Cl2PO
- Formula: Cl2OP
- Molecular weight: 117.879
- CAS Registry Number: 12381-09-8
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
View reactions leading to Cl2OP+ (ion structure unspecified)
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
3.83 ± 0.25 | NBAE | Mathur, Rothe, et al., 1976 | From POCl3 |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
P=O stretch | 1300 | T | Ar | IR | Moores and Andrews, 1989 | ||
PCl2 a-stretch | 621 | T | Ar | IR | Moores and Andrews, 1989 | ||
Additional references: Jacox, 1994, page 220
Notes
T | Tentative assignment or approximate value |
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mathur, Rothe, et al., 1976
Mathur, B.P.; Rothe, E.W.; Tang, S.Y.; Reck, G.,
Negative ions from phosphorus halides due to cesium charge exchange,
J. Chem. Phys., 1976, 64, 565. [all data]
Moores and Andrews, 1989
Moores, B.W.; Andrews, L.,
Oxidation of phosphorus(III) halides by red photolysis of ozone complexes in solid argon,
J. Phys. Chem., 1989, 93, 5, 1902, https://doi.org/10.1021/j100342a041
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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