Boric acid, trimethyl ester

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil341.99KN/AOwensby, Plank, et al., 1989Uncertainty assigned by TRC = 0.4 K; TRC
Tboil341.62KN/AKraher, Plank, et al., 1986Uncertainty assigned by TRC = 0.2 K; TRC
Tboil341.8KN/ASchindler, Plank, et al., 1977Uncertainty assigned by TRC = 0.3 K; TRC
Tboil341.90KN/ALecat, 1927Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus243.9KN/AWebster and Dennis, 1933Uncertainty assigned by TRC = 0.5 K; TRC
Tfus239.15KN/ATimmermans and Mattaar, 1921Uncertainty assigned by TRC = 0.5 K; TRC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
8.17319.Christopher and Shilman, 1967Based on data from 304. to 340. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
304.4 to 340.64.738001476.192-29.0Christopher and Shilman, 1967Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
Proton affinity (review)195.0kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity187.2kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
10.0PEKroner, Nolle, et al., 1973LLK
10.62EILappert, Litzow, et al., 1970RDSH
10.8 ± 0.3EIWada and Kiser, 1964RDSH
8.9 ± 0.2EILaw and Margrave, 1956RDSH
10.40PEKroner, Nolle, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
B+31.6 ± 1.0?EILaw and Margrave, 1956RDSH
BO2+17.5 ± 0.3?EIWada and Kiser, 1964RDSH
BO3+13.2 ± 0.3?EIWada and Kiser, 1964RDSH
BO3+12.7 ± 1.0?EILaw and Margrave, 1956RDSH
CHO+19.1 ± 0.3?EIWada and Kiser, 1964RDSH
CH3+13.6 ± 0.5?EILaw and Margrave, 1956RDSH
CH3O+12.7 ± 0.2?EIWada and Kiser, 1964RDSH
C2H5BO2+13.2 ± 0.2?EIWada and Kiser, 1964RDSH
C2H6BO+16.6 ± 0.3?EIWada and Kiser, 1964RDSH
C2H6BO2+13.0 ± 0.2CH3OEIWada and Kiser, 1964RDSH
C2H6BO2+9.6 ± 0.2CH3OEILaw and Margrave, 1956RDSH
C2H6BO3+12.1 ± 0.2CH3EIWada and Kiser, 1964RDSH

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Owensby, Plank, et al., 1989
Owensby, G.S.; Plank, C.A.; Laukhuf, W.L.S., Vapor-Liquid Equilibria of the Trimethyl Borate(1)-Trichloroethylene (2) System, J. Chem. Eng. Data, 1989, 34, 213. [all data]

Kraher, Plank, et al., 1986
Kraher, M.V.; Plank, C.A.; Laukhuf, W.L.S., Vapor-Liquid Equilibria of the System Trimethyl Borate(1) - n-Cyclohexane(2), J. Chem. Eng. Data, 1986, 31, 387. [all data]

Schindler, Plank, et al., 1977
Schindler, L.E.; Plank, C.A.; Christopher, P.M.; Laukhuf, W.L.S., Vapor-liquid equilibria of the ternary system methyl borate + methyl alcohol + carbon tetrachloride, J. Chem. Eng. Data, 1977, 22, 294-6. [all data]

Lecat, 1927
Lecat, M., New binary azeotropes: 6th list, Ann. Soc. Sci. Bruxelles, Ser. B, 1927, 47, 63-71. [all data]

Webster and Dennis, 1933
Webster, S.H.; Dennis, L.M., Preparation and urification of Methyl BOrate and Ethyl BOrate, J. Am. Chem. Soc., 1933, 55, 3233-5. [all data]

Timmermans and Mattaar, 1921
Timmermans, J.; Mattaar, J.F., Freezing points of orgainic substances VI. New experimental determinations., Bull. Soc. Chim. Belg., 1921, 30, 213. [all data]

Christopher and Shilman, 1967
Christopher, Phoebus M.; Shilman, Avner, Vapor pressures of trialkyl borates, J. Chem. Eng. Data, 1967, 12, 3, 333-335, https://doi.org/10.1021/je60034a012 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Kroner, Nolle, et al., 1973
Kroner, J.; Nolle, D.; Noth, H., Photoelektronenspektroskopische untersuchungen an bor-verbindungen, I Orbitalreihenfolgen und ladungsdichten in methylthiound methoxyborane, Z. Naturforsch. B:, 1973, 28, 416. [all data]

Lappert, Litzow, et al., 1970
Lappert, M.F.; Litzow, M.R.; Pedley, J.B.; Riley, P.N.K.; Spalding, T.R.; Tweedale, A., Bonding studies of compounds of boron and the group IV elements. Part III.First ionisation potentials of some simple boron compounds by electron impact and by a new empirical molecular orbital method, J. Chem. Soc. A, 1970, 2320. [all data]

Wada and Kiser, 1964
Wada, Y.; Kiser, R.W., A mass spectrometric study of trimethyl borate, J. Phys. Chem., 1964, 68, 1588. [all data]

Law and Margrave, 1956
Law, R.W.; Margrave, J.L., Mass spectrometer appearance potentials for positive ion fragments from BF3, B(CH3)3, B(C2H5)3, B(OCH3)3, and HB(OCH3)2, J. Chem. Phys., 1956, 25, 1086. [all data]


Notes

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