Molybdenum,tricarbonyl[(1,2,3,4,5,6-η)-1,3,5-cycloheptatriene]-
- Formula: C10H8MoO3
- Molecular weight: 272.13
- IUPAC Standard InChIKey: WQAVHVQYKSYTII-UHFFFAOYSA-N
- CAS Registry Number: 12125-77-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Cycloheptatriene molybdenum tricarbonyl; Molybdenum, tricarbonyl(1,3,5-cycloheptatriene)-; Tricarbonyl(η-1,3,5-cycloheptatriene)molybdenum; Tricarbonyl(cycloheptatriene)molybdenum; Molybdenum,tricarbonyl[(1,2,3,4,5,6-η6)-1,3,5-cycloheptatriene]-; tricarbonyl[(1,2,3,4,5,6-η)cyclohepta-1,3,5-triene]molybdenum
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Phase change data
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 21.0 ± 0.96 | kcal/mol | N/A | Pilcher and Skinner, 1983 | See also Brown, Connor, et al., 1977. |
Gas phase ion energetics data
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.44 | PE | Fragala, Ciliberto, et al., 1979 | Vertical value; LLK |
7.46 ± 0.05 | PE | Gower, Kane-Maguire, et al., 1977 | Vertical value; LLK |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-IW-2034 |
NIST MS number | 237809 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Brown, Connor, et al., 1977
Brown, D.L.S.; Connor, Joseph A.; Demain, Christopher P.; Leung, May L.; Martinho-Simoes, Jose A.; Skinner, Henry A.; Zafarani Moattar, Mohamed T.,
The thermochemistry of carbonyl complexes of Cr, Mo, Wand Co with arenes, cycloheptatriene, and norbornadiene,
Journal of Organometallic Chemistry, 1977, 142, 3, 321-335, https://doi.org/10.1016/S0022-328X(00)88348-5
. [all data]
Fragala, Ciliberto, et al., 1979
Fragala, I.; Ciliberto, E.; Granozzi, G.; Deganello, G.,
He-I and He-II excited photoelectron spectra of cycloheptatrienetricarbonyl complexes of group VIA metals,
J. Organomet. Chem., 1979, 182, 511. [all data]
Gower, Kane-Maguire, et al., 1977
Gower, M.; Kane-Maguire, L.A.P.; Maier, J.P.; Sweigart, D.A.,
Ultraviolet photoelectron spectra of cyclohepta-1,3,5-triene and mesitylene tricarbonyl complexes of the group 6A metals,
J. Chem. Soc. Dalton Trans., 1977, 316. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References
- Symbols used in this document:
ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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