Diindium monoxide

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 32699 ± 15 Ar C-X 300 306 Douglas, Hauge, et al., 1983
To = 31854 ± 15 Kr C-X 306 314 Douglas, Hauge, et al., 1983
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1 Sym. stretch 576 Ar AB Douglas, Hauge, et al., 1983
2 Bend 139 Kr AB Douglas, Hauge, et al., 1983

State:   B2
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 26524.53 gas B2-X 373 377 Lakin, van den Hoek, et al., 1997

State:   B1
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 25815 gas B1-X 380 388 Lakin, van den Hoek, et al., 1997
To = 25644 ± 15 Kr Douglas, Hauge, et al., 1983
To = 25535 ± 15 Kr Douglas, Hauge, et al., 1983
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 InO s-stretch 219.2 gas AB Lakin, van den Hoek, et al., 1997
2 Bend 94 T gas AB Lakin, van den Hoek, et al., 1997

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 19260 ± 15 Kr Douglas, Hauge, et al., 1983

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 InO s-stretch 222 gas LF Lakin, van den Hoek, et al., 1997
Πu 2 Bend 52 H gas LF Lakin, van den Hoek, et al., 1997
Σu+ 3 InO a-stretch 745.4 Ne IR Makowiecki, Lynch, et al., 1971
3 InO a-stretch 735.2 Ar IR Makowiecki, Lynch, et al., 1971
Hinchcliffe and Ogden, 1973
Zehe, Lynch, et al., 1979
Burkholder, Yustein, et al., 1992
3 InO a-stretch 728.2 Kr IR Makowiecki, Lynch, et al., 1971
3 InO a-stretch 722.4 N2 IR Hinchcliffe and Ogden, 1969
Makowiecki, Lynch, et al., 1971
Hinchcliffe and Ogden, 1971
Hinchcliffe and Ogden, 1973
Zehe, Lynch, et al., 1979

Additional references: Jacox, 1994, page 64; Jacox, 2003, page 81

Notes

H(1/2)(2ν)
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Douglas, Hauge, et al., 1983
Douglas, M.A.; Hauge, R.H.; Margrave, J.L., High Temp. Sci., 1983, 16, 35. [all data]

Lakin, van den Hoek, et al., 1997
Lakin, N.M.; van den Hoek, G.; Beattie, I.R.; Brown, J.M., The identification of In[sub 2]O in the gas phase by high resolution electronic spectroscopy, J. Chem. Phys., 1997, 107, 11, 4439, https://doi.org/10.1063/1.474786 . [all data]

Makowiecki, Lynch, et al., 1971
Makowiecki, D.M.; Lynch, D.A.; Carlson, K.D., Infrared spectra of the aluminum family suboxides, J. Phys. Chem., 1971, 75, 1963. [all data]

Hinchcliffe and Ogden, 1973
Hinchcliffe, A.J.; Ogden, J.S., Matrix isolation studies on the gallium-indium-oxygen system. Infrared spectra and structures of molecular gallium(I) oxide, indium(I) oxide and indium gallium suboxide (InOGa), J. Phys. Chem., 1973, 77, 21, 2537, https://doi.org/10.1021/j100907a010 . [all data]

Zehe, Lynch, et al., 1979
Zehe, M.J.; Lynch, D.A., Jr.; Kelsall, B.J.; Carlson, K.D., Matrix reactions of molecular oxygen with indium and gallium atoms, J. Phys. Chem., 1979, 83, 6, 656, https://doi.org/10.1021/j100469a004 . [all data]

Burkholder, Yustein, et al., 1992
Burkholder, T.R.; Yustein, J.T.; Andrews, L., Reactions of pulsed laser evaporated gallium and indium atoms with molecular oxygen: matrix infrared spectra of new gallium dioxide and indium dioxide species, J. Phys. Chem., 1992, 96, 25, 10189, https://doi.org/10.1021/j100204a019 . [all data]

Hinchcliffe and Ogden, 1969
Hinchcliffe, A.J.; Ogden, J.S., Chem. Commun., 1969, 1053. [all data]

Hinchcliffe and Ogden, 1971
Hinchcliffe, A.J.; Ogden, J.S., Vibrational analysis for the molecules gallium oxide, indium oxide, and thallium oxide. Comment, J. Phys. Chem., 1971, 75, 25, 3908, https://doi.org/10.1021/j100694a030 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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