Carbon dioxide
- Formula: CO2
- Molecular weight: 44.0095
- IUPAC Standard InChIKey: CURLTUGMZLYLDI-UHFFFAOYSA-N
- CAS Registry Number: 124-38-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Carbon oxide (CO2); Carbonic acid, gas; Carbonic anhydride; Dry ice; CO2; Anhydride carbonique; Carbonica; Kohlendioxyd; Kohlensaure; UN 1013; UN 1845; UN 2187; Cardice; Dricold; Drikold; Carbonic acid anhydride; Khladon 744; R 744
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
By formula: O2+ + CO2 = (O2+ • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.8 ± 0.9 | kcal/mol | AVG | N/A | Average of 4 out of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.5 | cal/mol*K | PHPMS | Hiraoka, Nakajima, et al., 1988 | gas phase; M |
ΔrS° | 18.9 | cal/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=9.80 kcal/mol; M |
ΔrS° | 20.7 | cal/mol*K | N/A | Dotan, Davidson, et al., 1978 | gas phase; switching reaction(O2+)O2, Entropy change calculated or estimated; Conway and Janik, 1970; M |
ΔrS° | 20. | cal/mol*K | N/A | Meot-Ner (Mautner) and Field, 1977 | gas phase; Entropy change calculated or estimated, DG>, ΔrH>; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 4.4 | kcal/mol | DT | Rakshit and Warneck, 1981 | gas phase; M |
ΔrG° | 4.3 | kcal/mol | FA | Dotan, Davidson, et al., 1978 | gas phase; switching reaction(O2+)O2, Entropy change calculated or estimated; Conway and Janik, 1970; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
9.4 | 600. | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; Entropy change calculated or estimated, DG>, ΔrH>; M |
By formula: CO2+ + CO2 = (CO2+ • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16. ± 1. | kcal/mol | AVG | N/A | Average of 7 out of 10 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.1 | cal/mol*K | PHPMS | Hiraoka, Nakajima, et al., 1988 | gas phase; M |
ΔrS° | 18.6 | cal/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=15.9 kcal/mol; M |
ΔrS° | 19.5 | cal/mol*K | DT | Van Koppen, Kemper, et al., 1983 | gas phase; M |
ΔrS° | 22.8 | cal/mol*K | PHPMS | Headley, Mason, et al., 1982 | gas phase; M |
ΔrS° | 21.1 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
By formula: O- + CO2 = (O- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 48. ± 10. | kcal/mol | AVG | N/A | Average of 8 out of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 48.0 ± 5.0 | kcal/mol | IMRE | Adams and Bohme, 1970 | gas phase; O3- + CO2 <=> CO3- + O2; B |
By formula: I- + CO2 = (I- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.7 ± 1.8 | kcal/mol | N/A | Piani, Becucci, et al., 2008 | gas phase; Stated electron affinity is the Vertical Detachment Energy; B |
ΔrH° | 4.0 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
ΔrH° | 4.7 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
ΔrH° | 3.20 | kcal/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
ΔrH° | 5.60 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 13.4 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
ΔrS° | 18.2 | cal/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 0.7 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
ΔrG° | 0.80 ± 0.10 | kcal/mol | TDAs | Banic and Iribarne, 1985 | gas phase; B,M |
ΔrG° | 0.40 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
By formula: O2- + CO2 = (O2- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19.00 ± 0.20 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
ΔrH° | 17.7 ± 1.8 | kcal/mol | IMRE | Pack and Phelps, 1966 | gas phase; Corrected with more recent EA(O2) = 0.45 eV; B,M |
ΔrH° | 25.4 ± 4.6 | kcal/mol | PDis | Vestal and Mauclaire, 1977 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24.2 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
ΔrS° | 21. | cal/mol*K | DT | Pack and Phelps, 1966 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 11.7 ± 2.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
ΔrG° | 12.2 ± 1.2 | kcal/mol | IMRE | Pack and Phelps, 1966 | gas phase; Corrected with more recent EA(O2) = 0.45 eV; B |
ΔrG° | 10.0 | kcal/mol | FA | Adams and Bohme, 1970 | gas phase; switching reaction(O2-)O2; Conway and Nesbit, 1968; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
12.9 | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; switching reaction(O2-)H2O; Arshadi and Kebarle, 1970; M |
By formula: F- + CO2 = (F- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 32.07 | kcal/mol | N/A | Arnold, Bradforth, et al., 1995, 2 | gas phase; B |
ΔrH° | 32.3 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
ΔrH° | 31.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
ΔrH° | 33.0 ± 3.0 | kcal/mol | IMRE | McMahon and Northcott, 1978 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 26.7 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
ΔrS° | 24. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 24.3 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
ΔrG° | 24.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
ΔrG° | 11.6 | kcal/mol | FA | Spears and Ferguson, 1973 | gas phase; DG>; M |
By formula: Cl- + CO2 = (Cl- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.80 ± 0.50 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B |
ΔrH° | 7.60 | kcal/mol | TDEq | Hiraoka, Shoda, et al., 1986 | gas phase; B,M |
ΔrH° | 8.00 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.2 | cal/mol*K | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
ΔrS° | 19.6 | cal/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 2.10 | kcal/mol | TDEq | Hiraoka, Shoda, et al., 1986 | gas phase; B |
