni and Kebarle, 1973gas phase; M

(C2H8N+ • 2Dimethylamine) + Dimethylamine = (C2H8N+ • 3Dimethylamine)

By formula: (C2H8N+ • 2C2H7N) + C2H7N = (C2H8N+ • 3C2H7N)

Quantity Value Units Method Reference Comment
Δr9.9kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr26.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

(C2H8N+ • 3Dimethylamine) + Dimethylamine = (C2H8N+ • 4Dimethylamine)

By formula: (C2H8N+ • 3C2H7N) + C2H7N = (C2H8N+ • 4C2H7N)

Quantity Value Units Method Reference Comment
Δr7.9kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr22.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

(C2H8N+ • 4Dimethylamine) + Dimethylamine = (C2H8N+ • 5Dimethylamine)

By formula: (C2H8N+ • 4C2H7N) + C2H7N = (C2H8N+ • 5C2H7N)

Quantity Value Units Method Reference Comment
Δr6.3kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr22.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

(C2H8N+ • Dimethylamine) + Dimethylamine = (C2H8N+ • 2Dimethylamine)

By formula: (C2H8N+ • C2H7N) + C2H7N = (C2H8N+ • 2C2H7N)

Quantity Value Units Method Reference Comment
Δr16.4kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr27.2cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

C3H10N+ + Dimethylamine = (C3H10N+ • Dimethylamine)

By formula: C3H10N+ + C2H7N = (C3H10N+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr20.5kcal/molPHPMSYamdagni and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr28.5cal/mol*KPHPMSYamdagni and Kebarle, 1973gas phase; M

Potassium ion (1+) + Dimethylamine = (Potassium ion (1+) • Dimethylamine)

By formula: K+ + C2H7N = (K+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr19.5kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr21.4cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(dimethylamino)methanol = Dimethylamine + Formaldehyde

By formula: C3H9NO = C2H7N + CH2O

Quantity Value Units Method Reference Comment
Δr30.2 ± 0.2kcal/molCmRogers and Rapiejko, 1974liquid phase; Heat of formation derived by 77PED/RYL; ALS

Sodium ion (1+) + Dimethylamine = (Sodium ion (1+) • Dimethylamine)

By formula: Na+ + C2H7N = (Na+ • C2H7N)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

1-(4-chlorophenyl)-1,3-dimethylurea = Benzene, 1-chloro-4-isocyanato- + Dimethylamine

By formula: C9H11ClN2O = C7H4ClNO + C2H7N

Quantity Value Units Method Reference Comment
Δr37.05 ± 0.60kcal/molEqkChimishkyan, Svetlova, et al., 1984solid phase; Dissociation; ALS

N,N-Dimethyl-N'-p-methylphenylurea = Dimethylamine + Benzene, 1-isocyanato-4-methyl-

By formula: C10H14N2O = C2H7N + C8H7NO

Quantity Value Units Method Reference Comment
Δr30.7 ± 0.1kcal/molEqkChimishkyan, Svetlova, et al., 1984solid phase; Dissociation; ALS

3-(4-Methoxyphenyl)-1,1-dimethylurea = Dimethylamine + Benzene, 1-isocyanato-4-methoxy-

By formula: C10H14N2O2 = C2H7N + C8H7NO2

Quantity Value Units Method Reference Comment
Δr22.8 ± 0.2kcal/molEqkChimishkyan, Svetlova, et al., 1984solid phase; Dissociation; ALS

Urea, N'-(3-chlorophenyl)-N,N-dimethyl- = Dimethylamine + Benzene, 1-chloro-3-isocyanato-

By formula: C9H11ClN2O = C2H7N + C7H4ClNO

Quantity Value Units Method Reference Comment
Δr35.37 ± 0.43kcal/molEqkChimishkyan, Svetlova, et al., 1984solid phase; Dissociation; ALS

Fluometuron = Dimethylamine + Benzene, 1-isocyanato-3-(trifluoromethyl)-

By formula: C10H11F3N2O = C2H7N + C8H4F3NO

Quantity Value Units Method Reference Comment
Δr36.35 ± 0.67kcal/molEqkChimishkyan, Svetlova, et al., 1984solid phase; Dissociation; ALS

Diuron = Benzene, 1,2-dichloro-4-isocyanato- + Dimethylamine

By formula: C9H10Cl2N2O = C7H3Cl2NO + C2H7N

Quantity Value Units Method Reference Comment
Δr28.32 ± 0.55kcal/molEqkChimishkyan, Svetlova, et al., 1984solid phase; Dissociation; ALS

Allyl chloride + 2Dimethylamine = N-Allyl-N,N-dimethylamine + Dimethylamine hydrochloride

