Ga2H6
Vibrational and/or electronic energy levels
Go To: Top, References, Notes
Data compilation copyright
by the U.S. Secretary of Commerce on behalf of the U.S.A.
All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
|
Vib. sym. |
No. |
Approximate type of mode |
cm-1 |
Med. |
Method |
References |
|
ag |
1 |
GaHt stretch |
2000 |
|
Ar |
Ra |
Souter, Andrews, et al., 1994 |
|
1 |
GaHt stretch |
1986 |
|
N2 |
Ra |
Souter, Andrews, et al., 1994 |
|
2 |
GaHb stretch |
1474 |
|
Ar |
Ra |
Souter, Andrews, et al., 1994 |
|
2 |
GaHb stretch |
1471 |
|
N2 |
Ra |
Souter, Andrews, et al., 1994 |
|
3 |
GaH2 deform. |
736 |
|
Ar |
Ra |
Souter, Andrews, et al., 1994 |
|
3 |
GaH2 deform. |
733 |
|
N2 |
Ra |
Souter, Andrews, et al., 1994 |
b2u |
8 |
GaHt stretch |
1993 |
m |
gas |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
8 |
GaHt stretch |
2015 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
8 |
GaHt stretch |
1996 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
8 |
GaHt stretch |
1995.0 |
|
H2 |
IR |
Wang and Andrews, 2003 |
|
8 |
GaHt stretch |
2000 |
m |
N2 |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
9 |
GaH2 rock |
760 |
w |
gas |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
9 |
GaH2 rock |
773 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
9 |
GaH2 rock |
761 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
9 |
GaH2 rock |
770 |
m |
N2 |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
b1g |
11 |
GaHt stretch |
2011 |
|
Ar |
Ra |
Souter, Andrews, et al., 1994 |
|
11 |
GaHt stretch |
1997 |
|
N2 |
Ra |
Souter, Andrews, et al., 1994 |
b1u |
13 |
GaHb stretch |
1202 |
s |
gas |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
13 |
GaHb stretch |
1213 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
13 |
GaHb stretch |
1208 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
13 |
GaHb stretch |
1195 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
13 |
GaHb stretch |
1202 |
|
H2 |
IR |
Wang and Andrews, 2003 |
|
13 |
GaHb stretch |
1220 |
s |
N2 |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
14 |
GaH2 rock? |
659 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
14 |
GaH2 rock? |
655 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
14 |
GaH2 rock? |
653 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
14 |
GaH2 rock? |
648 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
14 |
GaH2 rock? |
655 |
s |
N2 |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
14 |
GaH2 rock? |
647 |
w |
N2 |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
b3g |
15 |
GaH2 deform. |
763 |
|
Ar |
Ra |
Souter, Andrews, et al., 1994 |
|
15 |
GaH2 deform. |
761 |
|
N2 |
Ra |
Souter, Andrews, et al., 1994 |
b3u |
16 |
GaHt stretch |
1976 |
m |
gas |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
16 |
GaHt stretch |
1985 |
s |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
16 |
GaHt stretch |
1968 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
16 |
GaHt stretch |
1975.7 |
|
H2 |
IR |
Wang and Andrews, 2003 |
|
16 |
GaHt stretch |
1985 |
m |
N2 |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
17 |
GaHb stretch |
1273 |
s |
gas |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
17 |
GaHb stretch |
1283 |
s |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
17 |
GaHb stretch |
1278 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
17 |
GaHb stretch |
1253 |
m |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
17 |
GaHb stretch |
1272 |
|
H2 |
IR |
Wang and Andrews, 2003 |
|
17 |
GaHb stretch |
1282 |
m |
N2 |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
18 |
GaH2 bend |
671 |
vs T |
gas |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
18 |
GaH2 bend |
676 |
vs |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
18 |
GaH2 bend |
666 |
s |
Ar |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
18 |
GaH2 bend |
671 |
|
H2 |
IR |
Wang and Andrews, 2003 |
|
18 |
GaH2 bend |
673 |
vs |
N2 |
IR |
Downs, Goode, et al., 1989 Pulham, Downs, et al., 1991 |
|
Additional references: Jacox, 1994, page 372; Jacox, 1998, page 333
Notes
w | Weak |
m | Medium |
s | Strong |
vs | Very strong |
T | Tentative assignment or approximate value |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright
by the U.S. Secretary of Commerce on behalf of the U.S.A.
All rights reserved.
Souter, Andrews, et al., 1994
Souter, P.F.; Andrews, L.; Downs, A.J.; Greene, T.M.; Ma, B.; Schaefer, H.F., III,
Observed and calculated Raman spectra of the Ga2H6 and Ga2D6 molecules,
J. Phys. Chem., 1994, 98, 49, 12824, https://doi.org/10.1021/j100100a004
. [all data]
Downs, Goode, et al., 1989
Downs, A.J.; Goode, M.J.; Pulham, C.R.,
Gallane at last! Synthesis and properties of binary gallium hydride,
J. Am. Chem. Soc., 1989, 111, 5, 1936, https://doi.org/10.1021/ja00187a090
. [all data]
Pulham, Downs, et al., 1991
Pulham, C.R.; Downs, A.J.; Goode, M.J.; Rankin, D.W.H.; Robertson, H.E.,
Gallane: synthesis, physical and chemical properties, and structure of the gaseous molecule Ga2H6 as determined by electron diffraction,
J. Am. Chem. Soc., 1991, 113, 14, 5149, https://doi.org/10.1021/ja00014a003
. [all data]
Wang and Andrews, 2003
Wang, X.; Andrews, L.,
Infrared Spectra of Gallium Hydrides in Solid Hydrogen: GaH,
J. Phys. Chem. A, 2003, 107, 51, 11371, https://doi.org/10.1021/jp035393d
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69:
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