Cl2PO

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to Cl2OP+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
3.83 ± 0.25NBAEMathur, Rothe, et al., 1976From POCl3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
P=O stretch 1300 T Ar IR Moores and Andrews, 1989
PCl2 a-stretch 621 T Ar IR Moores and Andrews, 1989

Additional references: Jacox, 1994, page 220

Notes

TTentative assignment or approximate value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mathur, Rothe, et al., 1976
Mathur, B.P.; Rothe, E.W.; Tang, S.Y.; Reck, G., Negative ions from phosphorus halides due to cesium charge exchange, J. Chem. Phys., 1976, 64, 565. [all data]

Moores and Andrews, 1989
Moores, B.W.; Andrews, L., Oxidation of phosphorus(III) halides by red photolysis of ozone complexes in solid argon, J. Phys. Chem., 1989, 93, 5, 1902, https://doi.org/10.1021/j100342a041 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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