Anthracene

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas53. ± 4.kcal/molAVGN/AAverage of 6 values; Individual data points

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
9.89050.Dorofeeva O.V., 1988S(T) values calculated by [ Kudchadker S.A., 1979] are 3.6-4.1 J/mol*K greater than recommended ones. Cp(T) values from two calculations agree within 0.3 J/mol*K. Recommended values are also reproduced in the reference book [ Frenkel M., 1994].; GT
14.68100.
20.98150.
28.334200.
40.093273.15
44.15 ± 0.24298.15
44.453300.
59.689400.
72.395500.
82.550600.
90.662700.
97.237800.
102.65900.
107.151000.
110.941100.
114.141200.
116.881300.
119.221400.
121.231500.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid29. ± 3.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δcsolid-1688. ± 4.kcal/molAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
solid,1 bar49.510cal/mol*KN/AGoursot, Girdhar, et al., 1970DH
solid,1 bar49.510cal/mol*KN/AGoursot, Girdhar, et al., 1968DH
solid,1 bar49.59cal/mol*KN/AHuffman, Parks, et al., 1931Extrapolation below 90 K, 14.98 cal/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
50.60298.15Radomska and Radomski, 1980T = 180 to 430 K. Data given graphically. Cp calculated from equation.; DH
50.311298.15Goursot, Girdhar, et al., 1970T = 5 to 500 K.; DH
50.311298.15Goursot, Girdhar, et al., 1968T = 5 to 520 K. Only 6 points given; summary article.; DH
51.98298.15Ueberreiter and Orthmann, 1950T = 293 to 368 K. Equation only.; DH
49.50297.2Huffman, Parks, et al., 1931T = 94 to 297 K. Value is unsmoothed experimental datum.; DH
53.01298.15Hildebrand, Duschak, et al., 1917T = 293 to 593 K. From heat content data.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil613.2KN/AWeast and Grasselli, 1989BS
Tboil613.0KN/ABuckingham and Donaghy, 1982BS
Tboil613.1KN/ABurriel, 1931Uncertainty assigned by TRC = 0.3 K; TRC
Tboil613.KN/AKirby, 1921Uncertainty assigned by TRC = 5. K; TRC
Quantity Value Units Method Reference Comment
Tfus490. ± 3.KAVGN/AAverage of 27 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple488.93KN/AGoursot, Girdhar, et al., 1970, 2Uncertainty assigned by TRC = 0.01 K; TRC
Quantity Value Units Method Reference Comment
Δvap18.8kcal/molCGCZhao, Unhannanant, et al., 2008AC
Δvap19.0 ± 0.29kcal/molGCHaftka, Parsons, et al., 2006Based on data from 413. to 473. K.; AC
Δvap18.9kcal/molCGCPuri, Chickos, et al., 2001AC
Δvap19.1kcal/molCGCChickos, Hesse, et al., 1998AC
Δvap19.0kcal/molCGCChickos, Hosseini, et al., 1995Based on data from 453. to 503. K.; AC
Quantity Value Units Method Reference Comment
Δsub23. ± 3.kcal/molAVGN/AAverage of 12 values; Individual data points