By formula: C3H5Cl + 2C2H7N = C5H11N + C2H8ClN

Quantity Value Units Method Reference Comment
Δr-19.74 ± 0.09kcal/molCmBeldie, Aelenei, et al., 1982liquid phase; ALS

N,N-Dimethyl-N'-m-methylphenylurea = Dimethylamine + Benzene, 1-isocyanato-3-methyl-

By formula: C10H14N2O = C2H7N + C8H7NO

Quantity Value Units Method Reference Comment
Δr26.27kcal/molEqkChimishkyan, Svetlova, et al., 1984solid phase; Dissociation; ALS

2Dimethylamine + Formaldehyde = Methanediamine, N,N,N',N'-tetramethyl- + Water

By formula: 2C2H7N + CH2O = C5H14N2 + H2O

Quantity Value Units Method Reference Comment
Δr-45.6 ± 0.6kcal/molCmRogers and Rapiejko, 1974gas phase; ALS

Fenuron = Benzene, isocyanato- + Dimethylamine

By formula: C9H12N2O = C7H5NO + C2H7N

Quantity Value Units Method Reference Comment
Δr32.07 ± 0.69kcal/molEqkChimishkyan, Svetlova, et al., 1984solid phase; ALS

Dimethylamine + Formaldehyde = (dimethylamino)methanol

By formula: C2H7N + CH2O = C3H9NO

Quantity Value Units Method Reference Comment
Δr-30.2 ± 0.2kcal/molCmRogers and Rapiejko, 1974gas phase; ALS

2Methylamine = Dimethylamine + Ammonia

By formula: 2CH5N = C2H7N + H3N

Quantity Value Units Method Reference Comment
Δr-4.70kcal/molEqkIssoire and Long, 1960gas phase; ALS

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference
31.4000.LN/A
56. MN/A

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C2H7N+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)8.24 ± 0.08eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)222.2kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity214.3kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.2 ± 0.1PEAue, Webb, et al., 1980LLK
8.2PEAue and Bowers, 1979LLK
8.83EIBaldwin, Loudon, et al., 1977LLK
8.2 ± 0.1PEAue, Webb, et al., 1976LLK
8.30PEVovna and Vilesov, 1974LLK
8.25 ± 0.02PEMaier and Turner, 1973LLK
8.07PECullen, Frost, et al., 1972LLK
8.25PECornford, Frost, et al., 1971LLK
8.36PEAl-Joboury and Turner, 1964RDSH
8.24 ± 0.02PIWatanabe and Mottl, 1957RDSH
8.95PEDaamen and Oskam, 1978Vertical value; LLK
8.97PEKimura and Osafune, 1975Vertical value; LLK
8.85PEGibbins, Lappert, et al., 1975Vertical value; LLK
8.929PEAue, Webb, et al., 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3+14.8CH3NHEISenSharma and Franklin, 1973LLK
CH4N+10.80?EILoudon and Webb, 1977LLK
C2H3+16.6 ± 0.5?EIGallegos and Kiser, 1962RDSH
C2H6N+9.65HEILossing, Lam, et al., 1981LLK
C2H6N+10.55?EILoudon and Webb, 1977LLK
C2H6N+10.50?EILoudon and Webb, 1977LLK
C2H6N+9.41 ± 0.06HEISolka and Russell, 1974LLK
C2H6N+10.1 ± 0.1HEITaft, Martin, et al., 1965RDSH
H4N+14.05 ± 0.05?EIHaney and Franklin, 1969RDSH

De-protonation reactions

C2H6N- + Hydrogen cation = Dimethylamine

By formula: C2H6N- + H+ = C2H7N

Quantity Value Units Method Reference Comment
Δr395.1 ± 2.0kcal/molD-EARadisic, Xu, et al., 2002gas phase; BDE supported by 72GOL/SOL, over McMillen and Golden, 1982; B
Δr396.44 ± 0.89kcal/molG+TSMacKay, Hemsworth, et al., 1976gas phase; B
Quantity Value Units Method Reference Comment
Δr387.9 ± 2.1kcal/molH-TSRadisic, Xu, et al., 2002gas phase; BDE supported by 72GOL/SOL, over McMillen and Golden, 1982; B
Δr389.20 ± 0.60kcal/molIMREMacKay, Hemsworth, et al., 1976gas phase; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H8N+ + Dimethylamine = (C2H8N+ • Dimethylamine)

By formula: C2H8N+ + C2H7N = (C2H8N+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr24.1kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Δr20.8kcal/molPHPMSYamdagni and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr28.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Δr25.7cal/mol*KPHPMSYamdagni and Kebarle, 1973gas phase; M

(C2H8N+ • Dimethylamine) + Dimethylamine = (C2H8N+ • 2Dimethylamine)

By formula: (C2H8N+ • C2H7N) + C2H7N = (C2H8N+ • 2C2H7N)

