Hydrogen cation
- Formula: H+
- Molecular weight: 1.00739
- IUPAC Standard InChIKey: GPRLSGONYQIRFK-UHFFFAOYSA-N
- CAS Registry Number: 12408-02-5
- Chemical structure:
This structure is also available as a 2d Mol file - Isotopologues:
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- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150, reactions 151 to 200, reactions 201 to 250, reactions 251 to 300, reactions 301 to 350, reactions 351 to 400, reactions 401 to 450, reactions 451 to 500, reactions 501 to 550, reactions 551 to 600, reactions 601 to 650, reactions 651 to 700, reactions 701 to 750, reactions 751 to 800, reactions 801 to 850, reactions 851 to 900, reactions 901 to 950, reactions 951 to 1000, reactions 1001 to 1050, reactions 1051 to 1100, reactions 1101 to 1150, reactions 1151 to 1200, reactions 1201 to 1250, reactions 1251 to 1300, reactions 1351 to 1375
- Gas phase ion energetics data
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1301 to 1350
C8H5F6N2O3S2- + = C8H6F6N2O3S2
By formula: C8H5F6N2O3S2- + H+ = C8H6F6N2O3S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1311. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C12H7F4N2- + = C12H8F4N2
By formula: C12H7F4N2- + H+ = C12H8F4N2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1360. ± 8.4 | kJ/mol | IMRE | Koppel, Koppel, et al., 1998 | gas phase |
C11H5F4N2- + = C11H6F4N2
By formula: C11H5F4N2- + H+ = C11H6F4N2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1354. ± 8.4 | kJ/mol | IMRE | Koppel, Koppel, et al., 1998 | gas phase |
C13H5F4N2- + = C13H6F4N2
By formula: C13H5F4N2- + H+ = C13H6F4N2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1337. ± 8.4 | kJ/mol | IMRE | Koppel, Koppel, et al., 1998 | gas phase |
By formula: C13H3F9N- + H+ = C13H4F9N
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1339. ± 8.4 | kJ/mol | IMRE | Koppel, Koppel, et al., 1998 | gas phase |
By formula: C12ClF9N- + H+ = C12HClF9N
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1318. ± 8.4 | kJ/mol | IMRE | Koppel, Koppel, et al., 1998 | gas phase |
C13H5F5NO- + =
By formula: C13H5F5NO- + H+ = C13H6F5NO
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1302. ± 8.4 | kJ/mol | IMRE | Koppel, Koppel, et al., 1998 | gas phase |
C6H11O6- + =
By formula: C6H11O6- + H+ = C6H12O6
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1389. ± 17. | kJ/mol | IMRB | Cai and Cole, 2002 | gas phase |
C9H5CrO3- + =
By formula: C9H5CrO3- + H+ = C9H6CrO3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1554. ± 21. | kJ/mol | IMRB | Lane and Squires, 1985 | gas phase |
By formula: C2H7NO2P- + H+ = C2H8NO2P
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1536. ± 21. | kJ/mol | IMRB | Anderson, DePuy, et al., 1984 | gas phase |
By formula: C10H7N2O- + H+ = C10H8N2O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1320. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
CHF2O4S2- + =
By formula: CHF2O4S2- + H+ = CH2F2O4S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1286. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C10H4F9O6S3- + H+ = C10H5F9O6S3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1279. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C10H3F9NO8S3- + = C10H4F9NO8S3
By formula: C10H3F9NO8S3- + H+ = C10H4F9NO8S3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1277. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C11H4F9O7S3- + H+ = C11H5F9O7S3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1274. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C8H7F3NO2S- + =
By formula: C8H7F3NO2S- + H+ = C8H8F3NO2S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1334. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C14F10N- + H+ = C14HF10N
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1307. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C10H3F4N2- + = C10H4F4N2
By formula: C10H3F4N2- + H+ = C10H4F4N2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1289. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C15F12N- + H+ = C15HF12N
