Fenitrothion

• Formula: C₉H₁₂NO₅PS
• Molecular weight: 277.234
• IUPAC Standard InChI: InChI=1S/C9H12NO5PS/c1-7-6-8(4-5-9(7)10(11)12)15-16(17,13-2)14-3/h4-6H,1-3H3 Copy

  
• IUPAC Standard InChIKey: ZNOLGFHPUIJIMJ-UHFFFAOYSA-N Copy
• CAS Registry Number: 122-14-5
• Chemical structure:
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• Other names: Phenitrothion; Phosphorothioic acid, O,O-dimethyl O-(3-methyl-4-nitrophenyl) ester; Phosphorothioic acid, O,O-dimethyl O-(4-nitro-m-tolyl) ester; Accothion; Agria 1050; Agriya 1050; Agrothion; Akotion; Bayer S 5660; Bayer 41831; BAY 41831; CL 47300; CP 47114; EI 47300; ENT 25,715; Falithion; Folithion; Metathion; Metathion E-50; Metathione; Metathionine E-50; Metation; Metation E-50; Monsanto CP 47114; MEP (Pesticide); MEP (Phosphorus insecticide); Nitrophos; Nuvanol; Oleosumifene; Ovadofos; OMS 43; S 112A; S 5660; Sumithian; Sumithion; Verthion; AC-47300; Aceothion; American cyanamid cl-47,300; Arbogal; BAY S 5660; Cekutrothion; m-Cresol, 4-nitro-, O-ester with O,O-dimethyl phosphorothioate; Cyfen; Cytel; Cyten; O,O-Dimethyl-O-(3-methyl-4-nitrofenyl)-monothiofosfaat; O,O-Dimethyl-O-(3-methyl-4-nitro-phenyl)-monothiophosphate; Dimethyl 3-methyl-4-nitrophenyl phosphorothionate; O,O-Dimethyl O-(3-methyl-4-nitrophenyl) thiophosphate; O,O-Dimethyl-O-(4-nitro-5-methylphenyl)-thionophosphate; O,O-Dimethyl O-(4-nitro-3-methylphenyl)thiophosphate; O,O-Dimethyl O-4-nitro-m-tolyl phosphorothioate; Dimethyl 4-nitro-m-tolyl phosphorothionate; O,O-Dimetil-O-(3-metil-4-nitrofenil) fosforotioato; O,O-Dimetil-O-(3-metil-4-nitro-fenil)-monotiofosfato; Fenitox; Fenitrotion; Folithion ec 50; Kotion; Macbar; MEP; Metathio E-50; Metathionine; Methylnitrophos; Mglawik F; Novathion; Owadofos; Pennwalt C-4852; S-1102A; Sumitomo S-1102A; Thiophosphate de O,O-dimethyle et de O-(3-methyl-4-nitrophenyle); O,O-Dimethyl-(3-methyl-4-nitrophenyl) ester of phosphorothioic acid; Dicofen; O,O-Dimethyl O-4-nitro-m-tolyl thiophosphate; O,O-DiMe O-(3-methyl-4-nitrophenyl) thiophosphate; O,O-Dimethyl O-(3-methyl-4-nitrophenyl) phosphorothioate; Oleometathion; Tionfos 50 LE; Sumigran; Sumifene; Owadophos; bis-Fenitrothion
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• Information on this page:
  • IR Spectrum
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Phase change data
  • Henry's Law data
  • Mass spectrum (electron ionization)
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IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Kovats' RI, non-polar column, custom temperature program

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Normal alkane RI, non-polar column, isothermal

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Normal alkane RI, non-polar column, temperature ramp

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Normal alkane RI, non-polar column, custom temperature program

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Erdmann, Rochholz, et al., 1992
Erdmann, F.; Rochholz, G.; Schütz, H., Retention-indices on OV-1 of approximately 170 commonly used pesticides, Mikrochim. Acta, 1992, 106, 3-6, 219-226, https://doi.org/10.1007/BF01242093 . [all data]

Oyama, Sano, et al., 1987
Oyama, N.; Sano, T.; Syoyama, M.; Maeda, K., Studies on systematic analysis of poisonous compounds in forensic chemistry. II. Application of capillary column gas chromatography to substance identification by means of retention indices, Eisei Kagaku, 1987, 33, 5, 342-348, https://doi.org/10.1248/jhs1956.33.342 . [all data]