Quantity Value Units Method Reference Comment
Δr16.4kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr27.2cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

(C2H8N+ • 2Dimethylamine) + Dimethylamine = (C2H8N+ • 3Dimethylamine)

By formula: (C2H8N+ • 2C2H7N) + C2H7N = (C2H8N+ • 3C2H7N)

Quantity Value Units Method Reference Comment
Δr9.9kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr26.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

(C2H8N+ • 3Dimethylamine) + Dimethylamine = (C2H8N+ • 4Dimethylamine)

By formula: (C2H8N+ • 3C2H7N) + C2H7N = (C2H8N+ • 4C2H7N)

Quantity Value Units Method Reference Comment
Δr7.9kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr22.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

(C2H8N+ • 4Dimethylamine) + Dimethylamine = (C2H8N+ • 5Dimethylamine)

By formula: (C2H8N+ • 4C2H7N) + C2H7N = (C2H8N+ • 5C2H7N)

Quantity Value Units Method Reference Comment
Δr6.3kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr22.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

C3H9Si+ + Dimethylamine = (C3H9Si+ • Dimethylamine)

By formula: C3H9Si+ + C2H7N = (C3H9Si+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr60.0kcal/molPHPMSLi and Stone, 1990gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)C6H5COOC2H5; Wojtyniak and Stone, 1986; M
Quantity Value Units Method Reference Comment
Δr42.7cal/mol*KPHPMSLi and Stone, 1990gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)C6H5COOC2H5; Wojtyniak and Stone, 1986; M

C3H9Sn+ + Dimethylamine = (C3H9Sn+ • Dimethylamine)

By formula: C3H9Sn+ + C2H7N = (C3H9Sn+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr44.2kcal/molPHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
Δr44.1kcal/molPHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr30.3cal/mol*KN/AStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
Δr31.8cal/mol*KN/AStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
28.3525.PHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
27.4525.PHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M

C3H10N+ + Dimethylamine = (C3H10N+ • Dimethylamine)

By formula: C3H10N+ + C2H7N = (C3H10N+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr20.5kcal/molPHPMSYamdagni and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr28.5cal/mol*KPHPMSYamdagni and Kebarle, 1973gas phase; M

Potassium ion (1+) + Dimethylamine = (Potassium ion (1+) • Dimethylamine)

By formula: K+ + C2H7N = (K+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr19.5kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr21.4cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

Lithium ion (1+) + Dimethylamine = (Lithium ion (1+) • Dimethylamine)

By formula: Li+ + C2H7N = (Li+ • C2H7N)

Quantity Value Units Method Reference Comment
Δr42.2kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Δr27.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Δr34.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Sodium ion (1+) + Dimethylamine = (Sodium ion (1+) • Dimethylamine)

By formula: Na+ + C2H7N = (Na+ • C2H7N)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1998.
NIST MS number 291481

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Issoire and Long, 1960
Issoire, J.; Long, C., Etude de la thermodynamique chimique de la reaction de formation des methylamines, Bull. Soc. Chim. France, 1960, 2004-2012. [all data]

Cox and Pilcher, 1970
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Muller, 1910
Muller, J.-A., Sur les chaleurs de combustion et les poids specifiques des methylamines, Ann. Chim. Phys., 1910, 20, 116-130. [all data]

Aston, Eidinoff, et al., 1939
Aston, J.G.; Eidinoff, M.L.; Forster, W.S., The heat capacity and entropy, heats of fusion and vaporization and the vapor pressure of dimethylamine, J. Am. Chem. Soc., 1939, 61, 1539-1543. [all data]

Roberts, Emeleus, et al., 1939
Roberts, E.R.; Emeleus, H.J.; Briscoe, H.V.A., Preparation and Prop. of Ethyldideuteramine and Dimethyldeuteramine, J. Chem. Soc., 1939, 1939, 41. [all data]

Simon and Huter, 1935
Simon, A.; Huter, J., Vapor Pressure Curves, Melting Point and Chemical Constants of Dimethyl, Trimethyl- and Isobutylamines, Z. Elektrochem., 1935, 41, 28. [all data]

Simon and Huter, 1935, 2
Simon, A.; Huter, J., Z. Elektrochem., 1935, 41, 294. [all data]

Wiberg and Sutterlin, 1935
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Aston, J.G.; Eidinoff, M.L.; Forster, W.S., The Heat Capacity and Entropy, Heats of Fusion and Vaporization and the Vapor Pressure of Dimethylamine., J. Am. Chem. Soc., 1939, 61, 1539. [all data]

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Aston, Eidinoff, et al., 1939, 3
Aston, J.G.; Eidinoff, M.L.; Forster, W.S., The heat capacity and entropy, heats of fusion and vaporization and the vapor pressure of dimethylamine, J. Am. Chem. Soc., 1939, 61, 1539-15. [all data]

