Titanium,bis(η5-2,4-cyclopentadien-1-yl)diiodo-
- Formula: C10H10I2Ti
- Molecular weight: 431.862
- CAS Registry Number: 12152-92-0
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C10H10I2Ti (solution) + (solution) = 2C10H10ClITi (solution)
By formula: C10H10I2Ti (solution) + C10H10Cl2Ti (solution) = 2C10H10ClITi (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -0.81 | kcal/mol | EqS | Bruce and Tyler, 1985 | solvent: Perdeuterated benzene; The reaction enthalpy relies on a single value for the equilibrium constant. It assumes a negligible reaction entropy |
(cr) +
(cr) = C10H10I2Ti (cr) + 2
(g)
By formula: C12H10O2Ti (cr) + I2 (cr) = C10H10I2Ti (cr) + 2CO (g)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -17.7 ± 0.50 | kcal/mol | RSC | Dias, Dias, et al., 1987 |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.0 ± 0.1 | PE | Cauletti, Clark, et al., 1980 | Vertical value |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bruce and Tyler, 1985
Bruce, M.R.M.; Tyler, D.R.,
Organometallics, 1985, 4, 528. [all data]
Dias, Dias, et al., 1987
Dias, A.R.; Dias, P.B.; Diogo, H.P.; Galvão, A.M.; Minas da Piedade, M.E.; Martinho Simões, J.A.,
Organometallics, 1987, 6, 1427. [all data]
Cauletti, Clark, et al., 1980
Cauletti, C.; Clark, J.P.; Green, J.C.; Jackson, S.E.; Fragala, I.L.; Ciliberto, E.; Coleman, A.W.,
Photoelectron spectra of bis-cyclopentadienyl metal dihalides,
J. Electron Spectrosc. Relat. Phenom., 1980, 18, 61. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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