Triethyl phosphite

• Formula: C₆H₁₅O₃P
• Molecular weight: 166.1553
• IUPAC Standard InChI: InChI=1S/C6H15O3P/c1-4-7-10(8-5-2)9-6-3/h4-6H2,1-3H3 Copy

  
• IUPAC Standard InChIKey: BDZBKCUKTQZUTL-UHFFFAOYSA-N Copy
• CAS Registry Number: 122-52-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Phosphorous acid, triethyl ester; Triethoxyphosphine; (C2H5O)3P; Ethyl phosphite, (EtO)3P; UN 2323; Phosphorus ether
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• Information on this page:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Phase change data
  • IR Spectrum
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Normal alkane RI, non-polar column, custom temperature program

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zverev, Villem, et al., 1981
Zverev, V.V.; Villem, Y.Y.; Arshinova, R.P., Photoelectron spectra of di- and triesters of trivalent phosphorus, Dokl. Akad. Nauk SSSR, 1981, 256, 1412. [all data]

Chattorpadhyay, Findley, et al., 1981
Chattorpadhyay, S.; Findley, G.L.; McGlynn, S.P., Photoelectron spectroscopy of phosphites and phosphates, J. Electron Spectrosc. Relat. Phenom., 1981, 24, 27. [all data]

Arshinova, Zverev, et al., 1981
Arshinova, R.P.; Zverev, V.V.; Villem, Y.Y.; Villem, N.V., Ionization potentials, electron structures, and steric structures of tervalent-phosphorus di-and tri-esters, J. Gen. Chem. USSR, 1981, 51, 1503, In original 1757. [all data]

Yarbrough and Hall, 1978
Yarbrough, L.W., II; Hall, M.B., Photoelectron spectra of substituted chromium, molybdenum, and tungsten pentacarbonyls. Relative π-acceptor and σ-donor properties of various phosphorus ligands, Inorg. Chem., 1978, 17, 2269. [all data]

Cowley, Lattman, et al., 1977
Cowley, A.H.; Lattman, M.; Montag, R.A.; Verkade, J.G., The coordination behavior of acyclic phosphites; a UV photoelectron spectroscopic study, Inorg. Chim. Acta, 1977, 25, 151. [all data]

Betteridge, Thompson, et al., 1972
Betteridge, D.; Thompson, M.; Baker, A.D.; Kemp, N.R., Photoelectron spectra of phosphorus halides, alkyl phosphites and phosphates, organophosphorus pesticides, and related compounds, Anal. Chem., 1972, 44, 2005. [all data]

Kostiainen, 2000
Kostiainen, O., Gas Chromatography in Screening of Chemicals Related to the Chemical Weapons Convention in Encyclopedia of Analytical Chemistry, Meyers, R.A., ed(s)., John Wiley Sons Ltd, Chichester, 2000, 963-979. [all data]

OPCW, 1997
OPCW, Conference of the States Parties C-I/DEC.64 (22 May 1997), 1997, retrieved from http://www.opcw.org/html/global/c_series/csp1/CI_DEC64.html. [all data]

Notes

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• Symbols used in this document:
  

  IE (evaluated)

  Recommended ionization energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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