Selenium dimer
- Formula: Se2
- Molecular weight: 157.92
- IUPAC Standard InChIKey: XIMIGUBYDJDCKI-UHFFFAOYSA-N
- CAS Registry Number: 12185-17-0
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
View reactions leading to Se2+ (ion structure unspecified)
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
1.940 ± 0.070 | LPES | Snodgrass, Coe, et al., 1989 | B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.6 | PE | Potts and Novak, 1983 | LBLHLM |
8.9 ± 0.2 | EI | Grade, Wienecke, et al., 1983 | LBLHLM |
8.70 ± 0.05 | PE | Streets and Berkowitz, 1976 | LLK |
~8.84 | S | Barrow, Burton, et al., 1970 | RDSH |
8.88 ± 0.03 | PI | Berkowitz and Chupka, 1969 | RDSH |
8.93 | PE | Potts and Novak, 1983 | Vertical value; LBLHLM |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
Se+ | 12.0 ± 0.5 | Se | EI | Uy and Drowart, 1969 | RDSH |
Se+ | 13. ± 13. | Se | PI | Berkowitz and Chupka, 1969 | RDSH |
Se+ | 12.6 ± 0.5 | Se | EI | Uy, Muenow, et al., 1968 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Snodgrass, Coe, et al., 1989
Snodgrass, J.T.; Coe, J.V.; McHugh, K.M.; Freidhoff, C.B.; Bowen, K.H.,
Photoelectron Spectroscopy of the Selenium and Tellurium Containing Negative Ions: SeO2-, Se2- and Te2-,
J. Phys. Chem., 1989, 93, 4, 1249, https://doi.org/10.1021/j100341a016
. [all data]
Potts and Novak, 1983
Potts, A.W.; Novak, I.,
Ultraviolet photoelectron spectra of selenium and tellurium,
J. Electron Spectrosc. Relat. Phenom., 1983, 28, 267. [all data]
Grade, Wienecke, et al., 1983
Grade, M.; Wienecke, J.; Rosinger, W.; Hirschwald, W.,
Electron impact investigation of the molecules SeS(g) and TeSe(g) under high-temperature equilibrium conditions,
Ber. Bunsen-Ges. Phys. Chem., 1983, 87, 355. [all data]
Streets and Berkowitz, 1976
Streets, D.G.; Berkowitz, J.,
Photoelectron spectroscopy of Se2 and Te2,
J. Electron Spectrosc. Relat. Phenom., 1976, 9, 269. [all data]
Barrow, Burton, et al., 1970
Barrow, R.F.; Burton, W.G.; Callomon, J.H.,
Absorption spectrum of gaseous 80Se2 in the region 51500-55000 cm-1,
J. Chem. Soc. Faraday Trans., 1970, 66, 2685. [all data]
Berkowitz and Chupka, 1969
Berkowitz, J.; Chupka, W.A.,
Photoionization of high-temperature vapors. VI. S2, Se2, and Te2,
J. Chem. Phys., 1969, 50, 4245. [all data]
Uy and Drowart, 1969
Uy, O.M.; Drowart, J.,
Mass spectrometric determination of the dissociation energies of the molecules BiO, BiS, BiSe and BiTe,
J. Chem. Soc. Faraday Trans., 1969, 65, 3221. [all data]
Uy, Muenow, et al., 1968
Uy, O.M.; Muenow, D.W.; Ficalora, P.J.; Margrave, J.L.,
Mass spectrometric studies at high temperatures. Part 30. Vaporization of Ga2S3, Ga2Se3 and Ga2Te3, and stabilities of the gaseous gallium chalcogenides,
J. Chem. Soc. Faraday Trans., 1968, 64, 2998. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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