1-Decanol
- Formula: C10H22O
- Molecular weight: 158.2811
- IUPAC Standard InChI: InChI=1S/C10H22O/c1-2-3-4-5-6-7-8-9-10-11/h11H,2-10H2,1H3
- IUPAC Standard InChIKey: MWKFXSUHUHTGQN-UHFFFAOYSA-N
- CAS Registry Number: 112-30-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Other names: Decyl alcohol; n-Decan-1-ol; n-Decanol; n-Decyl alcohol; Alcohol C10; Alfol 10; Capric alcohol; Caprinic alcohol; Decanol; Nonylcarbinol; Sipol L10; T-148; Decylic Alcohol; Decan-1-ol; Decanol-(1); Agent 504; Antak; Dytol S-91; Decyl, n- alcohol; Lorol 22; Primary decyl alcohol; Royaltac; C 10 alcohol; Epal 10; Royaltac-85; Royaltac M-2; Lorol C10; Nonylcacarbinol; 1-Hydroxydecane; Conol 10N; Kalcohl 10H; NSC 406313; Nacol 10-99
- Information on this page:
- Other data available:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -395. ± 10. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -478.1 ± 1.1 | kJ/mol | Ccb | Mosselman and Dekker, 1975 | ALS |
| ΔfH°liquid | -479.74 ± 0.96 | kJ/mol | Ccb | Chao and Rossini, 1965 | see Rossini, 1934; ALS |
| ΔfH°liquid | -486.1 ± 3.3 | kJ/mol | Ccb | Green, 1960 | ALS |
| ΔfH°liquid | -486.1 ± 3.0 | kJ/mol | Ccb | Verkade and Coops, 1927 | estimated uncertainty; DRB |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -6619. ± 8. | kJ/mol | Ccb | Freeman and Bagby, 1989 | Corresponding ΔfHºliquid = -460. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| ΔcH°liquid | -6601.1 ± 1.1 | kJ/mol | Ccb | Mosselman and Dekker, 1975 | Corresponding ΔfHºliquid = -478.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| ΔcH°liquid | -6599.63 ± 0.75 | kJ/mol | Ccb | Chao and Rossini, 1965 | see Rossini, 1934; Corresponding ΔfHºliquid = -479.61 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| ΔcH°liquid | -6593.3 ± 3.3 | kJ/mol | Ccb | Green, 1960 | Corresponding ΔfHºliquid = -485.97 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| ΔcH°liquid | -6593.1 | kJ/mol | Ccb | Verkade and Coops, 1927 | Corrected for 298 and 1 atm.; Corresponding ΔfHºliquid = -486.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 372.98 | 298.15 | Andreoli-Ball, Patterson, et al., 1988 | DH |
| 387.8 | 304.05 | Naziev and Bashirov, 1988 | T = 304 to 497 K. p = 0.1 MPa. Unsmoothed experimental datum given as 2.45 kJ/kg*K. Cp data given at pressures from 0.1 to 50 MPa.; DH |
| 369.96 | 298.15 | Costas and Patterson, 1985 | T = 283.15, 298.15, 313.15 K.; DH |
| 377.8 | 305.79 | Griigo'ev, Yanin, et al., 1979 | T = 305 to 463 K. p = 0.98 bar.; DH |
| 377. | 301. | Svensson, 1979 | T = 301 to 461 K.; DH |
| 377.30 | 303.15 | Woycicka and Kalinowska, 1975 | DH |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C10H21O- + =
By formula: C10H21O- + H+ = C10H22O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1560. ± 8.4 | kJ/mol | CIDC | Haas and Harrison, 1993 | gas phase; CIDC at 50 eV 1.0 kcal/mol weaker than metastable value. |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1533. ± 8.8 | kJ/mol | H-TS | Haas and Harrison, 1993 | gas phase; CIDC at 50 eV 1.0 kcal/mol weaker than metastable value. |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H.,
Enthalpies of formation of n-alkan-1-ols,
J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]
Chao and Rossini, 1965
Chao, J.; Rossini, F.D.,
Heats of combustion, formation, and isomerization of nineteen alkanols,
J. Chem. Eng. Data, 1965, 10, 374-379. [all data]
Rossini, 1934
Rossini, F.D.,
Heats of combustion and of formation of the normal aliphatic alcohols in the gaseous and liquid states, and the energies of their atomic linkages,
J. Res. NBS, 1934, 13, 189-197. [all data]
Green, 1960
Green, J.H.S.,
Revision of the values of the heats of formation of normal alcohols,
Chem. Ind. (London), 1960, 1215-1216. [all data]
Verkade and Coops, 1927
Verkade, P.E.; Coops, J., Jr.,
Calorimetric researches XIV. Heats of combustion of successive members of homologous series: the normal primary aliphatic alcohols,
Recl. Trav. Chim. Pays-Bas, 1927, 46, 903-917. [all data]
Freeman and Bagby, 1989
Freeman, B.; Bagby, M.O.,
Heats of combustion of fatty esters and triglycerides,
J. Am. Oil Chem. Soc., 1989, 66, 1601-1605. [all data]
Andreoli-Ball, Patterson, et al., 1988
Andreoli-Ball, L.; Patterson, D.; Costas, M.; Caceres-Alonso, M.,
Heat capacity and corresponding states in alkan-1-ol-n-alkane systems, J. Chem. Soc.,
Faraday Trans. 1, 1988, 84(11), 3991-4012. [all data]
Naziev and Bashirov, 1988
Naziev, Ya.M.; Bashirov, M.M.,
Isobaric specific heats of higher alcohols at elevated pressures,
Teplofiz. Vysok. Temp., 1988, 26, 58-62. [all data]
Costas and Patterson, 1985
Costas, M.; Patterson, D.,
Self-association of alcohols in inert solvents, J. Chem. Soc.,
Faraday Trans. 1, 1985, 81, 635-654. [all data]
Griigo'ev, Yanin, et al., 1979
Griigo'ev, B.A.; Yanin, G.S.; Rastorguev, Yu.L.; Thermophysical parameters of alcohols, Tr. GIAP,
54, 1979, 57-64. [all data]
Svensson, 1979
Svensson, Ch.,
Enthalpies of vaporization of 1-decanol and 1-dodecanol and their influence on the CH2-increment for the enthalpies of formation,
J. Chem. Thermodynam., 1979, 11, 593-596. [all data]
Woycicka and Kalinowska, 1975
Woycicka, M.K.; Kalinowska, B.,
Enthalpies of mixing and excess heat capacities of dilute solutions of n-decanol with n-heptane and n-tridecane, Bull. Acad. Pol. Sci.,
Ser. Sci. Chim., 1975, 23, 759-764. [all data]
Haas and Harrison, 1993
Haas, M.J.; Harrison, A.G.,
The Fragmentation of Proton-Bound Cluster Ions and the Gas-Phase Acidities of Alcohols,
Int. J. Mass Spectrom. Ion Proc., 1993, 124, 2, 115, https://doi.org/10.1016/0168-1176(93)80003-W
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.