ΔrG° | 2.10 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
By formula: (I- • 2CO2) + CO2 = (I- • 3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.20 | kcal/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
ΔrH° | 3.7 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
ΔrH° | 4.6 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.4 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -0.6 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (I- • 4CO2) + CO2 = (I- • 5CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.70 | kcal/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
ΔrH° | 3.1 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
ΔrH° | 4.3 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.0 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.4 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (I- • CO2) + CO2 = (I- • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.6 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
ΔrH° | 4.7 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
ΔrH° | 2.60 | kcal/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.3 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 0.7 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (I- • 5CO2) + CO2 = (I- • 6CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.0 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
ΔrH° | 1.80 | kcal/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
ΔrH° | 4.2 | kcal/mol | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19. | cal/mol*K | N/A | Hiraoka, Mizuse, et al., 1987 | gas phase; Entropy change calculated or estimated; M |
By formula: (Na+ • CO2) + H2O = (Na+ • H2O • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.7 | kcal/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
ΔrH° | 22.9 | kcal/mol | FA | Perry, Rowe, et al., 1980 | gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 25.3 | cal/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
ΔrS° | 25.6 | cal/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M |
By formula: CHO2+ + CO2 = (CHO2+ • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19.8 | kcal/mol | PHPMS | Szulejko and McMahon, 1992 | gas phase; M |
ΔrH° | 18.0 | kcal/mol | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
ΔrH° | 19.1 | kcal/mol | PHPMS | Jennings, Headley, et al., 1982 | gas phase; M |
ΔrH° | 20.1 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 26.6 | cal/mol*K | PHPMS | Szulejko and McMahon, 1992 | gas phase; M |
ΔrS° | 22.2 | cal/mol*K | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
ΔrS° | 27.1 | cal/mol*K | PHPMS | Jennings, Headley, et al., 1982 | gas phase; M |
ΔrS° | 24.2 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
By formula: (I- • 3CO2) + CO2 = (I- • 4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.80 | kcal/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
ΔrH° | 3.6 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
ΔrH° | 4.5 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.0 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: NO2- + CO2 = (NO2- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.30 ± 0.20 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
ΔrH° | 9.30 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.2 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
ΔrS° | 24.2 | cal/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 2.1 ± 2.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
ΔrG° | 2.00 ± 0.20 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
By formula: NO- + CO2 = (NO- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.5 ± 0.3 | kcal/mol | DT | Illies, 1988 | gas phase; ΔrH(0 K)=8.60 kcal/mol; M |
ΔrH° | 7.7 ± 0.4 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
ΔrH° | 13.8 | kcal/mol | FA | Dunkin, Fehsenfeld, et al., 1971 | gas phase; switching reaction(NO+)NO, ΔrH<; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.0 | cal/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=8.60 kcal/mol; M |
ΔrS° | 13.7 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (Br- • CO2) + CO2 = (Br- • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.1 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
ΔrH° | 6.0 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.0 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 0.3 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (CO2+ • CO2) + CO2 = (CO2+ • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.6 ± 0.3 | kcal/mol | PHPMS | Hiraoka, Nakajima, et al., 1988 | gas phase; M |
ΔrH° | 8.3 | kcal/mol | EI | Cameron, Aitken, et al., 1994 | gas phase; M |
ΔrH° | 3.3 | kcal/mol | PI | Linn and Ng, 1981 | gas phase; M |
ΔrH° | 6.0 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 14.1 | cal/mol*K | PHPMS | Hiraoka, Nakajima, et al., 1988 | gas phase; M |
ΔrS° | 24.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
By formula: Br- + CO2 = (Br- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.3 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B |
ΔrH° | 6.7 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 16.5 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1.8 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (Cl- • 2CO2) + CO2 = (Cl- • 3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.8 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
ΔrH° | 6.80 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.4 | cal/mol*K | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 0.1 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
