Dilithium dichloride
- Formula: Cl2Li2
- Molecular weight: 84.788
- CAS Registry Number: 12345-57-2
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.20 | PI | Berkowitz, Batson, et al., 1980 | LLK |
| ~10.70 | PE | Potts and Lee, 1979 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Li2Cl+ | 10.0 | Cl | EI | Bloom and Williams, 1981 | LLK |
| Li2Cl+ | 10.6 | Cl | EI | Berkowitz, Tasman, et al., 1962 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Berkowitz, Batson, et al., 1980
Berkowitz, J.; Batson, C.H.; Goodman, G.L.,
Photoionization of lithium chloride vapors: The structure and stability of alkali halide molecules and ions,
J. Chim. Phys., 1980, 77, 631. [all data]
Potts and Lee, 1979
Potts, A.W.; Lee, E.P.F.,
Photoelectron spectra and electronic structure of lithium halide monomers and dimers,
J. Chem. Soc. Faraday Trans. 2, 1979, 75, 941. [all data]
Bloom and Williams, 1981
Bloom, H.; Williams, D.J.,
A mass spectrometric study of the vapors above the molten salt systems LiCl-CuCl, LiBr-CuBr, and NaI-CuI,
J. Chem. Phys., 1981, 75, 4636. [all data]
Berkowitz, Tasman, et al., 1962
Berkowitz, J.; Tasman, H.A.; Chupka, W.A.,
Double-oven experiments with lithium halide vapors,
J. Chem. Phys., 1962, 36, 2170. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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