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
15.9498.N/ARojas and Orozco, 2003See also Hanshaw, Nutt, et al., 2008.; AC
17.3398.GCLei, Chankalal, et al., 2002Based on data from 323. to 473. K.; AC
16.7398.GCHinckley, Bidleman, et al., 1990Based on data from 343. to 453. K.; AC
14.0519.AStephenson and Malanowski, 1987Based on data from 504. to 615. K.; AC
14.8500.N/AKudchadker, Kudchadker, et al., 1979See also Hanshaw, Nutt, et al., 2008.; AC
14.1558.IMortimer and Murphy, 1923Based on data from 500. to 616. K.; AC
14.4515.IMortimer and Murphy, 1923Based on data from 500. to 616. K. See also Boublik, Fried, et al., 1984.; AC
14.2555.INELSON and SENSEMAN, 1922Based on data from 496. to 614. K.; AC
14.5511.INELSON and SENSEMAN, 1922Based on data from 496. to 614. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
496.4 to 613.84.724262759.53-30.753Mortimer and Murphy, 1923Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
23.4 ± 0.1320. to 355.MEOja, Chen, et al., 2009AC
23.5 ± 0.2320. to 350.MEOja, Chen, et al., 2009AC
23.3 ± 0.31369.MESiddiqi, Siddiqui, et al., 2009Based on data from 339. to 399. K.; AC
22.8 ± 0.29337.N/AChen, Oja, et al., 2006Based on data from 320. to 354. K.; AC
21.8338.GSGrayson and Fosbraey, 2006Based on data from 323. to 353. K.; AC
23.6 ± 0.1350.MERibeiro da Silva, Monte, et al., 2006Based on data from 340. to 360. K.; AC
24.50 ± 0.45358.MEVerevkin, 2004Based on data from 348. to 368. K.; AC
23. ± 1.283. to 323.LEMcEachern and Sandoval, 2001AC
22.6423. to 488.MEMEmmenegger and Piccand, 1999AC
24.50338. to 353.MEKloc and Laudise, 1998AC
23.90 ± 0.67341.MEOja and Suuberg, 1998Based on data from 318. to 363. K.; AC
23.8383.GSNass, Lenoir, et al., 1995Based on data from 313. to 453. K.; AC
24.52338.GSHansen and Eckert, 1986Based on data from 313. to 363. K.; AC
23.6346.GSRordorf, 1986Based on data from 318. to 373. K.; AC
22.5353. to 399.GSBender, Bieling, et al., 1983AC
21.9 ± 0.2303.GSSonnefeld, Zoller, et al., 1983Based on data from 283. to 323. K.; AC
22.7376.GSMacknick and Prausnitz, 1979Based on data from 358. to 393. K.; AC
23.6 ± 0.1363. to 448.HSADygdala, Stefanski, et al., 1977AC
23.2328. to 372.METaylor and Crookes, 1976AC
24.1 ± 0.1353. to 432.MEMalaspina, 1973AC
23.8393.CMalaspina, 1973AC
20.1290. to 358.ME,CWiedemann, 1972See also Beech and Lintonbon, 1971.; AC
23.54342.VKelley and Rice, 1964ALS
23.5 ± 0.50342. to 359.N/AKelley and Rice, 1964, 2See also Cox and Pilcher, 1970.; AC
22. ± 0.31337.TEBudurov, 1960Based on data from 327. to 346. K.; AC
24.71 ± 0.69303. to 373.N/AHoyer and Peperle, 1958See also Cox and Pilcher, 1970.; AC
24.70 ± 0.70303.VHoyer and Peperle, 1958, 2Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 24.3 kcal/mol; ALS
24.40 ± 0.50338. to 353.N/ABradley and Cleasby, 1953See also Cox and Pilcher, 1970.; AC
24.40346.N/ABradley and Cleasby, 1953, 2Based on data from 339. to 353. K.; AC
24.400338.7VBradley and Cleasby, 1953, 3ALS
23.3 ± 0.5396. to 421.HSAStevens, 1953AC
23.3 ± 0.5396.VStevens, 1953, 2ALS
22.0 ± 0.50364.MEInokuchi, Shiba, et al., 1952AC
21.6353.MEInokuchi, 1951AC
23.3 ± 0.29378. to 398.RGSears and Hopke, 1949AC
22.3 ± 1.0353.N/AWolf and Weghofer, 1938AC
22.3 ± 0.2353.VWolf and Weghofer, 1938, 2ALS

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
7.0201488.93N/AGoursot, Girdhar, et al., 1970Note that table of smoothed values indicates Hm = 6485 J/mol and Sm = 251 J/mol*K.; DH
7.12492.DSCRojas and Orozco, 2003Based on data from 463. to 503. K.; AC
7.53491.DSCStoroniak, Krzyminski, et al., 2003AC
6.88489.4DSCLisicki and Jamróz, 2000AC
7.020488.9N/ADomalski and Hearing, 1996AC
6.8905490.N/AUeberreiter and Orthmann, 1950DH
6.9001489.7N/AHildebrand, Duschak, et al., 1917DH

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
14.36488.93Goursot, Girdhar, et al., 1970Note; DH
13.9490.Ueberreiter and Orthmann, 1950DH
14.1489.7Hildebrand, Duschak, et al., 1917DH

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
6.9312490.6crystaline, IliquidRadomska and Radomski, 1980DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
14.1490.6crystaline, IliquidRadomska and Radomski, 1980DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C14H11+ + Anthracene = (C14H11+ • Anthracene)

By formula: C14H11+ + C14H10 = (C14H11+ • C14H10)

Quantity Value Units Method Reference Comment
Δr16.0kcal/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr28.cal/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.1352.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M

Anthracene photodimer = 2Anthracene

By formula: C28H20 = 2C14H10

Quantity Value Units Method Reference Comment
Δr-16.0kcal/molCmBendig, Buchwitz, et al., 1981liquid phase; solvent: Cyclohexane; Dimerization, see Bendig and Kreysig, 1981; ALS
Δr6.9 ± 1.5kcal/molCmDonati, Guarini, et al., 1981solid phase; ALS

C14H10+ + Anthracene = (C14H10+ • Anthracene)

By formula: C14H10+ + C14H10 = (C14H10+ • C14H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr16.4kcal/molPHPMSMeot-Ner (Mautner), 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr26.cal/mol*KPHPMSMeot-Ner (Mautner), 1980gas phase; M

