Molybdenum,bis(η-benzene)-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas95.9 ± 4.9kcal/molReviewMartinho Simões 
Δfgas78.8 ± 2.8kcal/molReviewMartinho Simões 
Δfgas79.1 ± 2.6kcal/molReviewMartinho Simões 
Δfgas78.9 ± 2.4kcal/molReviewMartinho SimõesSelected data. Average of the values from Connor, El-Saied, et al., 1981.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid73.3 ± 4.4kcal/molReviewMartinho Simões 
Δfsolid56.2 ± 1.9kcal/molReviewMartinho Simões 
Δfsolid56.5 ± 1.7kcal/molReviewMartinho Simões 
Δfsolid56.3 ± 1.3kcal/molReviewMartinho SimõesSelected data. Average of the values from Connor, El-Saied, et al., 1981.
Quantity Value Units Method Reference Comment
Δcsolid-1789.8 ± 4.4kcal/molCC-SBFischer and Reckziegel, 1961Please also see Pedley and Rylance, 1977, Cox and Pilcher, 1970, and Tel'noi and Rabinovich, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub22.6 ± 2.0kcal/molCC-SBFischer and Reckziegel, 1961 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
5.52 ± 0.05PEEvans, Green, et al., 1974Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Connor, El-Saied, et al., 1981
Connor, J.A.; El-Saied, N.I.; Martinho Simões, J.A.; Skinner, H.A., J. Organometal. Chem., 1981, 212, 405. [all data]

Fischer and Reckziegel, 1961
Fischer, E.O.; Reckziegel, A., Chem. Ber., 1961, 94, 2204. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Evans, Green, et al., 1974
Evans, S.; Green, J.C.; Jackson, S.E.; Higginson, B., He(I) photoelectron spectra of some transition-metal sandwich complexes, J. Chem. Soc. Dalton Trans., 1974, 304. [all data]


Notes

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