o-Dimethylbenzene chromium tricarbonyl
- Formula: C11H10CrO3
- Molecular weight: 242.1914
- IUPAC Standard InChI: InChI=1S/C8H10.3CO.Cr/c1-7-5-3-4-6-8(7)2;3*1-2;/h3-6H,1-2H3;;;;
- IUPAC Standard InChIKey: NOHKERUDDYWNCW-UHFFFAOYSA-N
- CAS Registry Number: 12129-29-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Chromium,tricarbonyl[(1,2,3,4,5,6-η)-1,2-dimethylbenzene]-; Chromium,tricarbonyl[(1,2,3,4,5,6-η6)-1,2-dimethylbenzene]-
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.29 | CTS | Kobayashi, Kobayashi, et al., 1973 | LLK |
| 6.7 ± 0.1 | EI | Gilbert, Leach, et al., 1973 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C8H10+ | 8.5 ± 0.1 | ? | EI | Gilbert, Leach, et al., 1973 | LLK |
| C8H10Cr+ | 9.6 ± 0.1 | 3CO | EI | Gilbert, Leach, et al., 1973 | LLK |
| C9H10OCr+ | 7.9 ± 0.1 | 2CO | EI | Gilbert, Leach, et al., 1973 | LLK |
| C10H10O2Cr+ | 7.0 ± 0.1 | CO | EI | Gilbert, Leach, et al., 1973 | LLK |
| Cr+ | 13.1 ± 0.1 | ? | EI | Gilbert, Leach, et al., 1973 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kobayashi, Kobayashi, et al., 1973
Kobayashi, H.; Kobayashi, M.; Kaizu, Y.,
Molecular complexes of arenetricarbonylchromium,
Bull. Chem. Soc. Jpn., 1973, 46, 3109. [all data]
Gilbert, Leach, et al., 1973
Gilbert, J.R.; Leach, W.P.; Miller, J.R.,
Ionisation appearance potential measurements in arene chromium tricarbonyls,
J. Organomet. Chem., 1973, 49, 219. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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