Maleic anhydride + Anthracene = Anthracene-maleic anhydride Diels-Alder adduct

By formula: C4H2O3 + C14H10 = C18H12O3

Quantity Value Units Method Reference Comment
Δr-22. ± 0.5kcal/molCmKiselev, Mavrin, et al., 1982liquid phase; solvent: Benzene; ALS
Δr-22.4kcal/molEqkLenz, Hegedus, et al., 1982liquid phase; solvent: 1,2,4-C6H3Cl3; ALS

1,4-Dewar anthracene = Anthracene

By formula: C14H10 = C14H10

Quantity Value Units Method Reference Comment
Δr-77.4 ± 0.2kcal/molEqkDreeskamp, Kapahnke, et al., 1988liquid phase; solvent: Heptane; Isomerization; ALS

Anthracene + 2,5-Furnadione, 3-(1-methylethyl)- = C21H18O3

By formula: C14H10 + C7H8O3 = C21H18O3

Quantity Value Units Method Reference Comment
Δr-20.9kcal/molEqkLenz, Hegedus, et al., 1982liquid phase; solvent: 1,2,4-C6H3Cl3; ALS

9,10-Dihydro-9,10-ethanoanthracene-11,11,12,12-tetracarbonitrile = Anthracene + Tetracyanoethylene

By formula: C20H10N4 = C14H10 + C6N4

Quantity Value Units Method Reference Comment
Δr9.69 ± 0.50kcal/molCmRogers, 1972solid phase; ALS

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference
15. XN/A
35.4000.XN/A
17. LN/A
1.4 MN/A
56. VN/A

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C14H10+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.439 ± 0.006eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)209.7kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity202.3kcal/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.530 ± 0.020LPESAndo, Mitsui, et al., 2007B
0.5300 ± 0.0050LPESScheidt and Weinkauf, 1997B
0.60 ± 0.10TDEqHeinis, Chowdhury, et al., 1993ΔGea(343 K) = -13.2 kcal/mol; ΔSea = -1.1 eu.; B
0.660 ± 0.060ECDRuoff, Kadish, et al., 1995Revised data, work of Becker and Chen, 1966; B
0.570 ± 0.020ECDLyons, Morris, et al., 1968B
0.5560 ± 0.0080ECDBecker and Chen, 1966B
<0.481 ± 0.039ECDWojnarovits and Foldiak, 1981EA is an upper limit: Chen and Wentworth, 1989.; B
0.41998ECDWentworth and Becker, 1962B

Proton affinity at 298K

Proton affinity (kcal/mol) Reference Comment
207.8Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Gas basicity at 298K

Gas basicity (review) (kcal/mol) Reference Comment
201.4Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Ionization energy determinations

IE (eV) Method Reference Comment
7.439 ± 0.006LSHager and Wallace, 1988LL
7.47EIStahl and Maquin, 1984LBLHLM
7.43PEKlasinc, Kovac, et al., 1983LBLHLM
7.45 ± 0.05EQMautner(Meot-Ner), 1980LLK
7.47PEStreets and Williams, 1974LLK
7.47SKoch, Otto, et al., 1973LLK
7.40PIAihara and Inokuchi, 1973LLK
7.41 ± 0.05PEEland, 1972LLK
7.47 ± 0.01PEDewar and Goodman, 1972LLK
7.40PEClark, Brogli, et al., 1972LLK
7.47 ± 0.01PEBoschi, Murrell, et al., 1972LLK
7.41PERowland, 1971Unpublished result of J.H.D. Eland; LLK
7.414SKitagawa, 1968RDSH
7.5PIKitagawa, 1968RDSH
7.15SAngus and Morris, 1966RDSH
7.42CTSKuroda, 1964RDSH
7.2CTSFinch, 1964RDSH
7.43CTSBriegleb, 1964RDSH
7.40CTSKinoshita, 1962RDSH
7.4PITerenin, 1961RDSH
7.35CTSBriegleb, Czekalla, et al., 1961RDSH
7.37CTSBirks and Stifkin, 1961RDSH
7.55EIWacks and Dibeler, 1959RDSH
21.1EIWacks and Dibeler, 1959RDSH
7.4CTSFoster, 1959RDSH
7.4CTSBriegleb and Czekalla, 1959RDSH
7.23CTSMatsen, 1956RDSH
7.43 ± 0.03PEKlasinc, Kovac, et al., 1978Vertical value; LLK
7.41 ± 0.02PESchmidt, 1977Vertical value; LLK
7.41PEClar and Schmidt, 1976Vertical value; LLK
7.40PEJongsma, Vermeer, et al., 1975Vertical value; LLK
7.42 ± 0.02PEHush, Cheung, et al., 1975Vertical value; LLK
7.44 ± 0.03PEMarschner and Goetz, 1974Vertical value; LLK
7.40PESchafer, Schweig, et al., 1972Vertical value; LLK