ΔrG° | 0.10 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; B |
By formula: (Cl- • CO2) + CO2 = (Cl- • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.2 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
ΔrH° | 7.20 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.8 | cal/mol*K | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.4 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
ΔrG° | 1.00 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; B |
By formula: H3O+ + CO2 = (H3O+ • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.3 | kcal/mol | PHPMS | Szulejko and McMahon, 1992 | gas phase; M |
ΔrH° | 15.3 | kcal/mol | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
ΔrH° | 14.4 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 21.2 | cal/mol*K | PHPMS | Szulejko and McMahon, 1992 | gas phase; M |
ΔrS° | 24.6 | cal/mol*K | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
ΔrS° | 20.7 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
By formula: (Na+ • 2H2O • CO2) + H2O = (Na+ • 3H2O • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.4 | kcal/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23. | cal/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 5.5 | kcal/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
By formula: (O2+ • CO2) + CO2 = (O2+ • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.6 ± 0.5 | kcal/mol | PHPMS | Hiraoka, Nakajima, et al., 1988 | gas phase; M |
ΔrH° | 7.5 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.7 | cal/mol*K | PHPMS | Hiraoka, Nakajima, et al., 1988 | gas phase; M |
ΔrS° | 15. | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; Entropy change is questionable; M |
By formula: (Na+ • 3H2O) + CO2 = (Na+ • CO2 • 3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.2 | kcal/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 25. | cal/mol*K | N/A | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -0.3 | kcal/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: (Na+ • 3CO2) + CO2 = (Na+ • 4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.4 | kcal/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 25. | cal/mol*K | N/A | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.7 | 310. | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: Na+ + CO2 = (Na+ • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.9 | kcal/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
ΔrH° | 13.7 | kcal/mol | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.1 | cal/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
ΔrS° | 19.8 | cal/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
6.6 | 310. | DT | Keller and Beyer, 1971 | gas phase; low E/N; M |
By formula: (I- • 6CO2) + CO2 = (I- • 7CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.3 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
ΔrH° | 1.90 | kcal/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
By formula: (I- • 7CO2) + CO2 = (I- • 8CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.1 ± 2.0 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
ΔrH° | 1.90 | kcal/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
By formula: (Cl- • 3CO2) + CO2 = (Cl- • 4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.40 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; entropy estimated.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24. | cal/mol*K | N/A | Hiraoka, Shoda, et al., 1986 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -0.80 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; entropy estimated.; B |
By formula: CO3- + CO2 = C2O5-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.90 ± 0.20 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
ΔrH° | 7.10 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1.0 ± 2.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
ΔrG° | 0.60 ± 0.20 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
By formula: HO- + CO2 = (HO- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 50.9 ± 2.5 | kcal/mol | CIDT | Squires, 1992 | gas phase; Dissociative protonation threshold at nPrSH, 9 kcal> calc. CIDC(HOCO2-..HSH) = 7:1 HOCO2-; B |
ΔrH° | 87.60 | kcal/mol | Endo | Hierl and Paulson, 1984 | gas phase; Implies ΔHacid = 291.4, anion appears too stable - JEB; B |
By formula: (CO2+ • 2CO2) + CO2 = (CO2+ • 3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.0 | kcal/mol | EI | Cameron, Aitken, et al., 1994 | gas phase; M |
ΔrH° | 5.1 ± 0.3 | kcal/mol | PHPMS | Hiraoka, Nakajima, et al., 1988 | gas phase; M |
ΔrH° | 2.8 | kcal/mol | PI | Linn and Ng, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.1 | cal/mol*K | PHPMS | Hiraoka, Nakajima, et al., 1988 | gas phase; M |
By formula: (Na+ • H2O • CO2) + H2O = (Na+ • 2H2O • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.4 | kcal/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.6 | cal/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
By formula: (F- • 3CO2) + CO2 = (F- • 4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.8 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.3 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -0.2 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (F- • 4CO2) + CO2 = (F- • 5CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.6 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.3 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.0 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (F- • 5CO2) + CO2 = (F- • 6CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.3 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.5 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.4 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: C7O15- + 7CO2 = C8O17-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; Estimated entropy; single temperature measurement; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -2.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; Estimated entropy; single temperature measurement; B |