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1287. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C7H3F6O4- + H+ = C7H4F6O4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1282. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C10F8N3- + H+ = C10HF8N3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1281. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C9HF4N2- + H+ = C9H2F4N2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1278. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C9H3F9NO6S3- + H+ = C9H4F9NO6S3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1275. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C7HF4N2- + =
By formula: C7HF4N2- + H+ = C7H2F4N2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1365. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C13H8NO- + =
By formula: C13H8NO- + H+ = C13H9NO
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1360. ± 42. | kJ/mol | EIAE | Muftakhov, Vasil'ev, et al., 1999 | gas phase |
C7H8NO2S- + =
By formula: C7H8NO2S- + H+ = C7H9NO2S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1397. ± 8.4 | kJ/mol | IMRE | Koppel, Koppel, et al., 2001 | gas phase |
HP- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1547. ± 34. | kJ/mol | D-EA | Ervin and Lineberger, 2005 | gas phase |
By formula: C8H5ClF4O2S- + H+ = C8H6ClF4O2S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1353.9 | kJ/mol | IMRE | Zhang, Badal, et al., 2013 | gas phase |
By formula: C9H5F3NO2S- + H+ = C9H6F3NO2S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1328.4 | kJ/mol | IMRE | Zhang, Badal, et al., 2013 | gas phase |
By formula: C8H5F3NO4S- + H+ = C8H6F3NO4S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1322.6 | kJ/mol | IMRE | Zhang, Badal, et al., 2013 | gas phase |
By formula: C9H4F7O4S2- + H+ = C9H5F7O4S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1247.3 | kJ/mol | IMRE | Zhang, Badal, et al., 2013 | gas phase |
By formula: C10H4F9O4S2- + H+ = C10H5F9O4S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1240.1 | kJ/mol | IMRE | Zhang, Badal, et al., 2013 | gas phase |
C12H11F6O5S2- + = C12H12F6O5S2
By formula: C12H11F6O5S2- + H+ = C12H12F6O5S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1233.4 | kJ/mol | IMRE | Zhang, Badal, et al., 2013 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1527. ± 24. | kJ/mol | D-EA | Engelking and Lineberger, 1977 | gas phase |
By formula: C12HF9N- + H+ = C12H2F9N
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1329. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C10F7O- + H+ = C10HF7O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1314. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C11H5F5NO2- + H+ = C11H6F5NO2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1312. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C7H7- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1575. ± 21. | kJ/mol | D-EA | Gunion, Karney, et al., 1996 | gas phase |
C12H9N2O2- + =
By formula: C12H9N2O2- + H+ = C12H10N2O2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1374. ± 8.4 | kJ/mol | IMRE | Koppel, Koppel, et al., 1998 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1470. ± 6.7 | kJ/mol | D-EA | Carpenter, Covington, et al., 2000 | gas phase |
C6H7N2O2- + =
By formula: C6H7N2O2- + H+ = C6H8N2O2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1460. ± 13. | kJ/mol | IMRB | Lee, 2005 | gas phase |
By formula: C10H4F9O2S- + H+ = C10H5F9O2S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1310.8 | kJ/mol | IMRE | Zhang, Badal, et al., 2013 | gas phase |
By formula: C10H4F9O4S2- + H+ = C10H5F9O4S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1237.6 | kJ/mol | IMRE | Zhang, Badal, et al., 2013 | gas phase |
C11H3F12O4S2- + = C11H4F12O4S2
By formula: C11H3F12O4S2- + H+ = C11H4F12O4S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1224.7 | kJ/mol | IMRE | Zhang, Badal, et al., 2013 | gas phase |
By formula: C7H5F3NO2S- + H+ = C7H6F3NO2S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1312. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C2F6N- + =
By formula: C2F6N- + H+ = C2HF6N
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1357. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
By formula: C10F7O- + H+ = C10HF7O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1307. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C7H9O3- + =
By formula: C7H9O3- + H+ = C7H10O3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1376. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase |
C10H11O2- + =
