dipotassium oxide
- Formula: K2O
- Molecular weight: 94.1960
- CAS Registry Number: 12136-45-7
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to K2O+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 320.87 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 313.53 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
4.7 ± 0.4 | PI | Dao, Peterson, et al., 1984 | LBLHLM |
4.96 | S | Butman, Kudin, et al., 1984 | LBLHLM |
7.5 ± 1.0 | S | Farber, Srivastava, et al., 1982 | LBLHLM |
10.7 ± 0.3 | EI | Simmons, Lowden, et al., 1977 | LLK |
7.5 ± 0.1 | EI | Ehlert, 1977 | LLK |
7.5 ± 0.2 | EI | Ehlert, 1977 | LLK |
~5. | EI | Gusarov and Gorokhov, 1966 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Dao, Peterson, et al., 1984
Dao, P.D.; Peterson, K.I.; Castleman, A.W., Jr.,
The photoionization of oxidized metal clusters,
J. Chem. Phys., 1984, 80, 563. [all data]
Butman, Kudin, et al., 1984
Butman, M.F.; Kudin, L.S.; Krasnov, K.S.,
The Mass-spectrometric determination of the proton affinity of the molecules M2O (M = Na, K, Rb, Cs),
Russ. J. Inorg. Chem., 1984, 29, 1228, In original 2150. [all data]
Farber, Srivastava, et al., 1982
Farber, M.; Srivastava, R.D.; Moyer, J.W.,
Mass spectrometric determination of the thermodynamics of potassium hydroxide and minor potassium-containing species required in magnetohydrodynamic power systems,
J. Chem. Thermodyn., 1982, 14, 1103. [all data]
Simmons, Lowden, et al., 1977
Simmons, L.L.; Lowden, L.F.; Ehlert, T.C.,
A mass spectrometric study of K2CO3 and K2O,
J. Phys. Chem., 1977, 81, 706. [all data]
Ehlert, 1977
Ehlert, T.C.,
Mass spectrometric investigations of the oxides of potassium,
High Temp. Sci., 1977, 9, 237. [all data]
Gusarov and Gorokhov, 1966
Gusarov, A.V.; Gorokhov, L.N.,
Vapor composition over potassium oxide,
Teplofiz. Vysokikh Temperatur, 1966, 4, 590, In original 558. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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