By formula: (F- • 2CO2) + CO2 = (F- • 3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.2 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.6 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 0.5 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (F- • CO2) + CO2 = (F- • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.3 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.2 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1.9 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (O2- • 2CO2) + CO2 = (O2- • 3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.0 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -0.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
By formula: (O2- • 3CO2) + CO2 = (O2- • 4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.7 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -0.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
By formula: (O2- • 4CO2) + CO2 = (O2- • 5CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.4 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
By formula: (O2- • 5CO2) + CO2 = (O2- • 6CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.0 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
By formula: (O2- • 6CO2) + CO2 = (O2- • 7CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.3 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
By formula: (O2- • CO2) + CO2 = (O2- • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.60 ± 0.20 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.2 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
By formula: (NO2- • 2CO2) + CO2 = (NO2- • 3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.3 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -0.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
By formula: (NO2- • 3CO2) + CO2 = (NO2- • 4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 25.9 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
By formula: (NO2- • 4CO2) + CO2 = (NO2- • 5CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.3 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
By formula: (NO2- • 5CO2) + CO2 = (NO2- • 6CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.1 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -2.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 13.777 ± 0.001 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 129.2 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 123.3 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
-0.599986 | EIAE | Knapp, Echt, et al., 1986 | Unbound but in -0.3 eV well, from (CO2)n; B |
-1.60 ± 0.10 | NBIE | Compton, Reinhardt, et al., 1975 | B |
Ionization energy determinations
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C+ | 25. ± 2. | O2 | PI | Hitchcock, Brion, et al., 1980 | LLK |
C+ | 22.7 ± 0.2 | O2 | EI | Bussieres and Marmet, 1977 | LLK |
C+ | 27.8 ± 0.1 | 2O | EI | Bussieres and Marmet, 1977 | LLK |
C+ | 24.6 ± 1.0 | O2 | EI | Crowe and McConkey, 1974 | LLK |
C+ | 28.4 ± 0.6 | 2O | EI | Cuthbert, Farren, et al., 1968 | RDSH |
C+ | 14.2 ± 0.5 | 2O | EI | Cuthbert, Farren, et al., 1968 | RDSH |
C+ | 23.2 ± 0.5 | O2 | EI | Cuthbert, Farren, et al., 1968 | RDSH |
CO+ | 19. ± 2. | O | PI | Hitchcock, Brion, et al., 1980 | LLK |
CO+ | 19.466 | O | PE | Eland and Berkowitz, 1977, 2 | LLK |
CO+ | 19.42 ± 0.075 | O | EI | Bussieres and Marmet, 1977 | LLK |
CO+ | 19.466 | O | PE | Kronebusch and Berkowitz, 1976 | LLK |
CO+ | 20.9 ± 1.0 | O | EI | Crowe and McConkey, 1974 | LLK |
CO+ | 29.0 | O | PI | Samson and Gardner, 1973 | LLK |
O+ | 19. ± 1. | CO | PI | Hitchcock, Brion, et al., 1980 | LLK |
O+ | 19.071 | CO | PE | Eland and Berkowitz, 1977, 2 | LLK |
O+ | 19.05 ± 0.05 | CO | EI | Bussieres and Marmet, 1977 | LLK |
O+ | 19.067 | CO | PE | Kronebusch and Berkowitz, 1976 | LLK |
O+ | 19.393 ± 0.008 | ? | PI | Parr and Taylor, 1974 | LLK |
O+ | 22.6 ± 1.0 | CO | EI | Crowe and McConkey, 1974 | LLK |
O+ | 19.10 ± 0.01 | CO | PI | Dibeler and Walker, 1967 | RDSH |
Gas Chromatography
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | Squalane | 27. | 154. | Hively and Hinton, 1968 | He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm |
Packed | Squalane | 49. | 153. | Hively and Hinton, 1968 | He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm |
Packed | Squalane | 67. | 152. | Hively and Hinton, 1968 | He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm |
Packed | Squalane | 86. | 152. | Hively and Hinton, 1968 | He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka, Nakajima, et al., 1988
Hiraoka, K.; Nakajima, G.; Shoda, S.,
Determination of the Stabilities of CO2+(CO2)n and O2+(CO2)n Clusters with n = 1 - 6,
Chem. Phys. Lett., 1988, 146, 6, 535, https://doi.org/10.1016/0009-2614(88)87495-5
. [all data]
Illies, 1988
Illies, A.J.,
Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures,
J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037
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Dotan, Davidson, et al., 1978
Dotan, I.; Davidson, J.A.; Fehsenfeld, F.C.; Albritton, D.L.,