By formula: C10H11O2- + H+ = C10H12O2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1390. ± 8.4 | kJ/mol | IMRE | Decouzon, Gal, et al., 1997 | gas phase |
C10H11O2- + =
By formula: C10H11O2- + H+ = C10H12O2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1390. ± 8.8 | kJ/mol | IMRE | Decouzon, Gal, et al., 1997 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Koppel, Taft, et al., 1994
Koppel, I.A.; Taft, R.W.; Anvia, F.; Zhu, S.Z.; Hu, L.Q.; Sung, K.S.; Desmarteau, D.D.; Yagupolskii, L.M.,
The Gas-Phase Acidities of Very Strong Neutral Bronsted Acids,
J. Am. Chem. Soc., 1994, 116, 7, 3047, https://doi.org/10.1021/ja00086a038
. [all data]
Koppel, Koppel, et al., 1998
Koppel, I.; Koppel, J.; Maria, P.C.; Gal, J.F.; Notario, R.; Vlasov, V.M.; Taft, R.W.,
Comparison of Bronsted acidities of neutral NH-acids in gas phase, dimethyl sulfoxide and water,
Int. J. Mass Spectrom., 1998, 175, 1-2, 61-69, https://doi.org/10.1016/S0168-1176(98)00113-X
. [all data]
Cai and Cole, 2002
Cai, Y.; Cole, R.B.,
Stabilization of anionic adducts in negative ion electrospray mass spectrometry,
Anal. Chem., 2002, 74, 5, 985-991, https://doi.org/10.1021/ac0108818
. [all data]
Lane and Squires, 1985
Lane, K.R.; Squires, R.R.,
Formation of HCr(CO)3- from the remarkable reaction of hydride ion with benzenechromium tricarbonyl,
J. Am. Chem. Soc., 1985, 107, 6403. [all data]
Anderson, DePuy, et al., 1984
Anderson, D.R.; DePuy, C.H.; Filley, J.; Bierbaum, V.M.,
Gas Phase Chemistry of Trimethyl Phosphite,
J. Am. Chem. Soc., 1984, 106, 22, 6513, https://doi.org/10.1021/ja00334a009
. [all data]
Muftakhov, Vasil'ev, et al., 1999
Muftakhov, M.V.; Vasil'ev, Y.V.; Khatymov, R.V.; Mazunov, V.A.; Takhistov, V.V.; Travkin, O.V.; Yakovleva, E.V.,
Thermochemistry of negatively charged ions. II. Energetics of formation of negative ions from acridanone and some of its derivatives,
Rapid Commun. Mass Spectrom., 1999, 13, 10, 912-923, https://doi.org/10.1002/(SICI)1097-0231(19990530)13:10<912::AID-RCM585>3.0.CO;2-W
. [all data]
Koppel, Koppel, et al., 2001
Koppel, I.A.; Koppel, J.; Leito, I.; Koppel, I.; Mishima, M.; Yagupolskii, L.M.,
The enormous acidifying effect of the supersubstituent =NSO2CF3 on the acidity of derivatives of benzenesulfonamide and toluene-p-sulfonamide in the gas phase and in dimethyl sulfoxide,
J. Chem. Soc. Perkin Trans., 2001, 2, 2, 229-232, https://doi.org/10.1039/b005765g
. [all data]
Ervin and Lineberger, 2005
Ervin, K.M.; Lineberger, W.C.,
Photoelectron spectroscopy of phosphorus hydride anions,
J. Chem. Phys., 2005, 122, 19, 194303, https://doi.org/10.1063/1.1881153
. [all data]
Zhang, Badal, et al., 2013
Zhang, M.; Badal, M.M.R.; Koppel, I.A.; Mishima, M.,
Gas-Phase Acidities of alpha- and alpha,alpha-SO2CF3-Substituted Toluenes. Varying Resonance Demand in the Electron-Rich System,
Bull. Chem. Soc. Japan, 2013, 86, 7, 813-820, https://doi.org/10.1246/bcsj.20130052
. [all data]
Engelking and Lineberger, 1977
Engelking, P.C.; Lineberger, W.C.,
Laser photoelecton spectrometry of FeO-: Electron affinity, electronic state separations, and ground state vibrations of iron oxide, and a new ground state assignment,
J. Chem. Phys., 1977, 66, 5054. [all data]
Gunion, Karney, et al., 1996
Gunion, R.F.; Karney, W.; Wenthold, P.G.; Borden, W.T.; Lineberger, W.C.,
Ultraviolet Photoelectron Spectroscopy of Some C7H7- Isomers: Quadricyclanide, Norbornadienide, Cycloheptatrienide, and 1,6-Heptadiynide,
J. Am. Chem. Soc., 1996, 118, 21, 5074, https://doi.org/10.1021/ja954026f
. [all data]
Carpenter, Covington, et al., 2000
Carpenter, D.L.; Covington, A.M.; Thompson J.S.,
Laser Photodetachment Electron Spectroscopy of Tl-,
Phys. Rev. A, 2000, 61, 4, 42501, https://doi.org/10.1103/PhysRevA.61.042501
. [all data]
Lee, 2005
Lee, J.K.,
Insights into nucleic acid reactivity through gas-phase experimental and computational studies,
Int. J. Mass Spectrom., 2005, 240, 3, 261-272, https://doi.org/10.1016/j.ijms.2004.09.020
. [all data]
Decouzon, Gal, et al., 1997
Decouzon, M.; Gal, J.-F.; Maria, P.-C.; Bohm, S.; Jimenez, P.; Roux, M.V.; Exner, O.,
Steric Effects in Crowded Molecules in the Gas Phase: Polymethyl Substituted Benzoic Acids,
New J. Chem., 1997, 21, 561. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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