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Stone and Splinter, 1984
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Woodin, R.L.; Beauchamp, J.L., Bonding of Li+ to Lewis Bases in the Gas Phase. Reversals in Methyl Substituent Effects for Different Reference Acids, J. Am. Chem. Soc., 1978, 100, 2, 501, https://doi.org/10.1021/ja00470a024 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Radisic, Xu, et al., 2002
Radisic, D.; Xu, S.J.; Bowen, K.H., Photoelectron spectroscopy of the anions, CH3NH- and (CH3)(2)N- and the anion complexes, H-(CH3NH2) and (CH3)(2)N-[(CH3)(2)NH), Chem. Phys. Lett., 2002, 354, 1-2, 9-13, https://doi.org/10.1016/S0009-2614(01)01470-1 . [all data]

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MacKay, Hemsworth, et al., 1976
MacKay, G.J.; Hemsworth, R.S.; Bohme, D.K., Absolute gas-phase acidities of CH3NH2, C2H5NH2, (CH3)2NH, and (CH3)3N, Can. J. Chem., 1976, 54, 1624. [all data]

Li and Stone, 1990
Li, X.; Stone, A.J., Gas-Phase (CH3)3Si+ Affinities of Alkylamines and Proton Affinities of Trimethylsilyl Alkylamines, Int. J. Mass Spectrom. Ion Proc., 1990, 101, 2-3, 149, https://doi.org/10.1016/0168-1176(90)87008-5 . [all data]

Wojtyniak and Stone, 1986
Wojtyniak, A.C.M.; Stone, A.J., A High-Pressure Mass Spectrometric Study of the Bonding of Trimethylsilylium to Oxygen and Aromatic Bases, Can. J. Chem., 1986, 74, 59. [all data]

Meot-Ner (Mautner), 1992
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Yamdagni and Kebarle, 1973
Yamdagni, R.; Kebarle, P., Gas - Phase Basicites of Amines. Hydrogen Bonding in Proton - Bound Amine Dimers and Proton - Induced Cyclization of alpha, omega - Diamines, J. Am. Chem. Soc., 1973, 95, 11, 3504, https://doi.org/10.1021/ja00792a010 . [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Binding Energies and Stabilities of Potassium Ion Complexes from Studies of Gas Phase Ion Equilibria K+ + M = K+.M, J. Am. Chem. Soc., 1976, 98, 20, 6133, https://doi.org/10.1021/ja00436a011 . [all data]

Rogers and Rapiejko, 1974
Rogers, F.E.; Rapiejko, R.J., Thermochemistry of carbonyl addition reactions. II. Enthalpy of addition of dimethylamine to formaldehyde, J. Phys. Chem., 1974, 78, 599-603. [all data]

McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G., An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions, Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 . [all data]

Chimishkyan, Svetlova, et al., 1984
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Beldie, Aelenei, et al., 1982
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Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Aue, Webb, et al., 1980
Aue, D.H.; Webb, H.M.; Davidson, W.R.; Vidal, M.; Bowers, M.T.; Goldwhite, H.; Vertal, L.E.; Douglas, J.E.; Kollman, P.A.; Kenyon, G.L., Proton affinities photoelectron spectra of three-membered-ring J. Heterocycl. Chem., J. Am. Chem. Soc., 1980, 102, 5151. [all data]

Aue and Bowers, 1979
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Baldwin, Loudon, et al., 1977
Baldwin, M.A.; Loudon, A.G.; Webb, K.S.; Cardnell, P.C., Charge location and fragmentation under electron impact. V-The ionization potentials of (methylated) phosphoramides, guanidines, formamides, acetamides, ureas and thioureas, Org. Mass Spectrom., 1977, 12, 279. [all data]

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Maier, J.P.; Turner, D.W., Steric inhibition of resonance studied by molecular photoelectron spectroscopy Part 3. Anilines, Phenols and Related Compounds, J. Chem. Soc. Faraday Trans. 2, 1973, 69, 521. [all data]

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Cullen, W.R.; Frost, D.C.; Leeder, W.R., The ultraviolet and photoelectron spectra of some unsaturated fluorocarbon derivatives, J. Fluorine Chem., 1972, 1, 227. [all data]

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Gibbins, S.G.; Lappert, M.F.; Pedley, J.B.; Sharp, G.J., Bonding studies of transition-metal complexes. Part II. Helium-I photoelectron spectra of homoleptic d0, d1, and d10 tetrakis(dialkylamides) of transition group 4B metals tungsten hexakis(dimethylamide), J. Chem. Soc. Dalton Trans., 1975, 72. [all data]

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Taft, Martin, et al., 1965
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Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References