2,5,8,11-Tetraoxadodecane

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Quantity Value Units Method Reference Comment
Proton affinity (review)946.6kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity892.4kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
9.8PEBaker, Armen, et al., 1983Vertical value; LBLHLM

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C3H10N+ + 2,5,8,11-Tetraoxadodecane = (C3H10N+ • 2,5,8,11-Tetraoxadodecane)

By formula: C3H10N+ + C8H18O4 = (C3H10N+ • C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr145.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Δr167.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

C4H5N2+ + 2,5,8,11-Tetraoxadodecane = (C4H5N2+ • 2,5,8,11-Tetraoxadodecane)

By formula: C4H5N2+ + C8H18O4 = (C4H5N2+ • C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr155.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Δr173.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

C5H6N+ + 2,5,8,11-Tetraoxadodecane = (C5H6N+ • 2,5,8,11-Tetraoxadodecane)

By formula: C5H6N+ + C8H18O4 = (C5H6N+ • C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr145.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Δr160.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C6H14N+ + 2,5,8,11-Tetraoxadodecane = (C6H14N+ • 2,5,8,11-Tetraoxadodecane)

By formula: C6H14N+ + C8H18O4 = (C6H14N+ • C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr181.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Δr183.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

IR Spectrum

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Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Baker, Armen, et al., 1983
Baker, A.D.; Armen, G.H.; Funaro, S., Oral levels of crown ethers and related macrocycles studies by ultraviolet photoelectron spectroscopy: Relationship to complexation studies, J. Chem. Soc. Dalton Trans., 1983, 2519. [all data]

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]


Notes

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