Triethyl phosphite
- Formula: C6H15O3P
- Molecular weight: 166.1553
- IUPAC Standard InChIKey: BDZBKCUKTQZUTL-UHFFFAOYSA-N
- CAS Registry Number: 122-52-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Phosphorous acid, triethyl ester; Triethoxyphosphine; (C2H5O)3P; Ethyl phosphite, (EtO)3P; UN 2323; Phosphorus ether
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 8.3 | eV | N/A | N/A | L |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.2 | PE | Zverev, Villem, et al., 1981 | LLK |
8.4 | PE | Chattorpadhyay, Findley, et al., 1981 | LLK |
8.4 | PE | Arshinova, Zverev, et al., 1981 | LLK |
9.15 | PE | Yarbrough and Hall, 1978 | LLK |
8.99 | PE | Zverev, Villem, et al., 1981 | Vertical value; LLK |
8.90 | PE | Chattorpadhyay, Findley, et al., 1981 | Vertical value; LLK |
8.99 | PE | Arshinova, Zverev, et al., 1981 | Vertical value; LLK |
8.92 | PE | Cowley, Lattman, et al., 1977 | Vertical value; LLK |
8.8 | PE | Betteridge, Thompson, et al., 1972 | Vertical value; LLK |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | SE-54 | 922. | Kostiainen, 2000 | 25. m/0.32 mm/0.25 μm, He, 40. C @ 1. min, 10. K/min, 280. C @ 10. min |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | 5 % Phenyl methyl siloxane | 922. | OPCW, 1997 | Program: not specified |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zverev, Villem, et al., 1981
Zverev, V.V.; Villem, Y.Y.; Arshinova, R.P.,
Photoelectron spectra of di- and triesters of trivalent phosphorus,
Dokl. Akad. Nauk SSSR, 1981, 256, 1412. [all data]
Chattorpadhyay, Findley, et al., 1981
Chattorpadhyay, S.; Findley, G.L.; McGlynn, S.P.,
Photoelectron spectroscopy of phosphites and phosphates,
J. Electron Spectrosc. Relat. Phenom., 1981, 24, 27. [all data]
Arshinova, Zverev, et al., 1981
Arshinova, R.P.; Zverev, V.V.; Villem, Y.Y.; Villem, N.V.,
Ionization potentials, electron structures, and steric structures of tervalent-phosphorus di-and tri-esters,
J. Gen. Chem. USSR, 1981, 51, 1503, In original 1757. [all data]
Yarbrough and Hall, 1978
Yarbrough, L.W., II; Hall, M.B.,
Photoelectron spectra of substituted chromium, molybdenum, and tungsten pentacarbonyls. Relative π-acceptor and σ-donor properties of various phosphorus ligands,
Inorg. Chem., 1978, 17, 2269. [all data]
Cowley, Lattman, et al., 1977
Cowley, A.H.; Lattman, M.; Montag, R.A.; Verkade, J.G.,
The coordination behavior of acyclic phosphites; a UV photoelectron spectroscopic study,
Inorg. Chim. Acta, 1977, 25, 151. [all data]
Betteridge, Thompson, et al., 1972
Betteridge, D.; Thompson, M.; Baker, A.D.; Kemp, N.R.,
Photoelectron spectra of phosphorus halides, alkyl phosphites and phosphates, organophosphorus pesticides, and related compounds,
Anal. Chem., 1972, 44, 2005. [all data]
Kostiainen, 2000
Kostiainen, O.,
Gas Chromatography in Screening of Chemicals Related to the Chemical Weapons Convention
in Encyclopedia of Analytical Chemistry, Meyers, R.A., ed(s)., John Wiley Sons Ltd, Chichester, 2000, 963-979. [all data]
OPCW, 1997
OPCW,
Conference of the States Parties C-I/DEC.64 (22 May 1997), 1997, retrieved from http://www.opcw.org/html/global/cseries/csp1/CIDEC64.html. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References
- Symbols used in this document:
IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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