Reactions of O2+.O2 with CO2, O3 and CH4 and O2+.O3 with H2O and CH4 and their Role in Stratospheric Ion Chemistry,
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. [all data]
Conway and Janik, 1970
Conway, D.C.; Janik, G.S.,
Determination of the Bond Energies for the Series O2 - O2+ through O2 - O10+,
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Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H.,
Proton Affinity and Ion - Molecule Clustering in CO2 and CS2. Applications in Martian Ionospheric Chemistry,
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. [all data]
Rakshit and Warneck, 1981
Rakshit, A.B.; Warneck, P.,
Formation and Reactions of O2+.CO2, O2+.H2O and O2+(CO2)2 Ions,
Int. J. Mass Spectrom Ion Phys., 1981, 40, 2, 135, https://doi.org/10.1016/0020-7381(81)80037-X
. [all data]
Van Koppen, Kemper, et al., 1983
Van Koppen, P.A.M.; Kemper, P.R.; Illies, A.J.; Bowers, M.T.,
An Improved High - Pressure, Temperature - Variable Ion Source with Coaxial Electron Beam/Ion Exit Slit,
Int. J. Mass Spectrom. Ion Proc., 1983, 54, 3, 263, https://doi.org/10.1016/0168-1176(83)80015-9
. [all data]
Headley, Mason, et al., 1982
Headley, J.V.; Mason, R.S.; Jennings, K.R.,
Kinetics, Equilibria and Diffusion of Ions Produced in N2, CO and CO2, Studied as a Function of Temperature using a High - Pressure Pulsed Mass Spectrometer,
J. Chem. Soc., 1982, 78, 933. [all data]
Adams and Bohme, 1970
Adams, N.G.; Bohme, D.,
Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-,
J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449
. [all data]
Piani, Becucci, et al., 2008
Piani, G.; Becucci, M.; Bowen, M.S.; Oakman, J.; Hu, Q.; Continetti, R.E.,
Photodetachment and dissociation dynamics of microsolvated iodide clusters,
Phys. Scripta, 2008, 78, 5, 058110, https://doi.org/10.1088/0031-8949/78/05/058110
. [all data]
Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M.,
Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy,
J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576
. [all data]
Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S.,
Stability and Structure of Cluster Ions: Halide Ions with CO2,
J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962
. [all data]
Gomez, Taylor, et al., 2002
Gomez, H.; Taylor, T.R.; Neumark, D.M.,
Anion photoelectron spectroscopy of I-2(-)(CO2)(n)(n=1-8) clusters,
J. Chem. Phys., 2002, 116, 14, 6111-6117, https://doi.org/10.1063/1.1458246
. [all data]
Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr.,
Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions,
J. Chem. Phys., 1980, 73, 2195. [all data]
Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V.,
Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions,
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. [all data]
Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S.,
Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n,
J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560
. [all data]
Pack and Phelps, 1966
Pack, J.L.; Phelps, A.V.,
Electron Attachment and Detachment . II. Mixtures of O2 and CO2 and of O2 and H2O,
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. [all data]
Vestal and Mauclaire, 1977
Vestal, M.L.; Mauclaire, G.H.,
Photodissociaton of negative ions formed in CO2 and CO2/O2 Mixtures,
J. Chem. Phys., 1977, 67, 3758. [all data]
Conway and Nesbit, 1968
Conway, D.C.; Nesbit, L.E.,
Stability of O4-,
J. Chem. Phys., 1968, 48, 1, 509, https://doi.org/10.1063/1.1667956
. [all data]
Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E.,
Laboratory studies of negative ion reactions with atmospheric trace constituents,
J. Chem. Phys., 1974, 61, 3181. [all data]
Arshadi and Kebarle, 1970
Arshadi, M.; Kebarle, P.,
Hydration of OH- and O2- in the Gas Phase. Comparative Solvation of OH- by Water and the Hydrogen Halides. Effect of Acidity,
J. Phys. Chem., 1970, 74, 7, 1483, https://doi.org/10.1021/j100702a015
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Arnold, Bradforth, et al., 1995, 2
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Keller and Beyer, 1971
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Cross section for single and double ionization of carbon dioxide by electron impact threshold up to 180 eV,
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Ionization and dissociative ionization of CO2 by electron impact,
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Photodissociative ionization in the 21-41 eV region: O2, N2, CO, NO, CO2, H2O, NH3 and CH4,
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Schweig and Thiel, 1974
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Potts, A.W.; Williams, T.A.,
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Crowe, A.; McConkey, J.W.,
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Formation and predissociation of CO2+(C2Σ+g),
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Samson and Gardner, 1973
Samson, J.A.R.; Gardner, J.L.,
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Mass spectrometric study of the photoionization of small polyatomic molecules,
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Hively, R.A.; Hinton, R.E.,
Variation of the retention index with temperature on squalane substrates,
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. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy EA Electron affinity IE (evaluated) Recommended ionization energy T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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