bromophenylmercury
- Formula: C6H5BrHg
- Molecular weight: 357.60
- CAS Registry Number: 1192-89-8
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | 9.13 ± 0.74 | kcal/mol | Review | Martinho Simões | The enthalpy of formation relies on 67.3 ± 1.3 kcal/mol for the enthalpy of formation of Hg(Ph)2(l). |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(l) +
(cr) = 2C6H5BrHg (cr)
By formula: C12H10Hg (l) + Br2Hg (cr) = 2C6H5BrHg (cr)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -8.48 ± 0.29 | kcal/mol | RSC | Hartley, Pritchard, et al., 1951 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970. |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.1 | PE | Baidin, Chizhov, et al., 1981 | LLK |
| 8.77 ± 0.05 | PE | Baidin, Timoshenko, et al., 1985 | Vertical value; LBLHLM |
| 9.33 | PE | Baidin, Chizhov, et al., 1981 | Vertical value; LLK |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Hartley, Pritchard, et al., 1951
Hartley, K.; Pritchard, H.O.; Skinner, H.A.,
Thermochemistry of metallic alkyls. IV. Mercury diethyl and mercury diphenyl,
Trans. Faraday Soc., 1951, 47, 254, https://doi.org/10.1039/tf9514700254
. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Baidin, Chizhov, et al., 1981
Baidin, V.N.; Chizhov, Y.V.; Timoshenko, M.M.; Ustynyuk, Y.A.; Kritskaya, I.I.,
He(I) photoelectronic spectra of organic compounds with a mercury atom attached to an sp2 hybridized carbon,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981, 2362. [all data]
Baidin, Timoshenko, et al., 1985
Baidin, V.N.; Timoshenko, M.M.; Chizhov, Y.V.; Ustynyuk, Y.A.; Kritskaya, I.I.,
Photoelectron spectra nad the structure of organomercury compounds,
J. Organomet. Chem., 1985, 292, 55. [all data]
Notes
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- Symbols used in this document:
ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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