Potassium sodide
- Formula: KNa
- Molecular weight: 62.0881
- IUPAC Standard InChIKey: BITYAPCSNKJESK-UHFFFAOYSA-N
- CAS Registry Number: 12056-29-0
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 4.41636 ± 0.00017 | eV | N/A | N/A | L |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.465 ± 0.030 | LPES | Eaton, Sarkas, et al., 1992 | Vertical Detachment Energy: 0.575±0.015 eV.; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
4.4164 ± 0.0002 | PI | Kappes, Radi, et al., 1985 | LBLHLM |
4.41636 ± 0.00017 | LS | Leutwyler, Hofmann, et al., 1981 | LLK |
4.52 ± 0.05 | PI | Herrmann, Leutwyler, et al., 1978 | LLK |
4.57 ± 0.20 | EI | Zmbov, Wu, et al., 1977 | LLK |
4.5 ± 0.1 | PI | Foster, Leckenby, et al., 1969 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
K+ | 4.96 | Na | PI | Herrmann, Leutwyler, et al., 1978 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Eaton, Sarkas, et al., 1992
Eaton, J.G.; Sarkas, H.W.; Arnold, S.T.; Mchugh, K.M.; Bowen, K.H.,
Negative Ion Photoelectron Spectroscopy of the Heteronuclear Alkali-Metal Dimer and Trimer Anions - NaK-, KRb-, RbCS-, KCs-, Na2K-, and K2Cs,
Chem. Phys. Lett., 1992, 193, 1-3, 141, https://doi.org/10.1016/0009-2614(92)85697-9
. [all data]
Kappes, Radi, et al., 1985
Kappes, M.M.; Radi, P.; Schar, M.; Schumacher, E.,
Photoionization measurements on dialkali monohalides generated in supersonic nozzle beams,
Chem. Phys. Lett., 1985, 113, 243. [all data]
Leutwyler, Hofmann, et al., 1981
Leutwyler, S.; Hofmann, M.; Harri, H.-P.; Schumacher, E.,
The adiabatic ionization potentials of the alkali dimers Na2, NaK and K2,
Chem. Phys. Lett., 1981, 77, 257. [all data]
Herrmann, Leutwyler, et al., 1978
Herrmann, A.; Leutwyler, S.; Schumacher, E.; Woste, L.,
38. On metal-atom clusters IV. Photoionization thresholds and multiphoton ionization spectra of alkali-metal molecules,
Helv. Chim. Acta, 1978, 61, 453. [all data]
Zmbov, Wu, et al., 1977
Zmbov, K.F.; Wu, C.H.; Ihle, H.R.,
A mass spectrometric study of heteronuclear diatomic alkali metal molecules. Dissociation energies ionization potentials of NaLi, KLi, NaK,
J. Chem. Phys., 1977, 67, 4603. [all data]
Foster, Leckenby, et al., 1969
Foster, P.J.; Leckenby, R.E.; Robbins, E.J.,
The ionization potentials of clustered alkali metal atoms,
J. Phys. B:, 1969, 2, 478. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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