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C14H10+ + Anthracene = (C14H10+ • Anthracene)

By formula: C14H10+ + C14H10 = (C14H10+ • C14H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr16.4kcal/molPHPMSMeot-Ner (Mautner), 1980gas phase
Quantity Value Units Method Reference Comment
Δr26.cal/mol*KPHPMSMeot-Ner (Mautner), 1980gas phase

C14H11+ + Anthracene = (C14H11+ • Anthracene)

By formula: C14H11+ + C14H10 = (C14H11+ • C14H10)

Quantity Value Units Method Reference Comment
Δr16.0kcal/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr28.cal/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.1352.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW- 132
NIST MS number 228201

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Eugeny B. Stern, Antonina A. Goncharova, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Ferguson, Reeves, et al., 1957
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 1240
Instrument Beckman DU
Melting point 215
Boiling point 339.9

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dorofeeva O.V., 1988
Dorofeeva O.V., Thermodynamic Properties of Polycyclic Aromatic Hydrocarbons in the Gaseous Phase. Institute for High Temperatures, USSR Academy of Sciences, Preprint No.1-238 (in Russian), Moscow, 1988. [all data]

Kudchadker S.A., 1979
Kudchadker S.A., Chemical thermodynamic properties of anthracene and phenathrene, J. Chem. Thermodyn., 1979, 11, 1051-1059. [all data]

Frenkel M., 1994
Frenkel M., Thermodynamics of Organic Compounds in the Gas State, Vol. I, II, Thermodynamics Research Center, College Station, Texas, 1994, 1994. [all data]

Goursot, Girdhar, et al., 1970
Goursot, P.; Girdhar, H.L.; Westrum, E.F., Jr., Thermodynamics of polynuclear aromatic molecules. III. Heat capacities and enthalpies of fusion of anthracene, J. Phys. Chem., 1970, 74, 2538-2541. [all data]

Goursot, Girdhar, et al., 1968
Goursot, P.; Girdhar, H.L.; Westrum, E.F., Jr., Mesure de la capacite calorifique de l'anthracene de 5 a 520K, Compt. rend., 1968, C266, 949-950. [all data]

Huffman, Parks, et al., 1931
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Matsen, 1956
Matsen, F.A., Electron affinities, methyl affinities, and ionization energies of condensed ring aromatic hydrocarbons, J. Chem. Phys., 1956, 24, 602. [all data]

Klasinc, Kovac, et al., 1978
Klasinc, L.; Kovac, B.; Schoof, S.; Gusten, H., Photoelectron spectroscopy of 9-substituted anthracenes, Croat. Chem. Acta., 1978, 51, 307. [all data]

Schmidt, 1977
Schmidt, W., Photoelectron spectra of polynuclear aromatics. V. Correlations with ultraviolet absorption spectra in the catacondensed series, J. Chem. Phys., 1977, 66, 828. [all data]

Clar and Schmidt, 1976
Clar, E.; Schmidt, W., Correlations between photoelectron and phosphorescence spectra of polycyclic hydrocarbons, Tetrahedron, 1976, 32, 2563. [all data]

Jongsma, Vermeer, et al., 1975
Jongsma, C.; Vermeer, H.; Bickelhaupt, F.; Schafer, W.; Schweig, A., 10-methyl-9-phosphaanthracene, Tetrahedron, 1975, 31, 2931. [all data]

Hush, Cheung, et al., 1975
Hush, N.S.; Cheung, A.S.; Hilton, P.R., Binding energies of π- and "lone pair"-levels in mono- and diaza-phenanthrenes and anthracenes: an He(I) photoelectron spectroscopic study, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 385. [all data]

Marschner and Goetz, 1974
Marschner, F.; Goetz, H., Korrelation zwischen photoelektronen- und elektronen-spektren. II. Untersuchung aromatischer π-systeme mit modifizierten PPP-SCF-CI-parametern, Tetrahedron, 1974, 30, 3159. [all data]

Schafer, Schweig, et al., 1972
Schafer, W.; Schweig, A.; Bickelhaupt, F.; Vermeer, H., Photoelectron spectroscopy and conjugation. Direct proof of the unusual sequence of the two highest occupied π-molecular orbitals in the phosphorin (phosphabenzene) and the arsenin (arsabenzene) system, Angew. Chem. Int. Ed. Engl., 1972, 11, 924. [all data]

Ferguson, Reeves, et al., 1957
Ferguson, J.; Reeves, L.W.; Schneider, W.G., Vapor absorption spectra and oscillator strengths of naphthalene, anthracene, and pyrene, Can. J. Chem., 1957, 35, 1117-1123. [all data]


Notes

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