Hydrazine, 1,2-diphenyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid221.kJ/molCmCole and Gilbert, 1951 
Δfsolid280.kJ/molCcbLemoult, 1908see Lemoult, 1906
Quantity Value Units Method Reference Comment
Δcsolid-6658.4kJ/molCmCole and Gilbert, 1951 
Δcsolid-6654. ± 1.kJ/molCcbPongratz, Bohmert-Sub, et al., 1944 
Δcsolid-6643.8 ± 6.7kJ/molCcbSwietoslawski and Bobinska, 1929 
Δcsolid-6717.08kJ/molCcbLemoult, 1908see Lemoult, 1906

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tfus401.9KN/ACole and Gilbert, 1951, 2Uncertainty assigned by TRC = 0.5 K
Tfus407.KN/ATammann, 1913Uncertainty assigned by TRC = 1. K

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrazine, 1,2-diphenyl- = Benzidine

By formula: C12H12N2 = C12H12N2

Quantity Value Units Method Reference Comment
Δr-102.8 ± 1.0kJ/molCmPongratz, Bohmert-Sub, et al., 1944solid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -106.4 ± 0.2 kJ/mol; Heat of transposition

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.78 ± 0.05PERademacher, Bass, et al., 1977 
7.78PERademacher, 1975Vertical value

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner SRD/NIST
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin EPA-IR VAPOR PHASE LIBRARY
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Tosi, 1966
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 19820
Instrument Beckman DK 2
Melting point 131

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cole and Gilbert, 1951
Cole, L.G.; Gilbert, E.C., The heats of combustion of some nitrogen compounds and the apparent energy of the N-N bond, J. Am. Chem. Soc., 1951, 73, 5423-5427. [all data]

Lemoult, 1908
Lemoult, M.P., Recherches theoriques et experimentales sur les chaleurs de combustion et de formation des composes organiques, Ann. Chim. Phys., 1908, 13, 562-574. [all data]

Lemoult, 1906
Lemoult, M.P., Thermochimie. - Chaleur de combustion et de formation de quelques composes cycliques azotes, Compt. Rend., 1906, 143, 772-775. [all data]

Pongratz, Bohmert-Sub, et al., 1944
Pongratz, A.; Bohmert-Sub, S.; Scholtis, K., Zur thermochemie der benzidin-umlagerung, Ber., 1944, 77, 651-735. [all data]

Swietoslawski and Bobinska, 1929
Swietoslawski, M.W.; Bobinska, M.J., O cieple spalania kamfory, azobenzenu i hydrazobenzenu - Sur la chaleur de combustion du comphre, de l'hydrazobenzene, Rocz. Chem., 1929, 9, 723-730. [all data]

Cole and Gilbert, 1951, 2
Cole, L.G.; Gilbert, E.C., The Heats of Combustion of Some Nitrogen Compounds and the Apparent Energy of the N-N Bond, J. Am. Chem. Soc., 1951, 73, 5423. [all data]

Tammann, 1913
Tammann, G., Nachr. Ges. Wiss. Goettingen, Math.-Phys. Kl., 1913, 1913, 335. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Rademacher, Bass, et al., 1977
Rademacher, P.; Bass, V.-M.; Wildemann, M.; Weger, H., Photoelektronenspektren und Konformation von Hydrazobenzolen, Chem. Ber., 1977, 110, 1939. [all data]

Rademacher, 1975
Rademacher, P., Acyclische Hydrazine, Chem. Ber., 1975, 108, 1548. [all data]

Tosi, 1966
Tosi, C., Uv atlas of organic compounds, 1966, 2, D11/24. [all data]


Notes

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