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Titanium dicarbide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.540 ± 0.030LPESLi and Wang, 1999B
1.542 ± 0.020LPESWang, Ding, et al., 1997B

Ionization energy determinations

IE (eV) Method Reference Comment
8.7 ± 0.5EIKohl and Stearns, 1974LLK
8.2 ± 0.6EICocke and Gingerich, 1974LLK
8.2 ± 0.6EICocke and Gingerich, 1972LLK
8.7 ± 0.5EIStearns and Kohl, 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Li and Wang, 1999
Li, X.; Wang, L.-S., Electronic Structure and Chemical Bonding Between the First Row Transition Metals and C2: A Photoelectron Spectroscopy Study of MC2- (M=Sc, V, Cr, Mn, Fe, and Co), J. Chem. Phys., 1999, 111, 18, 8389, https://doi.org/10.1063/1.480218 . [all data]

Wang, Ding, et al., 1997
Wang, X.; Ding, C.; Wang, L.S., Vibrationally Resolved Photoelectron Spectra of TiCx-(x=2-5) Clusters, J. Phys. Chem., 1997, 101, 42, 7699, https://doi.org/10.1021/jp971838k . [all data]

Kohl and Stearns, 1974
Kohl, F.J.; Stearns, C.A., Vaporization and dissociation energies of the molecular carbides of titanium, zirconium, hafnium, and thorium, High Temp. Sci., 1974, 6, 284. [all data]

Cocke and Gingerich, 1974
Cocke, D.L.; Gingerich, K.A., Thermodynamic investigation of the gaseous molecules TiRh, Rh2, and Ti2Rh by mass spectrometry, J. Chem. Phys., 1974, 60, 1958. [all data]

Cocke and Gingerich, 1972
Cocke, D.L.; Gingerich, K.A., Determination of the heats of atomization of the molecules RhC2, RhC, and TiC2 by high temperature mass spectrometry, J. Chem. Phys., 1972, 57, 3654. [all data]

Stearns and Kohl, 1970
Stearns, C.A.; Kohl, F.J., The dissociation energies of titanium dicarbide and titanium tetracarbide, High Temp. Sci., 1970, 2, 274. [all data]


Notes

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