Lora-Tamayo, Rams, et al., 1986
Lora-Tamayo, C.; Rams, M.A.; Chacon, J.M.R., Gas Chromatographic Data for 187 Nitrogen- or Phosphorus-Containing Drugs and Metabolites of Toxicological Interest Analysed on Methyl Silicone Capillary Columns, J. Chromatogr., 1986, 374, 73-85, https://doi.org/10.1016/S0378-4347(00)83254-5 . [all data]

Tanabe, Mitobe, et al., 2000
Tanabe, A.; Mitobe, H.; Kawata, K.; Sakai, M.; Yasuhara, A., New monitoring system for ninety pesticides and related compounds in river water by solid-phase extraction with determination by gas chromatography/mass spectrometry, J. AOAC Int., 2000, 83, 1, 61-77. [all data]

Osselton and Snelling, 1986
Osselton, M.D.; Snelling, R.D., Chromatographic Identification of Pesticides, J. Chromatogr., 1986, 368, 265-271, https://doi.org/10.1016/S0021-9673(00)91068-9 . [all data]

TSunoda, 1986
TSunoda, N., Simultaneous determination of organophosphorous pesticides in forencis chemistry by gas-liquid chromatography with hydrogen flame ionization detector, Eisei Kagaku, 1986, 32, 2, 91-100, https://doi.org/10.1248/jhs1956.32.91 . [all data]

Murayama, Mukai, et al., 2000
Murayama, H.; Mukai, H.; Mitobe, H.; Moriyama, N., Simple method for determining trace pesticides in air using extraction disks, Anal. Sci., 2000, 16, 3, 257-263, retrieved from http://wwwsoc.nii.ac.;p/jsac/analsci/pdfs/a16₀257.pdf, https://doi.org/10.2116/analsci.16.257 . [all data]

Hayakawa, Niinomi, et al., 1990
Hayakawa, S.; Niinomi, J.; Kato, S.; Kanamaru, T., Retention time and mass number of agrochemicals by capillary column GC/MS, Mie-ken Kankyo-Kagaku Senta-kenkyu-ho-koku (Report of the Environmental Science Institute of Mie Prefecture), 1990, 10, 53-56. [all data]

Marozzi, Gambaro, et al., 1982
Marozzi, E.; Gambaro, V.; Saligari, E.; Mariani, R.; Lodi, F., Use of the retention index in gas chromatographic studies of drugs, J. Anal. Toxicol., 1982, 6, 4, 185-192, https://doi.org/10.1093/jat/6.4.185 . [all data]

Department of Food Safety and Welfare, 2006
Department of Food Safety, Ministry of Health; Welfare, Analytical methods for residual compositional substances of agricultural chemicals, feed aadditives, and veterinary drugs in foods, 2006, retrieved from http://www.mhlw.go.jp/english/topics/foodsafety/positivelist060228/de/060526-1a.pdf. [all data]

Kawara, Asada, et al., 2005
Kawara, K.; Asada, T.; Oikawa, K.; Tanabe, A., Multiresidue determination of pesticides in sediments by ultrasonically assisted extraction and gas chromatography/mass spectrometry, J. AOAC International, 2005, 88, 5, 1440-1451. [all data]

Zenkevich, Ostroukhova, et al., 2002
Zenkevich, I.G.; Ostroukhova, O.K.; Dolzhenko, V.I., Optimum analytical parameters for chromatographic characterization of pesticides, J. Anal. Chem. USSR (Engl. Transl.), 2002, 57, 1, 35-39. [all data]

Kawata, Mukai, et al., 1996
Kawata, K.; Mukai, H.; Tanabe, H.; Yasuhara, A., Annual variation of insecticides in precipitation in rural Japan, Bull. Environ. Contam. Toxicol., 1996, 57, 6, 853-858, https://doi.org/10.1007/s001289900268 . [all data]

Tameo and Kiyos, 1991
Tameo, O.; Kiyos, I., Simultaneous determination of pesticides by capillary gas chromatography, Cannot be traslated (in Japan), 1991, 14, 2, 109-122. [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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